(3-Bromophenyl)di(propan-2-yl)phosphane | 651330-02-8

• 物质功能分类: 有机原料 - 有机膦化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-Bromophenyl)di(propan-2-yl)phosphane
• 英文别名: (3-bromophenyl)-di(propan-2-yl)phosphane
• CAS: 651330-02-8
• 化学式: C₁₂H₁₈BrP
• 分子量: 273.153
• InChiKey: DTDBNXJWBHYYCB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 (3-Bromophenyl)di(propan-2-yl)phosphane 、 三苯基硼烷 、 四丁基溴化铵 、 叔丁基锂 以 四氢呋喃 为溶剂， 生成 [3-di(propan-2-yl)phosphanylphenyl]-triphenylboranuide;tetrabutylazanium
  参考文献：
  名称：

  Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis

  摘要：

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.

  DOI：

  10.1021/ic0350234

文献信息

• Organic Semiconductive Layer Comprising Phosphine Oxide Compounds
  申请人：Novaled GmbH

  公开号：US20180337339A1

  公开（公告）日：2018-11-22

  The present invention relates to an. organic semiconductive layer which is an electron transport layer and/or an electron injection layer and/or an n-type charge generation layer, the organic semiconductive layer comprising at least one compound of formula (1) wherein R 1 and R 2 are each independently selected from C 1 to C 16 alkyl; Ar 1 is selected from C 6 to C 14 arylene or C 3 to C 12 heteroarylene; Ar 2 is independently selected from C 14 to C 40 arylene or C 8 to C 40 heteroarylene; R 3 is independently selected from H, C 1 to C 12 alkyl or C 10 to C 20 aryl; wherein each of Ar 1 , Ar 2 and R 3 may each independently be unsubstituted or substituted with at least one C 1 to C 12 alky group; n is 0 or 1; and m is 1 in case of n=0; and m is 1 or 2 in case of n=1, phosphine oxide compounds comprised therein and to organic electroluminescent devices comprising such layers and compounds.
• Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis
  作者：Christine M. Thomas、Jonas C. Peters

  DOI：10.1021/ic0350234

  日期：2004.1.1

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.