[EN] METHOD FOR PREPARING ETHERS OF CYCLOALIPHATIC OR ARALIPHATIC DIOLS<br/>[FR] PROCÉDÉ DE PRÉPARATION D'ÉTHERS DE DIOLS CYCLOALIPHATIQUES OU ARALIPHATIQUES
申请人:BASF SE
公开号:WO2019110464A1
公开(公告)日:2019-06-13
The present invention relates to a method for preparing a dialkyi or dialkenyl ether of a cycloaliphatic or araliphatic diol, which comprises (i) reacting the cycloaliphatic or araliphatic diol with metallic sodium in an aprotic organic solvent in the presence of a catalytic amount of at least one monoether- monoalcohol of formula (I) wherein Y is identical or different and selected from C2-C4-alkylene, n is an integer in the range from 1 to 10, and R1 is C1-C4-Alkyl, whereby the corresponding disodium dialcoholate is obtained, reacting the disodium dialcoholate obtained in step (i) with an alkylation alkenylation reagent.
本发明涉及一种制备环脂环烷基或芳基二醇的二烷氧基或二烯氧基醚的方法,包括(i)在无水无氢的有机溶剂中,在至少一种式(I)的单醚-单醇的催化量存在下,将环脂环烷基或芳基二醇与金属钠反应,其中式中Y相同或不同,选择自C2-C4-烷基,n是1到10之间的整数,R1是C1-C4-烷基,从而得到相应的二钠二醇酸盐,将步骤(i)中得到的二钠二醇酸盐与烷基化烯基化试剂反应。