9,10-二氨基菲 | 53348-04-2

• 物质功能分类: 化学试剂 - 有机试剂 - 多胺
• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 9,10-二氨基菲
• 中文别名: 9,10-菲二胺；9,1-二氨基菲
• 英文名称: 9,10-diaminophenanthrene
• 英文别名: phenanthrene-9,10-diamine；9,10-Phenanthrenediamine
• CAS: 53348-04-2
• 化学式: C₁₄H₁₂N₂
• mdl: MFCD00001178
• 分子量: 208.263
• InChiKey: VPRFQZSTJXHBHL-UHFFFAOYSA-N

物化性质

• 熔点：
  164-166 °C (lit.)
• 沸点：
  457.6±25.0 °C(Predicted)
• 密度：
  1.283±0.06 g/cm3(Predicted)
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S37/39
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  2921590090
• 危险标志：
  GHS07
• 危险性描述：
  H315,H319,H335
• 危险性防范说明：
  P261,P305 + P351 + P338
• 储存条件：
  保持贮藏器密封，并将其放入一个紧密封装的容器中。存放在阴凉、干燥的地方。

SDS

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SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name : 9,10-Diaminophenanthrene
REACH No. : A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
CAS-No. : 53348-04-2
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), H335
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Xi Irritant R36/37/38
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Warning
Hazard statement(s)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statement(s)
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard none
Statements
Other hazards - none

---

SECTION 3: Composition/information on ingredients
Substances
Synonyms : 9,10-Phenanthrenediamine
Formula : C14H12N2
Molecular Weight : 208,26 g/mol
CAS-No. : 53348-04-2
EC-No. : 258-490-9
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
9,10-Phenanthrenediamine
Skin Irrit. 2; Eye Irrit. 2; STOT -
SE 3; H315, H319, H335
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
9,10-Phenanthrenediamine
Xi, R36/37/38 -
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

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SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

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SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

---

SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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SECTION 7: Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature: 2 - 8 °C
Air and moisture sensitive. Handle under inert gas. Protect from moisture.
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Impervious clothing., The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.

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SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing Melting point/range: 164 - 166 °C - lit.
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

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SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
Air Avoid moisture.
Incompatible materials
Strong oxidizing agents, Strong acids
Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

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SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.

---

SECTION 12: Ecological information
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available

---

SECTION 13: Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

---

SECTION 14: Transport information
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine Pollutant: no IATA: no
Special precautions for user
no data available

---

SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

---

SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
Eye Irrit. Eye irritation
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Skin Irrit. Skin irritation
STOT SE Specific target organ toxicity - single exposure
Full text of R-phrases referred to under sections 2 and 3
Xi Irritant
R36/37/38 Irritating to eyes, respiratory system and skin.
Further information
Copyright 2013 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为反应物：
  描述：

  9,10-二氨基菲 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 potassium tert-butylate 、 溶剂黄146 作用下， 以 甲苯 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  유기 화합물, 이를 포함하는 유기발광다이오드와 유기발광장치

  摘要：

  该发明涉及一种有机化合物，该有机化合物具有在双苯环中各连接了2个芳香环的杂环芳香核心，用于构成芬达靛多样性，以及将该有机化合物应用于发光层的有机发光二极管和有机发光器件。该发明的有机化合物在结构上坚固，热稳定性优异，并且具有优异的载流子迁移特性。通过将该发明的有机化合物应用于发光器件中，可以提高器件的发光效率，并制造长寿命的发光器件。

  公开号：

  KR20190042882A
• 作为产物：
  描述：

  9,10-二溴菲 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 potassium tert-butylate 、 氨 作用下， 以 水 、 甲苯 为溶剂， 反应 6.0h， 以170 mmol的产率得到9,10-二氨基菲
  参考文献：
  名称：

  一种含菲结构的有机电致发光材料及其有机发光器件

  摘要：

  本发明提供一种含菲结构的有机电致发光材料及其有机发光器件，属于有机光电材料技术领域。本发明提供的一种含菲结构的有机电致发光材料结构中含有菲环结构，菲环结构是一种性能优异的蓝光结构，有着较高的三线态能级和较宽的能隙，分子中通过连接苯并咪唑基团，增加了蓝光主体结构的电子传输能力，使得载流子传输平衡。与现有技术相比，将其应用于有机发光器件，特别是作为发光层中的蓝色发光材料使用，具有相对较高的发光效率和较低的驱动电压。

  公开号：

  CN108516961A
• 作为试剂：
  描述：

  1-硝基蒽醌 在 dodecacarbonyltetrarhodium(0) 、 9,10-二氨基菲 sodium hydroxide 、 一氧化碳 作用下， 以 乙二醇甲醚 为溶剂， 25.0 ℃ 、101.32 kPa 条件下， 反应 10.0h， 生成 氨基-9,10-蒽二酮
  参考文献：
  名称：

  添加胺的铑-羰基配合物催化在CO/H2O条件下有效选择性还原芳香硝基化合物提供芳香胺

  摘要：

  通过使用添加胺的铑羰基配合物 (Rh(CO)2(acac)、Rh4(CO)12)，在室温下使用 CO (1 atm) 和水还原芳香族硝基化合物得到芳香胺的催化活性非常高。和 Rh6(CO)16) 在 2-甲氧基乙醇或二甘醇二甲醚（二甘醇二甲醚）中，含有 5 当量的 NaOH 水溶液。还原过程不仅具有高催化活性，而且具有非常高的硝基选择性，如在提供 1-氨基蒽醌的 1-硝基蒽醌的情况下所展示的，没有任何其他不饱和基团，例如 C=O，被还原。使用 Rh6(CO)16-1 还原对硝基苯甲醚生成对茴香胺，获得了 1776 mol-cat−1 h−1 (296 g-atom Rh−1 h−1) 的 TOF（周转次数/时间） ,8-双(二甲氨基)-萘催化剂。

