1H-全氟辛烷 | 335-65-9

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 烃类卤化物
• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1H-全氟辛烷
• 中文别名: 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟辛烷
• 英文名称: 1H-perfluorooctane
• 英文别名: hydroperfluorooctane；1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluorooctane
• CAS: 335-65-9
• 化学式: C₈HF₁₇
• mdl: MFCD00042109
• 分子量: 420.069
• InChiKey: KBHBUUBXEQUIMV-UHFFFAOYSA-N

物化性质

• 沸点：
  118 °C(lit.)
• 密度：
  1.758 g/mL at 25 °C(lit.)
• 闪点：
  >230 °F
• 保留指数：
  395

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  17

安全信息

• 危险等级：
  6.1(b)
• 危险品标志：
  Xi
• 安全说明：
  S26,S37/39
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  29033990
• 危险品运输编号：
  2810
• 包装等级：
  III
• 危险类别：
  6.1(b)
• 储存条件：
  应存放在室温、密封和干燥的环境中。

SDS

1H-全氟辛烷MSDS英文版

反应信息

• 作为反应物：
  描述：

  1H-全氟辛烷 以83的产率得到全氟溴辛烷
  参考文献：
  名称：

  Synthesis of n-perfluorooctyl bromide

  摘要：

  本发明涉及n-全氟辛基溴的制备。根据本发明的连续过程，通过在气相中将溴与1-羟基十七氟-全氟辛烷反应，在450℃至520℃的温度下，在Br.sub.2/C.sub.8 F.sub.17 H摩尔比为0.2至5之间，并在接触时间为2至240秒之间的条件下进行。C.sub.8 F.sub.17 Br的选择性几乎完全，并避免了有毒副产品如全氟异丁烯的生成。

  公开号：

  US05545776A1
• 作为产物：
  描述：

  全氟辛基碘烷 在 二甲基二硫 作用下， 生成 1H-全氟辛烷
  参考文献：
  名称：

  甲基多氟烷基硫化物和多氟链烷磺酸的合成

  摘要：

  通过两种新途径合成的甲基多氟烷基硫化物：（i）多氟碘代烷与二甲基硫醚或二甲基二硫化物的光化学反应，和（ii）多氟碘代烷与甲烷硫醇钠在二甲基二硫化物存在下的反应是多氟链烷磺酸的有用前体。

  DOI：

  10.1039/c39720000249

文献信息

• Absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solution
  作者：David V. Avila、K. U. Ingold、Janusz Lusztyk、W. R. Dolbier、H. Q. Pan、M. Muir

  DOI：10.1021/ja00080a012

  日期：1994.1

  Absolute rate constants have been measured at 298±2 K for some reactions of C 2 F 5 . , n-C 3 F 7 . , n-C 7 F 15 . and n-C 8 F 17 . by time-resolved (laser flash photolysis) and competition kinetics. The last three of these radicals exhibit essentially equal reactivities, but C 2 F 5 . is somewhat more reactive

  对于 C 2 F 5 的某些反应，绝对速率常数已在 298±2 K 下测得。, nC 3 F 7 。, nC 7 F 15 。和nC 8 F 17 。通过时间分辨（激光闪光光解）和竞争动力学。这些自由基中的最后三个表现出基本相同的反应性，但 C 2 F 5 。有点反应性
• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• PHOTOACID GENERATOR, AND RESIN COMPOSITION FOR PHOTOLITHOGRAPHY
  申请人：SAN-APRO LTD.

  公开号：US20160368879A1

  公开（公告）日：2016-12-22

  Provided is a non-ionic photoacid generator (A) expressed by general formula (1). R1 and R2 each independently represents an alkyl group having 1-18 carbons or a fluoroalkyl group having 1-18 carbons, an alkenyl group having 2-18 carbons, an alkynyl group having 2-18 carbons, an aryl group having 6-18 carbons, a silyl group, or the like; m and n respectively represent the number of R1s and R2s, each number being an integer from 0 to 3, and the total number (m+n) of R1s and R2s being an integer from 1 to 6. The m number of R1s and the n number of R2s may each be the same or different. R3 represents a hydrocarbon having 1-18 carbons wherein one part or all of the hydrogen may be substituted by fluorine.

  提供的非离子光酸发生剂（A）由通式（1）表示。R1和R2分别独立表示具有1-18个碳原子的烷基基团或具有1-18个碳原子的氟烷基基团，具有2-18个碳原子的烯基基团，具有2-18个碳原子的炔基基团，具有6-18个碳原子的芳基基团，硅基团等；m和n分别表示R1和R2的数量，每个数字为0到3的整数，R1和R2的总数（m+n）为1到6的整数。R1的数量m和R2的数量n可以相同也可以不同。R3表示具有1-18个碳原子的碳氢化合物，其中氢的一部分或全部可以被氟取代。
• [EN] NITROGEN TITANIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID NITROGEN TITANIUM COMPLEX AND PROCESS FOR THE (CO)POLYMERIZATION OF CONJUGATED DIENES<br/>[FR] COMPLEXE D'AZOTE TITANE, SYSTÈME CATALYTIQUE COMPRENANT LEDIT COMPLEXE D'AZOTE TITANE ET PROCÉDÉ DE (CO)POLYMÉRISATION DE DIÈNES CONJUGUÉS
  申请人：VERSALIS SPA

