1-N,2-N-bis[3-(4-nitrophenyl)chromen-2-ylidene]benzene-1,2-dicarboxamide | 1367368-31-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 异黄酮类化合物
• 英文名称: 1-N,2-N-bis[3-(4-nitrophenyl)chromen-2-ylidene]benzene-1,2-dicarboxamide
• CAS: 1367368-31-7
• 化学式: C₃₈H₂₂N₄O₈
• 分子量: 662.615
• InChiKey: POVVWPKQRCTXNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  50
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  169
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  对硝基苯乙腈 在 吡啶 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 16.0h， 生成 1-N,2-N-bis[3-(4-nitrophenyl)chromen-2-ylidene]benzene-1,2-dicarboxamide
  参考文献：
  名称：

  Novel Synthesis of Bis-Iminocoumarins

  摘要：

  Reaction of 3-aryl iminocoumarins with diacid chlorides as C-electrophilic reagents under mild conditions novel bis-iminocoumarins in good yields. When the reaction was performed with alkylene dibromides by heating them in toluene in the presence of IRA 900 resin, bis-ether compounds were obtained by way opening the pyranic ring. The structures of the product obtained were characterized by Fourier transform infrared, H-1 NMR, C-13 NMR, and elemental analysis.

  DOI：

  10.1080/00397911.2010.531370

文献信息

• Novel Synthesis of Bis-Iminocoumarins
  作者：H. Ammar、S. Abid、Y. Le Bigot、R. El Gharbi

  DOI：10.1080/00397911.2010.531370

  日期：2012.3.15

  Reaction of 3-aryl iminocoumarins with diacid chlorides as C-electrophilic reagents under mild conditions novel bis-iminocoumarins in good yields. When the reaction was performed with alkylene dibromides by heating them in toluene in the presence of IRA 900 resin, bis-ether compounds were obtained by way opening the pyranic ring. The structures of the product obtained were characterized by Fourier transform infrared, H-1 NMR, C-13 NMR, and elemental analysis.