9,10-二氨基蒽-1-磺酸 | 1234379-68-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 9,10-二氨基蒽-1-磺酸
• 英文名称: 9,10-Diaminoanthracene-1-sulfonic acid
• CAS: 1234379-68-0
• 化学式: C₁₄H₁₂N₂O₃S
• 分子量: 288.327
• InChiKey: OWAHMBGDIIVRCY-UHFFFAOYSA-N

物化性质

• 密度：
  1.558±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  115
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  9,10-二氨基蒽-1-磺酸 在 sodium periodate 作用下， 以 水 、 乙酸乙酯 为溶剂， 反应 0.42h， 以96%的产率得到1-蒽醌磺酸
  参考文献：
  名称：

  Carbon–carbon cleavage of aryl diamines and quinone formation using sodium periodate: a novel application

  摘要：

  A first novel synthetic utility of sodium periodate for aryl diamine carbon-carbon cleavage is described. Aryl 1,2-diamine compounds were successfully converted into corresponding nitriles, while the developed method is also useful for the preparation of quinones from corresponding aryl 1,4-diamine compounds. The advantages of this protocol are shorter reaction time and mild reaction conditions to obtain moderate to good yields. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.05.103

文献信息

• Carbon–carbon cleavage of aryl diamines and quinone formation using sodium periodate: a novel application
  作者：Vikas N. Telvekar、Balaram S. Takale

  DOI：10.1016/j.tetlet.2010.05.103

  日期：2010.7

  A first novel synthetic utility of sodium periodate for aryl diamine carbon-carbon cleavage is described. Aryl 1,2-diamine compounds were successfully converted into corresponding nitriles, while the developed method is also useful for the preparation of quinones from corresponding aryl 1,4-diamine compounds. The advantages of this protocol are shorter reaction time and mild reaction conditions to obtain moderate to good yields. (C) 2010 Elsevier Ltd. All rights reserved.