Methyl-hederagonat | 5672-34-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Methyl-hederagonat
• 英文别名: Methyl hederagonate；methyl (4aS,6aR,6aS,6bR,8aR,9R,12aR,14bS)-9-(hydroxymethyl)-2,2,6a,6b,9,12a-hexamethyl-10-oxo-3,4,5,6,6a,7,8,8a,11,12,13,14b-dodecahydro-1H-picene-4a-carboxylate
• CAS: 5672-34-4
• 化学式: C₃₁H₄₈O₄
• 分子量: 484.72
• InChiKey: SCNJKSGGJJIVNC-CYFLCHJQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  35
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Methyl-hederagonat 在 sodium tetrahydroborate 作用下， 生成 methyl hederageninate
  参考文献：
  名称：

  Hederagenic acid and other constituents of Viburnum erubescens

  摘要：

  DOI：

  10.1016/s0031-9422(00)91382-7
• 作为产物：
  描述：

  23-methylhederagenin methyl ester 在 potassium permanganate 、 硫酸 、 丙酮 作用下， 生成 Methyl-hederagonat
  参考文献：
  名称：

  L'hédéracosideA，新的hétérosideExtrait du lierre（Hedera helix L.）

  摘要：

  在蒙特雷峰（Hedera helix L.）上的dans le bois et dans les feuilles de lierre（d.unhetérosideencore inconnu），l'hédéracosideA，倒入lequel la la宪章d'un glucosido-5-arabinoside de l'hédéragén可能参与到C-2葡聚糖的羟基参与中。范·德·哈尔（L'α-hédérinede van der Haar），《葡萄糖与鼠李糖》杂志，《复古》。

  DOI：

  10.1002/hlca.19550380225

文献信息

• 3-epi-Oleanene type triterpene glycosyl esters from leaves of Acanthopanax spinosus
  作者：Masazumi Miyakoshi、Yoshiteru Ida、Susumu Isoda、Junzo Shoji

  DOI：10.1016/0031-9422(93)85298-6

  日期：1993.7

  Three novel 3-epi-oleanene type triterpene oligo-glycosyl esters, spinosides D1-D3, were isolated from the leaves of Acanthopanax spinosus. The structures were established to be 28-O-alpha-L-rhamnopyranosyl(1 --> 4)-beta-D-glucopyranosyl (1 --> 6)-beta-D-glucopyranosyl esters of 3-epi-serratagenic acid, 3alpha-hydroxy-23-oxoolean-12-ene-28,29-dioic acid and 3alpha,23-dihydroxy-olean-12-ene-28,29-dioic acid.
• van der Haar, Recueil des Travaux Chimiques des Pays-Bas, 1925, vol. 44, p. 743,751, 752
  作者：van der Haar

  DOI：——

  日期：——
• Jacobs, Journal of Biological Chemistry, 1925, vol. 63, p. 621
  作者：Jacobs

  DOI：——

  日期：——
• Amey: A multipurpose, russet-skinned potato cultivar for the Eastern United States
  作者：K. G. Haynes、G. A. Porter、B. J. Christ、R. W. Goth、K. O. DeLong、D. E. Halseth、J. B. Sieczka、M. R. Henninger、S. B. Sterrett、G. C. Yencho、R. E. Webb

  DOI：10.1007/bf02883542

  日期：2001.5

  Amey is a late-maturing, russet-skinned, white-fleshed potato cultivar that yields more than Russet Burbank in most eastern United States potato production areas. Tubers of Amey are mostly oblong, occasionally long, with an evenly russetted skin. Tubers of Amey are smoother, more attractive, and have a much lower incidence of external defects than Russet Burbank. The specific gravity of Amey is equal to or greater than the specific gravity of Russet Burbank. French fries produced from Amey are lighter than or equal in color to those produced from Russet Burbank; however, tubers are frequently not long enough to satisfy the bench by industry. Baking and taste quality of Amey are excellent, and it has potential as a fresh market potato. Amey is resistant to race Ro1 of the golden nematode, powdery scab, and common scab. It is moderately susceptible to Verticillium milt. It is susceptible to potato leafroll virus, late blight, and early blight.
• Barton et al., Journal of the Chemical Society, 1954, p. 903,906
  作者：Barton et al.

  DOI：——

  日期：——