菲并[3,2-b]噻吩 | 224-10-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 菲并[3,2-b]噻吩
• 英文名称: phenanthro[3,2-b]thiophene
• 英文别名: phenanthro[3,2-b]thiophene；Phenanthro[3,2-b]thiophen；naphtho[2,1-f][1]benzothiole
• CAS: 224-10-2
• 化学式: C₁₆H₁₀S
• 分子量: 234.321
• InChiKey: BKDNKFGDTSYPHA-UHFFFAOYSA-N

物化性质

• 熔点：
  121-122 °C(Solv: hexane (110-54-3))
• 沸点：
  440.7±14.0 °C(Predicted)
• 密度：
  1.292±0.06 g/cm3(Predicted)
• 保留指数：
  401.6;401.49;401.78;401.52;401.89

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2934999090

反应信息

• 作为反应物：
  描述：

  菲并[3,2-b]噻吩 在 chromium(VI) oxide 、 溶剂黄146 作用下， 生成 phenanthro[3,2-b]thiophene-7,11-quinone
  参考文献：
  名称：

  Tilak, Proceedings - Indian Academy of Sciences, Section A, 1951, # 33, p. 85

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Naphthalen-1-ylmethyl-thiophene-3-carbaldehyde 在 PPA 作用下， 反应 0.33h， 以57%的产率得到菲并[3,2-b]噻吩
  参考文献：
  名称：

  菲并[ b ]噻吩的合成

  摘要：

  母菲并[ b ]噻吩的所有异构体，即菲[1,2- b ]噻吩，菲-[2,1- b ]噻吩，菲[2,3- b ]噻吩，菲[3,4-]合成了b ]噻吩，菲[3,4- b ]噻吩，菲[4,3- b ]噻吩和菲[9,10- b ]噻吩。

  DOI：

  10.1002/jhet.5570170623

文献信息

• Cascade reaction for the synthesis of polycyclic aromatic hydrocarbons via transient directing group strategy
  作者：Ziqi Wang、Wendan Dong、Bing Sun、Qinqin Yu、Fang-Lin Zhang

  DOI：10.1016/j.tet.2019.06.036

  日期：2019.7

  A Pd(II)-catalyzed cascade synthesis of diverse polycyclic aromatic hydrocarbons via transient directing group strategy has been developed, involving the consecutive arylation, cyclization and aromatization. The efficiency and practicality were demonstrated by wide substrate range, concise synthetic pathway and mild reaction conditions. The subsequent transformations of the benz[a]anthracene core accessed

  已经开发了一种通过Pd（II）催化的通过瞬态导向基团策略级联的多种多环芳烃，涉及连续的芳基化，环化和芳构化。广泛的底物范围，简明的合成途径和温和的反应条件证明了其效率和实用性。苯并[ a ]蒽核心的后续转化获得了天然的生物活性PAH分子。
• [EN] OCTAHYDRO BIQUINOLINE COMPOUND<br/>[FR] COMPOSÉ OCTAHYDROBIQUINOLINE
  申请人：UNIV NANYANG

  公开号：WO2010132029A1

  公开（公告）日：2010-11-18

  The present invention relates to an octahydro biquinoline compound. Provided is also a method of separating the octahydro biquinoline compound into enantiomers. The octahydro biquinoline compound is of the general formula (V): In formula (V) R1 is one of H, a protective group and an aliphatic group, with the aliphatic group having a main chain of a length of 1 to about 10 carbon atoms, comprising 0 to about 6 heteroatoms selected from the group consisting of N, O, S, Se and Si. R2 and R3 are independent from one another selected from the group consisting of (i) H, (ii) one of an aliphatic, an alicyclic, an aromatic, an arylaliphatic, and an arylalicyclic group comprising 0 to about 6 heteroatoms selected from the group consisting of N, O, S, Se and Si, an ester, a carbonate group, a carbamoyl group and a phosphate ester. R4 and R5 are independent from one another H, an aliphatic, an alicyclic, an aromatic, an arylaliphatic or an arylalicyclic group comprising 0 to about 6 heteroatoms selected from the group consisting of N, O, S, Se and Si.

