11-(甲基丙烯酰氨基)十一酸 | 59178-93-7

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 11-(甲基丙烯酰氨基)十一酸
• 英文名称: (11-Methacryloyl-amino)undecansaeure
• 英文别名: N-methacryloyl-11-aminoundecanoic acid；N-methacryl-11-aminoundecanoic acid；11-methacrylamidoundecanoic acid；11-Methacryloylaminoundecansaeure；11-(Methacryloylamino)undecanoic acid；11-(2-methylprop-2-enoylamino)undecanoic acid
• CAS: 59178-93-7
• 化学式: C₁₅H₂₇NO₃
• 分子量: 269.384
• InChiKey: YWRMFVZWFSDHFF-UHFFFAOYSA-N

物化性质

• 熔点：
  73-74°C
• 沸点：
  468.2±27.0 °C(Predicted)
• 密度：
  0.991±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  66.4
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 危险等级：
  IRRITANT
• 海关编码：
  2924199090

反应信息

• 作为反应物：
  描述：

  N-羟基丁二酰亚胺 、 11-(甲基丙烯酰氨基)十一酸 在 N,N'-二环己基碳二亚胺 、 溶剂黄146 作用下， 以 乙酸乙酯 、 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以72%的产率得到2,5-dioxopyrrolidin1-yl-11-methacrylamidoundecanoate
  参考文献：
  名称：

  WO2008/100907

  摘要：

  公开号：
• 作为产物：
  描述：

  11-氨基十一酸 、 甲基丙烯酰氯 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 生成 11-(甲基丙烯酰氨基)十一酸
  参考文献：
  名称：

  Hydrophilic, hydrophobic, and thermoreversible saccharide gels and

  摘要：

  聚合性可糖单体是通过蔗糖和（甲基）丙烯酸酯的反应制备的。在聚合可糖单体时形成了亲水性、疏水性和热可逆凝胶和泡沫。亲水性蔗糖单体是通过蔗糖与环氧丙烯酸酯反应合成的。疏水性蔗糖单体是通过蔗糖与丙烯酰氯反应，然后是乙酰氯反应合成的。热可逆蔗糖单体是通过将蔗糖改性为由丙烯酰氯和氨基羧酸制备的可聚合取代基而获得的。改性后的蔗糖单体与疏水性聚（烷基氧基）（甲基）丙烯酸酯共聚，以产生具有逆热可逆性质的水凝胶。这种热敏感水凝胶具有生物可降解性，可用于控制药物释放领域。

  公开号：

  US06018033A1

文献信息

• Surface-Treating Agents, Surface-Treated Powders, And Cosmetics Comprising The Same
  申请人：Nishihama Shuji

  公开号：US20080081029A1

  公开（公告）日：2008-04-03

  To provide surface-treating agents that can provide excellent hydrophobicity to powder and can improve its rinsability, to provide surface-treated powders that are treated with the surface-treating agent, and to provide cosmetics that comprise the surface-treated powder. A surface-treating agent consisting of a polymer which comprises a monomer (A) represented by the general formula (1) described below as a constituent monomer. (wherein R 1 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, R 2 represents an alkylene group having 4 to 22 carbon atoms, X 1 represents an —NH— group or an oxygen atom, and M 1 represents a hydrogen atom or a monovalent inorganic or organic cation.)

  提供能够为粉末提供出色疏水性并改善其可冲洗性的表面处理剂，提供经表面处理剂处理的粉末，以及提供包含经表面处理的粉末的化妆品。一种表面处理剂，由包含下述通用式（1）所描述的单体（A）作为组分单体的聚合物组成。 （其中R1代表氢原子或具有1至3个碳原子的烷基基团，R2代表具有4至22个碳原子的烷基基团，X1代表—NH—基团或氧原子，M1代表氢原子或一价无机或有机阳离子。）
• Fluoride-Releasing Compositions
  申请人：Xu Xiaoming

  公开号：US20120264939A1

  公开（公告）日：2012-10-18

  Chelating monomers and fluoride-releasing compositions are disclosed that may be incorporated into dental composite restorative materials, dental bonding agents or other dental materials, to produce materials with high fluoride release rates, and high fluoride recharge capability. Such dental restorative materials may help reduce the level of dental caries in patients, particularly the level of caries occurring on the margins of the restorative materials.

