2,6,10-trimethyltridecane | 3891-99-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,6,10-trimethyltridecane
• 英文别名: 2,6,10-Trimethyl-tridecan
• CAS: 3891-99-4
• 化学式: C₁₆H₃₄
• 分子量: 226.446
• InChiKey: MSRQAOLBRXEIHE-UHFFFAOYSA-N

物化性质

• 沸点：
  272 °C
• 密度：
  0.7773 g/cm3
• 保留指数：
  1467;1463;1461;1463;1463

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  金合欢醇 在 palladium on activated charcoal copper(l) iodide 、 氢气 、 triphenylphosphine dibromide 1:1 addition complex 作用下， 以 四氢呋喃 、 乙醇 为溶剂， -30.0 ℃ 、101.33 kPa 条件下， 反应 0.5h， 生成 2,6,10-trimethyltridecane
  参考文献：
  名称：

  Identification of male-specific volatiles from nearctic and neotropical stink bugs (Heteroptera: Pentatomidae)

  摘要：

  Males of the Central American stink bug species, Euschistus obscurus, produce an attractant pheromone composed of a blend of compounds characteristic of North American Euschistus spp. and the South American soybean pest, E. heros. The range of E. obscurus extends into the southern United States, the species is easy to rear, and males produce an exceptionally large quantity of pheromone (>0.5 mug/day/male). These factors made E. obscurus useful for characterizing the novel pheromone components of E. heros without importing this pest species into the United States. Euschistus obscurus males produce methyl (2E,4Z)-decadienoate (61 %) in abundance, which is characteristic of North American species, and methyl 2,6,10-trimethyltridecanoate (27 %), the main male-specific ester of E. heros. The chirality of Euschistus spp. methyl-branched esters, and field activity of synthetic formulations, remain to be determined.

  DOI：

  10.1007/bf02059746

文献信息

• Catalytic Production of Branched Small Alkanes from Biohydrocarbons
  作者：Shin-ichi Oya、Daisuke Kanno、Hideo Watanabe、Masazumi Tamura、Yoshinao Nakagawa、Keiichi Tomishige

  DOI：10.1002/cssc.201500375

  日期：2015.8.10

  Squalane, C30 algae‐derived branched hydrocarbon, was successfully converted to smaller hydrocarbons without skeletal isomerization and aromatization over ruthenium on ceria (Ru/CeO2). The internal CH2CH2 bonds located between branches are preferably dissociated to give branched alkanes with very simple distribution as compared with conventional methods using metal‐acid bifunctional catalysts.

  角鲨烷（C30藻类衍生的支链碳氢化合物）成功地转化为较小的碳氢化合物，而没有二氧化铈上钌（Ru / CeO 2）的骨架异构化和芳构化。内部CH 2  CH 2个位于分支之间的键优选解离，与使用金属-酸双官能催化剂的常规方法相比，用非常简单的分布，得到支链烷烃。
• The formation features of C10–C20 regular petroleum isoprenanes
  作者：G. N. Gordadze、M. V. Giruts、A. R. Poshibaeva、V. N. Koshelev

  DOI：10.1134/s0965544116080077

  日期：2016.8

  To model the formation processes of C-10-C-20 petroleum isoprenanes, thermolysis of regular and irregular C-20-C-40 isoprenanes (phytane, crocetane, squalane, and lycopane) and the suggested precursors of regular petroleum isoprenanes (phytol and isophytol) has been conducted. It has been shown that the thermolysis of these compounds results in the formation of regular, irregular, and pseudoregular isoprenanes; the trends in their distribution have been revealed; and the retention indices have been determined. It has been assumed that the pristane/phytane ratio, which is used in petroleum geochemistry, should be treated with caution.
• KISSIN, YURY V., IND. AND ENG. CHEM. RES., 26,(1987) N 8, 1633-1638
  作者：KISSIN, YURY V.

  DOI：——

  日期：——