  DOI：

  10.1246/bcsj.64.2624

文献信息

• NOVEL COMPOUND HAVING MULTIMER STRUCTURE OF XANTHENE DERIVATIVE, COLORING COMPOSITION, INK FOR INKJET RECORDING, METHOD OF INKJET RECORDING, COLOR FILTER, AND COLOR TONER
  申请人：FUJIFILM CORPORATION

  公开号：US20140176653A1

  公开（公告）日：2014-06-26

  There is provided a compound represented by formula (1): in formula (1), L represents a divalent to tetravalent linking group; D represents a residue obtained by removing 1 to 5 hydrogen atoms from a compound represented by formula (2); m represents an integer of 1 to 10, however, each L may be the same with or different from every other L; n represents an integer of 2 to 10, however, each D may be the same with or different from every other D; and in formula (2), each of R 4 to R 24 independently represents a hydrogen atom or a substituent, provided that formula (2) has at least one or more ionic hydrophilic groups.

  提供了一种由公式(1)表示的化合物：在公式(1)中，L代表二价到四价的连接基团；D代表通过从由公式(2)表示的化合物中去除1到5个氢原子获得的残基；m代表1到10的整数，但是，每个L可以相同也可以不同于其他L；n代表2到10的整数，但是，每个D可以相同也可以不同于其他D；在公式(2)中，R4到R24中的每一个独立地代表一个氢原子或一个取代基，前提是公式(2)至少有一个或更多的离子亲水基团。
• Synthesis of bis(trifluoromethylated) pyrazine-containing nitrogen heterocycles from hexafluorobiacetyl and ortho-diamines. Stabilization of the covalent dihydrates of pteridines and pyrido[3,4-b]pyrazines by trifluoromethyl groups
  作者：Mark Cushman、Wai Cheong Wong、Adelbert Bacher

  DOI：10.1039/p19860001043

  日期：——

  extent to which trifluoromethyl groups stabilize covalently bound hydrates. The substituted quinoxalines as well as the pyrido[2,3-b]pyrazine (25) and the lumazines (27), (29), and (31) were all found to exist as completely dehydrated aromatic species. Depending on the reaction conditions, both the aromatic form (33) and the stable, neutral covalent dihydrate form (34) could be obtained from the reaction

  为了确定三氟甲基基团稳定共价结合的水合物的程度，已经对源自全氟丁烷-2，3-二酮（PFBD）和多种邻二胺的反应产物的结构进行了研究。发现取代的喹喔啉以及吡啶并[2,3- b ]吡嗪（25）和lumazines（27），（29）和（31）均以完全脱水的芳族物质形式存在。取决于反应条件，芳族形式（33）和稳定的中性二价二水合物形式（34））可通过PFBD与4,5-二氨基-6-羟基嘧啶硫酸盐的反应制得（32）。还发现吡啶并[3，4- b ]吡嗪系统（36）和蝶啶（38）以稳定的中性共价二水合物存在，其中吡嗪环被选择性地水合。
• 一种含屈结构的有机电致发光材料及其有机发光器件
  申请人：长春海谱润斯科技有限公司

  公开号：CN108440418A

  公开（公告）日：2018-08-24

  本发明提供一种含屈结构的有机电致发光材料及其有机发光器件，属于有机光电材料技术领域。本发明提供的一种含屈结构的有机电致发光材料，屈环是一种性能优异的蓝光材料母核结构，有着较高的三线态能级和较宽的能隙，分子中通过连接苯并咪唑基团，增加了电子传输能力，使得载流子传输平衡。与现有技术相比，将其应用于有机发光器件，特别是作为发光层中的蓝色荧光客体使用，具有相对较高的发光效率。
• 一种含三亚苯结构的有机电致发光材料及其有机发光器件
  申请人：长春海谱润斯科技有限公司

  公开号：CN108276343A

  公开（公告）日：2018-07-13

  本发明提供一种含三亚苯结构的有机电致发光材料及其有机发光器件，属于有机光电材料技术领域。本发明提供的一种含三亚苯结构的有机电致发光材料，结构中含有三亚苯环，三亚苯环是一种性能优异的蓝光材料母核结构，有着较高的三线态能级和较宽的能隙，分子中通过连接苯并咪唑基团，增加了结构的电子传输能力，使得载流子传输平衡。与现有技术相比，将其应用于有机发光器件，特别是作为发光层中的蓝色客体材料使用，具有相对较高的发光效率。
• 一种含蒽结构的有机电致发光材料及其有机发光器件
  申请人：长春海谱润斯科技有限公司

  公开号：CN108276342A

  公开（公告）日：2018-07-13

  本发明提供一种含蒽结构的有机电致发光材料及其有机发光器件，属于有机光电材料技术领域。本发明提供的一种含蒽结构的有机电致发光材料，结构中含有蒽环，蒽环是一种性能优异的蓝光材料母核结构，有着较高的三线态能级和较宽的能隙，分子中通过连接苯并咪唑基团，增加了结构的电子传输能力，使得载流子传输平衡。与现有技术相比，将其应用于有机发光器件，特别是作为发光层中的蓝色客体材料使用，具有相对较高的发光效率。

表征谱图