(3aR,3'aS,4R,6'S,7R,7'R,7aS,7'aR)-6'-[(2S,3S,4R,5R,6R)-5-[tert-butyl(dimethyl)silyl]oxy-3-methoxy-6-(methoxymethyl)-4-phenylmethoxyoxan-2-yl]oxy-7'-phenylmethoxyspiro[3a,6,7,7a-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4,2'-4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7-ol | 256342-21-9

分子结构分类

有机化合物 - 有机氧化合物

中文名称

——

中文别名

——

英文名称

(3aR,3'aS,4R,6'S,7R,7'R,7aS,7'aR)-6'-[(2S,3S,4R,5R,6R)-5-[tert-butyl(dimethyl)silyl]oxy-3-methoxy-6-(methoxymethyl)-4-phenylmethoxyoxan-2-yl]oxy-7'-phenylmethoxyspiro[3a,6,7,7a-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4,2'-4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7-ol

英文别名

——

(3aR,3'aS,4R,6'S,7R,7'R,7aS,7'aR)-6'-[(2S,3S,4R,5R,6R)-5-[tert-butyl(dimethyl)silyl]oxy-3-methoxy-6-(methoxymethyl)-4-phenylmethoxyoxan-2-yl]oxy-7'-phenylmethoxyspiro[3a,6,7,7a-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4,2'-4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran]-7-ol化学式

CAS

256342-21-9

化学式

C₃₉H₅₆O₁₄Si

mdl

——

分子量

776.951

InChiKey

YEFRQINVGUMETM-PTPJCIHISA-N

BEILSTEIN

——

EINECS

——

物化性质

沸点：

779.7±60.0 °C(Predicted)
密度：

1.27±0.1 g/cm3(Predicted)