  本发明涉及一种八氢比喹啉化合物。还提供了将该八氢比喹啉化合物分离成对映体的方法。该八氢比喹啉化合物的一般式为（V）：在式（V）中，R1是H、保护基或脂肪基中的一种，其中脂肪基具有长度为1到约10个碳原子的主链，包括选自N、O、S、Se和Si的约0到6个杂原子。R2和R3彼此独立地选自（i）H、（ii）脂肪、脂环、芳香、芳基脂肪和芳基脂环基中的一种，包括选自N、O、S、Se和Si的约0到6个杂原子，酯、碳酸酯基、氨基甲酰基和磷酸酯。R4和R5彼此独立地是H、脂肪、脂环、芳香、芳基脂肪或芳基脂环基，包括选自N、O、S、Se和Si的约0到6个杂原子。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：TDK Corporation

  公开号：EP0857007A1

  公开（公告）日：1998-08-05

  In an organic EL device, a light emitting layer contains a specific coumarin derivative, and a hole injecting and/or transporting layer contains a specific tetraaryldiamine derivative. Also a light emitting layer in the form of a mix layer contains a specific coumarin derivative, a specific quinacridone compound or a specific styryl amine compound. There are provided at least two light emitting layers including a light emitting layer of the mix layer type wherein at least two dopants are contained so that at least two luminescent species may emit light. There is obtained an organic EL device capable of high luminance and continuous light emission and ensuring reliability. Multi-color light emission becomes possible.

  在有机电致发光器件中，发光层含有特定的香豆素衍生物，空穴注入和/或传输层含有特定的四芳基二胺衍生物。此外，混合层形式的发光层包含特定的香豆素衍生物、特定的喹吖啶酮化合物或特定的苯乙烯胺化合物。本发明提供了至少两个发光层，包括混合层类型的发光层，其中包含至少两种掺杂剂，从而至少有两种发光物质可以发光。这样就得到了一种有机 EL 器件，它能够实现高亮度和连续发光，并确保可靠性。多色发光成为可能。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC LUMINESCENT MEDIUM
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1191822A1

  公开（公告）日：2002-03-27

  An electroluminescence device comprising a pair of electrodes and a layer of an organic light emitting medium disposed between the pair of electrodes, wherein the layer of an organic light emitting medium comprises (A) at least one electron transporting compound and (B) an anthracene derivative having a specific structure and an organic light emitting medium comprising the above components (A) and (B). The device exhibits excellent heat resistance, has a long life time and provides efficient light emission. The organic light emitting medium is advantageously used for the organic EL device

  一种电致发光装置，包括一对电极和置于这对电极之间的一层有机发光介质，其中有机发光介质层包括(A) 至少一种电子传输化合物和(B) 具有特定结构的蒽衍生物，以及由上述组分(A)和(B)组成的有机发光介质。该装置具有优异的耐热性、较长的使用寿命和高效的发光性能。有机发光介质用于有机 EL 器件的优点是
• Organic electroluminescence device and organic light emitting medium
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US20020048688A1

  公开（公告）日：2002-04-25

  An electroluminescence device comprising a pair of electrodes and a layer of an organic light emitting medium disposed between the pair of electrodes, wherein the layer of an organic light emitting medium comprises (A) at least one electron transporting compound and (B) an anthracene derivative having a specific structure and an organic light emitting medium comprising the above components (A) and (B). The device exhibits excellent heat resistance, has a long life time and provides efficient light emission. The organic light emitting medium is advantageously used for the organic EL device

  一种电致发光装置，包括一对电极和置于这对电极之间的一层有机发光介质，其中有机发光介质层包括(A) 至少一种电子传输化合物和(B) 具有特定结构的蒽衍生物，以及由上述组分(A)和(B)组成的有机发光介质。该装置具有优异的耐热性、较长的使用寿命和高效的发光性能。有机发光介质用于有机 EL 器件的优点是