  公开号：WO2017017203A1

  公开（公告）日：2017-02-02

  Nitrogen titanium complex having general formula (I) or (II), wherein: - R1 represents a hydrogen atom; or is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - R2, R3, R4 and R5, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted, nitro groups, hydroxyl groups, amino groups; - Y represents a NH-R6 group wherein R6 represents a hydrogen atom, or is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or a N-R7 group wherein R7 is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - X1, X 2, X 3 and X 4, identical or different, represent a halogen atom, such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C1 -C20 alkyl groups, preferably C1-C15, -OCOR8 or -OR8 groups wherein R8 is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15; or one of X1, X2 and X3 is selected from ethers, such as,for example, diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably tetrahydrofuran (THF); - n is 1 in the case wherein Y represents a NH-R6 group wherein R6 has the same meanings reported above; or is 0 in the case wherein Y represents a N-R7 group wherein R7 has the same meanings reported above, or in the case wherein one of X1, X2 and X3 is selected from ethers; - R'1, R' 2, R'3, R'4, R'5, R'6 and R'7, identical or different, represent a hydrogen atom; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; - X'1 and X'2, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, -OCOR'8 groups or -OR'8 groups wherein R' 8 is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15; - Y' is selected from ethers such as, for example,diethylether, tetrahydrofuran (THF), dimethoxyethane, preferably is tetrahydrofuran (THF); or Y' represents a group having general formula (III), wherein R'1, R' 2, R'3, R'4, R'5, R'6 and R'7, have the same meanings as reported above; - m is 0 or 1. Said nitrogen titanium complex having general formula (I) or (II) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

  氮钛配合物的一般化学式为(I)或(II)，其中：- R1代表氢原子；或者选自线性或支链的C1-C20烷基，优选C1-C15，可选择卤代，环烷基可选择取代，芳基可选择取代；- R2、R3、R4和R5，相同或不同，代表氢原子；或选自线性或支链的C1-C20烷基，优选C1-C15，可选择卤代，环烷基可选择取代，芳基可选择取代，硝基，羟基，氨基；- Y代表NH-R6基团，其中R6代表氢原子，或选自线性或支链的C1-C20烷基，优选C1-C15，可选择卤代，环烷基可选择取代，芳基可选择取代；或N-R7基团，其中R7选自线性或支链的C1-C20烷基，优选C1-C15，可选择卤代，环烷基可选择取代，芳基可选择取代；- X1、X2、X3和X4，相同或不同，代表卤素原子，例如氯、溴、碘，优选氯；或选自线性或支链的C1-C20烷基，优选C1-C15，-OCOR8或-OR8基团，其中R8选自线性或支链的C1-C20烷基，优选C1-C15；或X1、X2和X3中的一个选自醚类化合物，例如二乙醚、四氢呋喃(THF)、二甲氧基乙烷，优选四氢呋喃(THF)；- n在Y代表NH-R6基团的情况下为1，其中R6具有上述相同含义；或在Y代表N-R7基团的情况下为0，其中R7具有上述相同含义，或在X1、X2和X3中的一个选自醚类化合物的情况下为0；- R'1、R'2、R'3、R'4、R'5、R'6和R'7，相同或不同，代表氢原子；或选自线性或支链的C1-C20烷基，优选C1-C15，可选择卤代，环烷基可选择取代，芳基可选择取代；- X'1和X'2，相同或不同，代表卤素原子，例如氯、溴、碘，优选氯；或选自线性或支链的C1-C20烷基，优选C1-C15，-OCOR'8基团或-OR'8基团，其中R'8选自线性或支链的C1-C20烷基，优选C1-C15；- Y'选自醚类化合物，例如二乙醚、四氢呋喃(THF)、二甲氧基乙烷，优选四氢呋喃(THF)；或Y'代表具有一般化学式(III)的基团，其中R'1、R'2、R'3、R'4、R'5、R'6和R'7具有上述相同含义；- m为0或1。具有一般化学式(I)或(II)的氮钛配合物可优势地用于共轭二烯的催化系统中的(共)聚合。
• Halogen substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20070135594A1

  公开（公告）日：2007-06-14

  A metallocene compound is represented by the formula (1): AMX n-1 wherein M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; A is a substituted monocyclic or polycyclic arenyl ligand pi-bonded to M, wherein said arenyl ligand includes at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.

  一种金属烯化合物可以用公式(1)表示： AMX n-1 其中，M是具有配位数n的过渡金属原子，选自元素周期表第3、4、5或6族，或为镧系金属原子，或锕系金属原子；A是与M以π键结合的取代的单环或多元环芳基配体，其中所述芳基配体包括至少一个直接键合到配体的可键合环位上的任意sp2碳原子上的卤素取代基；而X是单价阴离子配体，或者两个X连接并与金属原子结合形成一个金属环烯环，或者两个X连接形成一个螯合配体、二烯配体或烷基亚烯配体。