6,6-Bis(4-dimethylaminophenyl)-6H-chromeno<4,3-b>indol | 65694-76-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 异黄酮类化合物
• 英文名称: 6,6-Bis(4-dimethylaminophenyl)-6H-chromeno<4,3-b>indol
• 英文别名: 6,6-bis-(4-dimethylaminophenyl)-6H-chromeno[4,3-b]-indole；6,6-Bis(p-dimethylaminophenyl)-6,11-dihydro-[1]benzopyrano[4,3-b]indole；4-[6-[4-(dimethylamino)phenyl]-11H-chromeno[4,3-b]indol-6-yl]-N,N-dimethylaniline
• CAS: 65694-76-0
• 化学式: C₃₁H₂₉N₃O
• 分子量: 459.591
• InChiKey: FSQITWGNFVSCPA-UHFFFAOYSA-N

物化性质

• 熔点：
  147-151 °C(Solv: methanol (67-56-1))
• 沸点：
  664.4±55.0 °C(Predicted)
• 密度：
  1.234±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  31.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6,6-Bis(4-dimethylaminophenyl)-6H-chromeno<4,3-b>indol 在 氢氧化钾 、 sodium perchlorate 、 溶剂黄146 作用下， 以 水 、 甲苯 为溶剂， 反应 1.0h， 生成 Bis(4-dimethylaminophenyl)-<1-methyl-2-(2-hydroxyphenyl)-indol-3-yl>carbeniumperchlorat
  参考文献：
  名称：

  卤化铬Molekeln 2.合成[1]合成和酸基酯Verhalten取代基6,6-二苯基-6 H -chromeno [4,3- b ]吲哚

  摘要：

  取代的6,6-二苯基-6 H-苯并[4,3- b ]吲哚的盐变色分子，合成与酸化行为

  DOI：

  10.1002/hlca.19800630518
• 作为产物：
  描述：

  2-(1H-indol-2-yl)phenol 、 米氏酮 在 三氯氧磷 作用下， 以63%的产率得到6,6-Bis(4-dimethylaminophenyl)-6H-chromeno<4,3-b>indol
  参考文献：
  名称：

  卤化铬Molekeln 2.合成[1]合成和酸基酯Verhalten取代基6,6-二苯基-6 H -chromeno [4,3- b ]吲哚

  摘要：

  取代的6,6-二苯基-6 H-苯并[4,3- b ]吲哚的盐变色分子，合成与酸化行为

  DOI：

  10.1002/hlca.19800630518

文献信息

• Recording materials containing chromenoindoles
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04220356A1

  公开（公告）日：1980-09-02

  A chromenoindole derivative of the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group, an alkyl group substituted with one or more of a cyano group, a halogen atom or an alkoxy group, an aralkyl group, a phenyl group or a phenyl group substituted with one or more of an alkyl group or a halogen atom; X represents a hydrogen atom, an alkoxy group, a dialkylamino group, an alkylarylamino group, an alkylaralkylamino group, a diaralkylamino group, an acylamino group, a halogen atom or an alkyl group; Y represents a hydrogen atom, an alkyl group, a halogen atom, an alkoxy group of a nitro group; Z represents an acyl group, or a sulfonyl group; Q.sub.1 and Q.sub.2, which may be the same or different, each represents a hydrogen atom, a lower alkyl group or a halogen atom; and A.sub.1, A.sub.2, A.sub.3 and A.sub.4, which may be the same or different, each represents a halogen atom, an alkyl group or an alkoxy group; which upon contact with an electron acceptor material forms a color with superior light fastness and which is useful as a color former in various recording materials such as pressure-sensitive recording sheets, thermosensitive recording sheets, electrothermosensitive recording sheets, and photosensitive recording sheets.

  以下是通式（I）的一种色诱导体，其中R1和R2，可以相同也可以不同，分别代表烷基，被一个或多个氰基，卤素原子或烷氧基取代的烷基，芳基烷基，苯基或被一个或多个烷基或卤素原子取代的苯基;X代表氢原子，烷氧基，二烷基氨基，烷基芳基氨基，烷基芳基烷基氨基，二芳基氨基，酰胺基，卤素原子或烷基;Y代表氢原子，烷基，卤素原子，烷氧基或硝基;Z代表酰基或磺酰基;Q1和Q2，可以相同也可以不同，分别代表氢原子，低烷基或卤素原子;A1，A2，A3和A4，可以相同也可以不同，分别代表卤素原子，烷基或烷氧基;该色诱导体在与电子受体材料接触时形成具有优异耐光性的颜色，并且可用作各种记录材料中的颜色形成剂，如压敏记录纸，热敏记录纸，电热敏记录纸和光敏记录纸。
• Method of treating hair with heat and a cap which provides a signal regarding treatment
  申请人：Unilever Home & Personal Care USA, Division of Conopco, Inc.

  公开号：US20030059459A1

  公开（公告）日：2003-03-27

  A hair covering which comprises a woven or nonwoven substrate comprising synthetic or natural materials, which are impregnated, or coated, or both, with a mutable dye is described.

  本文描述了一种发套，它包括由合成材料或天然材料组成的编织基材或无纺基材，基材上浸渍或涂覆或同时浸渍或涂覆有可变异染料。
• GUNZENHAUSER S.; BALLI H., HELV. CHIM. ACTA, 1980, 63, NO 5, 1264-1283
  作者：GUNZENHAUSER S.、 BALLI H.

  DOI：——

  日期：——
• Silicone Baby Products
  申请人：YEUNG Hin Shing

  公开号：US20090108009A1

  公开（公告）日：2009-04-30

  The invention relates to silicone baby products such as bottles, feeding bottles, bottle holders, and pacifiers. The silicone baby products may optionally comprise a temperature indicator.
• Thermochromic Baby Bottle and Method of Using the Same
  申请人：Quintero Susana

  公开号：US20190298616A1

  公开（公告）日：2019-10-03

  A thermochromatic baby bottle for receiving and dispensing fluids to infants and babies along with a method of use comprises a bottle, a collar, a nipple, a cap, a ribbed sleeve, and a wings handle, any or all of which may have one or more thermochromic elements disposed on, in, or attached to them. A thermometer outline on the side of the bottle, a thermochromatic sticker, one or more raised thermochromic portions of the bottle shaped as rings encircling the bottle, or hidden shapes that become visible when one or more thermochromic elements are engaged, are all non-limiting examples of the one or more thermochromic elements. The bottle may have one or more narrow or graduated portions, one or more non-thermochromic design elements, or any other ornamentation may be disposed on the bottle's exterior as well.