9-phenyl-9H-carbazol-1-amine | 855180-11-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-phenyl-9H-carbazol-1-amine
• 英文别名: 9-phenylcarbazol-1-amine
• CAS: 855180-11-9
• 化学式: C₁₈H₁₄N₂
• 分子量: 258.323
• InChiKey: NQDMRWHYXXDCLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  31
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-phenyl-9H-carbazol-1-amine 在 aluminum (III) chloride 、 potassium acetate 、 potassium carbonate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 三氯氧磷 、 三环己基膦 作用下， 以 1,4-二氧六环 、 水 、 氯苯 、 丙酮 为溶剂， 生成 C₂₇H₂₅BN₂O₂
  参考文献：
  名称：

  헤테로고리 화합물 및 이를 포함한 유기 발광 소자

  摘要：

  本发明提供了一种化学式为1的杂环化合物及包含该化合物的有机发光器件。

  公开号：

  KR20200068392A
• 作为产物：
  描述：

  咔唑 在 copper(II) nitrate trihydrate 、 palladium 10% on activated carbon 、 乙酸酐 、 potassium carbonate 、 一水合肼 、 溶剂黄146 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 为溶剂， 反应 9.83h， 生成 9-phenyl-9H-carbazol-1-amine
  参考文献：
  名称：

  Carbazole N-substituent effect upon DTMA: stabilizing and photochromic modulating

  摘要：

  Dithienylmaleimide derivatives 7-27 were synthesized by introducing N-substituted carbazole for photo-stabilizing purpose, and the structures were fully confirmed. The photochromism and photo-stability were recorded via UV-vis spectra. Only ortho compounds 8-17 with N-substituents on carbazole moiety showed escalated photochromic change, while compound 7 and the para counterparts 18-27 showed no appreciable photochromism. Additionally, compounds 8-18 exhibited good photo-stability except 17 under 254 nm irradiation. The unstability of 17 may probably due to overrunning hindrance. These photochromic patterns indicated that hindrance and electronic effect mutually paid a decisive influence on the photochromism and photo-stability, which potentially exploited a new way to construct novel photochromic materials with regulable and conceivable performance. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.07.040

文献信息

• NOVEL COMPOUND AND ORGANIC ELECTROLUMINESCENCE DEVICE INCLUDING THESAME
  申请人：DOOSAN CORPORATION

  公开号：US20150236272A1

  公开（公告）日：2015-08-20

  The present invention relates to a novel indole-based compound having excellent hole injection and transport capabilities, light-emitting capabilities, and the like, and an organic electroluminescence device which includes the indole-based compound in one or more organic material layers thereof so as to improve characteristics such as light-emitting efficiency, driving voltage, and lifespan.

  本发明涉及一种新型的以吲哚为基础的化合物，具有优良的空穴注入和传输能力、发光能力等，并且包括该吲哚基化合物在一个或多个有机材料层中的有机电致发光器件，以改善其发光效率、驱动电压和寿命等特性。
• [EN] COMPOSITION OF MATTER FOR USE ORGANIC LIGHT-EMITTING DIODES<br/>[FR] COMPOSITION DE MATIÈRE DESTINÉE À ÊTRE UTILISÉE DANS DES DIODES ÉLECTROLUMINESCENTES ORGANIQUES
  申请人：KYULUX INC

  公开号：WO2019191454A1

  公开（公告）日：2019-10-03

  The present disclosure relates to compounds of Formula (I), (II), or (III) as compounds capable of emitting delayed fluorescence, and uses of the compounds in organic light-emitting diodes.

  本公开涉及化合物的公式(I)、(II)或(III)作为能够发射延迟荧光的化合物，以及在有机发光二极管中使用这些化合物的用途。
• ORGANIC ELECTROLUMINESCENT ELEMENT MATERIAL HAVING SILICON-CONTAINING FOUR MEMBERED RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel & Sumikin Chemical Co., Ltd.

  公开号：EP2762483A1

  公开（公告）日：2014-08-06

  Provided are a material for an organic electroluminescent element formed of a silicon-containing four-membered ring compound, and an organic electroluminescent element using the material. The material for an organic electroluminescent element is formed of a compound represented by the following formula (1) and is used for, for example,a light-emitting layer containing a phosphorescent light-emitting dopant in an organic electroluminescent element. In the formula, X represents nitrogen or phosphorus, L's each represent an (n+1)-valent aromatic hydrocarbon group or aromatic heterocyclic group, and at least one of the L's represents an aromatic heterocyclic group. A1 to A6 each represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, an aromatic heterocyclic group, or an amino group, and n represents an integer of 0 to 3.

  提供了一种用含硅四元环化合物制备有机电致发光元件的材料，以及使用该材料的有机电致发光元件。该有机电致发光元件的材料由以下式子（1）所表示的化合物组成，例如用于含有荧光杂质的发光层的有机电致发光元件。在该式中，X代表氮或磷，L分别代表（n+1）价芳香族烃基或芳香族杂环基，至少一个L代表芳香族杂环基。A1至A6分别代表烷基、环烷基、烯基、炔基、芳香族烃基、芳香族杂环基或氨基，n代表0至3的整数。
• DOUBLE-SPIRO TYPE COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE CONTAINING SAME
  申请人：LG CHEM, LTD.

  公开号：US20180002256A1

  公开（公告）日：2018-01-04

  The present specification relates to a double spiro structure compound, and an organic light emitting device comprising the same.

  本说明书涉及一种双螺旋结构化合物及包括其的有机发光装置。
• 화합물 및 이를 포함하는 유기 발광 소자
  申请人：Soulbrain Co., Ltd. 솔브레인 주식회사(120200555471) Corp. No ▼ 131111-0597525BRN ▼524-86-01789

  公开号：KR20190064518A

  公开（公告）日：2019-06-10

  본 발명은 화학식 1의 화합물 및 이를 포함하는 유기 발광 소자를 제공한다. [화학식 1]

  本发明提供了化学式1的化合物和包含该化合物的有机发光器件。 [化学式1]