计算性质

辛醇/水分配系数(LogP)：

3.88
重原子数：

54
可旋转键数：

14
环数：

7.0
sp3杂化的碳原子比例：

0.69
拓扑面积：

140
氢给体数：

1
氢受体数：

14

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	(2R,3'R,3aS,4'R,5'R,6S,7R,7aR)-6-[(2S,3S,4R,5R,6R)-5-[tert-butyl(dimethyl)silyl]oxy-3-methoxy-6-(methoxymethyl)-4-phenylmethoxyoxan-2-yl]oxy-5'-[(4-methoxyphenyl)methoxy]-7-phenylmethoxyspiro[4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-2,2'-oxane]-3',4'-diol	256342-18-4	C₄₆H₆₄O₁₅Si	885.091
——	[(2R,3R,4R,5S,6S)-6-[(2R,3aS,4'R,5'R,6S,7R,7aR)-4'-[tert-butyl(dimethyl)silyl]oxy-5'-[(4-methoxyphenyl)methoxy]-7-phenylmethoxyspiro[4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-2,2'-oxane]-6-yl]oxy-5-methoxy-2-(methoxymethyl)-4-phenylmethoxyoxan-3-yl]oxy-tri(propan-2-yl)silane	256342-09-3	C₅₅H₈₄O₁₄Si₂	1025.43
——	(2R,3R,4S,5S,6S)-6-[(2R,3aS,4'R,5'R,6S,7R,7aR)-4'-[tert-butyl(dimethyl)silyl]oxy-5'-[(4-methoxyphenyl)methoxy]-7-phenylmethoxyspiro[4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-2,2'-oxane]-6-yl]oxy-5-methoxy-2-(methoxymethyl)-4-phenylmethoxyoxan-3-ol	256342-10-6	C₄₆H₆₄O₁₄Si	869.091
——	[(2R,3'S,3aS,4'R,5'R,6S,7R,7aR)-6-[(2S,3S,4R,5R,6R)-5-[tert-butyl(dimethyl)silyl]oxy-3-methoxy-6-(methoxymethyl)-4-phenylmethoxyoxan-2-yl]oxy-3'-hydroxy-5'-[(4-methoxyphenyl)methoxy]-7-phenylmethoxyspiro[4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-2,2'-oxane]-4'-yl] benzoate	256342-16-2	C₅₃H₆₈O₁₆Si	989.199
——	[(2R,3R,4R,5S,6S)-5-methoxy-2-(methoxymethyl)-4-phenylmethoxy-6-[(2S,3R,4R,5S)-3-phenylmethoxy-4,5-bis(prop-2-enoxy)oxan-2-yl]oxyoxan-3-yl]oxy-tri(propan-2-yl)silane	256342-05-9	C₄₂H₆₄O₁₀Si	757.05
——	[(2R,3R,4S,5S,6S)-6-[(2R,3aS,4'R,5'R,6S,7R,7aR)-4'-[tert-butyl(dimethyl)silyl]oxy-5'-[(4-methoxyphenyl)methoxy]-7-phenylmethoxyspiro[4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-2,2'-oxane]-6-yl]oxy-5-methoxy-2-(methoxymethyl)-4-phenylmethoxyoxan-3-yl] benzoate	256342-11-7	C₅₃H₆₈O₁₅Si	973.199
——	[(2S,3R,4R,5S)-5-hydroxy-2-[(2S,3S,4R,5R,6R)-3-methoxy-6-(methoxymethyl)-4-phenylmethoxy-5-tri(propan-2-yl)silyloxyoxan-2-yl]oxy-3-phenylmethoxyoxan-4-yl] 2-chloroacetate	256342-06-0	C₃₈H₅₇ClO₁₁Si	753.402
——	[(3S,4R,5R,6S)-4-hydroxy-6-[(2S,3S,4R,5R,6R)-3-methoxy-6-(methoxymethyl)-4-phenylmethoxy-5-tri(propan-2-yl)silyloxyoxan-2-yl]oxy-5-phenylmethoxyoxan-3-yl] 2-chloroacetate	256342-29-7	C₃₈H₅₇ClO₁₁Si	753.402
——	(2S,3R,4R,5S)-5-[(2R,3S,4S,5R)-4-[tert-butyl(dimethyl)silyl]oxy-5-[(4-methoxyphenyl)methoxy]-3-phenylselanyloxan-2-yl]oxy-2-[(2S,3S,4R,5R,6R)-3-methoxy-6-(methoxymethyl)-4-phenylmethoxy-5-tri(propan-2-yl)silyloxyoxan-2-yl]oxy-3-phenylmethoxyoxan-4-ol	256342-08-2	C₆₁H₉₀O₁₄SeSi₂	1182.51
——	(2R,3R,4S,5S,6S)-6-[(3S,3'aS,6R,6'S,7'R,7'aR)-3-[(4-methoxyphenyl)methoxy]-7'-phenylmethoxyspiro[2,3-dihydropyran-6,2'-4,6,7,7a-tetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran]-6'-yl]oxy-5-methoxy-2-(methoxymethyl)-4-phenylmethoxyoxan-3-ol	256342-13-9	C₄₀H₄₈O₁₃	736.813
——	[(2S,3R,4R,5S)-5-[(2R,3S,4S,5R)-4-[tert-butyl(dimethyl)silyl]oxy-5-[(4-methoxyphenyl)methoxy]-3-phenylselanyloxan-2-yl]oxy-2-[(2S,3S,4R,5R,6R)-3-methoxy-6-(methoxymethyl)-4-phenylmethoxy-5-tri(propan-2-yl)silyloxyoxan-2-yl]oxy-3-phenylmethoxyoxan-4-yl] 2-chloroacetate	256342-07-1	C₆₃H₉₁ClO₁₅SeSi₂	1258.99
——	(2S,3R,4S,5S)-2-[(2S,3S,4S,5R,6R)-3-methoxy-6-(methoxymethyl)-5-[(4-methoxyphenyl)methoxy]-4-phenylmethoxyoxan-2-yl]oxy-4,5-bis(prop-2-enoxy)oxan-3-ol	256342-03-7	C₃₄H₄₆O₁₁	630.733
——	(2S,3R,4R,5S)-5-[(2R,3S,4S,5R)-4-[tert-butyl(dimethyl)silyl]oxy-5-[(4-methoxyphenyl)methoxy]-3-phenylseleninyloxan-2-yl]oxy-2-[(2S,3S,4R,5R,6R)-3-methoxy-6-(methoxymethyl)-4-phenylmethoxy-5-tri(propan-2-yl)silyloxyoxan-2-yl]oxy-3-phenylmethoxyoxan-4-ol	1053712-31-4	C₆₁H₉₀O₁₅SeSi₂	1198.51
——	(2R,3S,4R,5R,6R)-4-Benzyloxy-5-(4-methoxy-benzyloxy)-6-methoxymethyl-tetrahydro-pyran-2,3-diol	256341-93-2	C₂₂H₂₈O₇	404.46
——	[(3R,4R,5S)-4,5-bis(prop-2-enoxy)-2-(2,2,2-trichloroethanimidoyl)oxyoxan-3-yl] benzoate	256341-87-4