  本发明公开了可用于制备牙科复合修复材料、牙科粘接剂或其他牙科材料的螯合单体和释放氟化物组合物，以产生具有高氟释放速率和高氟充电能力的材料。这种牙科修复材料可以帮助减少患者的龋齿水平，特别是减少在修复材料边缘发生的龋齿水平。
• Surface-treating agents, surface-treated powders, and cosmetics comprising the same
  申请人：Nishihama Shuji

  公开号：US08753686B2

  公开（公告）日：2014-06-17

  To provide surface-treating agents that can provide excellent hydrophobicity to powder and can improve its rinsability, to provide surface-treated powders that are treated with the surface-treating agent, and to provide cosmetics that comprise the surface-treated powder. A surface-treating agent consisting of a polymer which comprises a monomer (A) represented by the general formula (1) described below as a constituent monomer. (wherein R1 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, R2 represents an alkylene group having 4 to 22 carbon atoms, X1 represents an —NH— group or an oxygen atom, and M1 represents a hydrogen atom or a monovalent inorganic or organic cation.)

  提供能够为粉末提供优异疏水性并改善其冲洗性能的表面处理剂，提供经表面处理剂处理过的粉末，以及包含经表面处理过的粉末的化妆品。该表面处理剂包括聚合物，其中包括以下通式（1）所表示的单体（A）作为组分单体。（其中R1表示氢原子或具有1至3个碳原子的烷基，R2表示具有4至22个碳原子的烷基，X1表示—NH—基或氧原子，M1表示氢原子或一价无机或有机阳离子。）
• Copolymer latex and photographic silver halide materials containing such latex
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0027284A1

  公开（公告）日：1981-04-22

  Latexes suited for homogeneously incorporating compounds with a photographically useful group into photographic silver halide emulsion materials. The latex incorporates a copolymer comprising recurring units of a monomer with photographically useful group, and recurring units of surface active monomer, according to the general formula : wherein: R' is hydrogen or methyl, n is0or1to20, L is R2 is hydrogen or a hydrocarbon group, R3 is a monovalent chemical bond or a bivalent aliphatic hydrocarbon group or such group interrupted by the group -COO- or-CONR-, and Y is a sulpho, sulphato or phosphono group in acid or salt form, and at least one of the groups -(CH2)n-, R2 or R3 is or comprises a hydrocarbon chain of at least 8 C-atoms.

  适用于在照相卤化银乳剂材料中均匀加入具有照相用途基团的化合物的胶乳。这种胶乳包含一种共聚物，该共聚物由具有摄影用途基团的单体的重复单元和表面活性单体的重复单元组成，其通式为 ： 其中 R' 是氢或甲基、 n 为 0 或 1 至 20、 L 是 R2 是氢或烃基、 R3 是一价化学键或二价脂肪族烃基或被基团-COO-或-CONR-打断的此类基团，以及 Y 是酸或盐形式的硫代、硫酸根或磷酰基，且基团-(CH2)n-、R2 或 R3 中至少有一个是或包含至少 8 个 C 原子的烃链。
• SURFACE-TREATING AGENT, SURFACE-TREATED POWDER, AND COSMETIC PREPARATION CONTAINING SAME
  申请人：Shiseido Company, Limited

  公开号：EP1803750A1

  公开（公告）日：2007-07-04

  To provide surface-treating agents that can provide excellent hydrophobicity to powder and can improve its rinsability, to provide surface-treated powders that are treated with the surface-treating agent, and to provide cosmetics that comprise the surface-treated powder. A surface-treating agent consisting of a polymer which comprises a monomer (A) represented by the general formula (1) described below as a constituent monomer. (wherein R1 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, R2 represents an alkylene group having 4 to 22 carbon atoms, X1 represents an -NH- group or an oxygen atom, and M1 represents a hydrogen atom or a monovalent inorganic or organic cation.)

  提供能使粉末具有优异的疏水性并能改善其漂洗性的表面处理剂，提供用该表面处理剂处理过的表面处理过的粉末，以及提供包含该表面处理过的粉末的化妆品。 一种由聚合物组成的表面处理剂，该聚合物由下述通式 (1) 所代表的单体 (A) 作为组成单体。 (其中R1代表氢原子或具有1至3个碳原子的烷基，R2代表具有4至22个碳原子的亚烷基，X1代表-NH-基团或氧原子，M1代表氢原子或一价无机或有机阳离子)。