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3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenal | 4951-40-0

中文名称
——
中文别名
——
英文名称
3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenal
英文别名
3-(2,6,6-Trimethylcyclohex-1-enyl)prop-2-enal;3-(2,6,6-trimethyl-cyclohex-1-enyl)-acrylaldehyde;3-(2,6,6-Trimethyl-cyclohex-1-enyl)-acrylaldehyd;β-Cyclocitrylidin-acetaldehyd;β-Ionon;3-(2,6,6-trimethylcyclohexen-1-yl)prop-2-enal
3-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenal化学式
CAS
4951-40-0
化学式
C12H18O
mdl
——
分子量
178.274
InChiKey
FLOPAOUVAMIAJN-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    66-67 °C(Press: 0.2 Torr)
  • 密度:
    0.951±0.06 g/cm3(Predicted)
  • 稳定性/保质期:

    存在于主流烟气中。

计算性质

  • 辛醇/水分配系数(LogP):
    2.6
  • 重原子数:
    13
  • 可旋转键数:
    2
  • 环数:
    1.0
  • sp3杂化的碳原子比例:
    0.58
  • 拓扑面积:
    17.1
  • 氢给体数:
    0
  • 氢受体数:
    1

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量
  • 下游产品
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

点击查看最新优质反应信息

文献信息

  • Über gezielte aldokondensationen—II
    作者:G. Wittig、P. Suchanek
    DOI:10.1016/s0040-4020(01)82193-1
    日期:1966.1
  • Isolation and identification of the polyenes formed during the thermal degradation of .beta.,.beta.-carotene
    作者:Jim Byers
    DOI:10.1021/jo00157a026
    日期:1983.5
  • 328. Studies in the polyene series. Part II
    作者:I. M. Heilbron、W. E. Jones、A. Spinks
    DOI:10.1039/jr9390001554
    日期:——
  • v. Braun; Kurtz, Chemische Berichte, 1937, vol. 70, p. 1009,1011
    作者:v. Braun、Kurtz
    DOI:——
    日期:——
  • New Degradable Alternating Copolymers from Naturally Occurring Aldehydes: Well-Controlled Cationic Copolymerization and Complete Degradation
    作者:Yasushi Ishido、Arihiro Kanazawa、Shokyoku Kanaoka、Sadahito Aoshima
    DOI:10.1021/ma3004828
    日期:2012.5.22
    Three naturally occurring conjugated aldehydes, (1R)-(-)-myrtenal, (S)-(-)-perillaldehyde, and beta-cyclocittal, were cationically copolymerized with isobutyl vinyl ether using the EtSO3H/GaCl3 initiating system in the presence of 1,4-dioxane as an added Lewis base. Alternating copolymerization proceeded exclusively via 1,2-carbonyl addition of the aldehydes. In addition, controlled alternating copolymerization was achieved under appropriate reaction conditions, producing copolymers with controlled molecular weights and narrow molecular weight distributions. The relationships between the copolymerization behaviors and the cyclic side group structures of the aldehydes suggested that conjugated and bicyclic structures were important factors for controlled alternating copolymerization. However, too much bulkiness around the carbonyl group resulted in termination of copolymerization. The resulting alternating copolymers were stable under neutral and basic conditions. In sharp contrast, mild acidic conditions degraded the alternating copolymers almost selectively to conjugated aldehydes with low molecular weights as nearly single products.
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