2-Tert-butyl-9,10-dinaphthalen-2-ylanthracene-9,10-diol | 920979-25-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-Tert-butyl-9,10-dinaphthalen-2-ylanthracene-9,10-diol
• 英文别名: 2-tert-butyl-9,10-dinaphthalen-2-ylanthracene-9,10-diol
• CAS: 920979-25-5
• 化学式: C₃₈H₃₂O₂
• 分子量: 520.671
• InChiKey: GZVLFBSMFKTIHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  40
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Tert-butyl-9,10-dinaphthalen-2-ylanthracene-9,10-diol 在 溶剂黄146 、 tin(ll) chloride 作用下， 反应 3.0h， 以1.7 g的产率得到3-叔丁基-9,10-二(2-萘)蒽
  参考文献：
  名称：

  Efficient blue organic light-emitting devices based on novel anthracence derivatives with pronounced thermal stability and excellent film-forming property

  摘要：

  A series of anthracene based blue host materials was synthesized and characterized with respect to their chemical, luminescence, film-forming and thermal properties. The anthracene derivatives are strongly blue fluorescent (lambda(f) = 435-445 nm) with high fluorescence quantum yields (Phi(f) = 0.71-0.85). All of these compounds have excellent film-forming properties and thermal properties. Organic light-emitting devices (OLEDs) fabricated using these three compounds as blue host emitter and using 0.5-wt% tetra (t-butyl) perylene (TBPe) dopant in the emitting layer exhibit good light emitting performance with bright blue emission. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2006.08.086
• 作为产物：
  描述：

  2-溴萘 、 2-叔丁基蒽醌 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 2.0h， 生成 2-Tert-butyl-9,10-dinaphthalen-2-ylanthracene-9,10-diol
  参考文献：
  名称：

  Efficient blue organic light-emitting devices based on novel anthracence derivatives with pronounced thermal stability and excellent film-forming property

  摘要：

  A series of anthracene based blue host materials was synthesized and characterized with respect to their chemical, luminescence, film-forming and thermal properties. The anthracene derivatives are strongly blue fluorescent (lambda(f) = 435-445 nm) with high fluorescence quantum yields (Phi(f) = 0.71-0.85). All of these compounds have excellent film-forming properties and thermal properties. Organic light-emitting devices (OLEDs) fabricated using these three compounds as blue host emitter and using 0.5-wt% tetra (t-butyl) perylene (TBPe) dopant in the emitting layer exhibit good light emitting performance with bright blue emission. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2006.08.086

文献信息

• Synthesis process
  申请人：Coggan A. Jennifer

  公开号：US20070020481A1

  公开（公告）日：2007-01-25

  A process for preparing a substituted or unsubstituted 9,10-diarylanthracene including reacting an organometallic substituted or unsubstituted aryl compound with a substituted or unsubstituted anthraquinone to yield a substituted or unsubstituted diol; and reacting the substituted or unsubstituted diol with a reducing agent to yield the substituted or unsubstituted 9,10-diarylanthracene is disclosed. An electroluminescent device comprising a light-emitting layer comprising the substituted or unsubstituted 9,10-diarylanthracene is also disclosed.

  本发明公开了一种制备取代或未取代的9,10-二芳基蒽的方法，包括将有机金属取代或未取代的芳基化合物与取代或未取代的蒽醌反应，得到取代或未取代的二醇；将取代或未取代的二醇与还原剂反应，得到取代或未取代的9,10-二芳基蒽。本发明还公开了一种包括含有取代或未取代的9,10-二芳基蒽的发光层的电致发光装置。
• US8766023B2
  申请人：——

  公开号：US8766023B2

  公开（公告）日：2014-07-01
• Efficient blue organic light-emitting devices based on novel anthracence derivatives with pronounced thermal stability and excellent film-forming property
  作者：Silu Tao、Shandong Xu、Xiaohong Zhang

  DOI：10.1016/j.cplett.2006.08.086

  日期：2006.10

  A series of anthracene based blue host materials was synthesized and characterized with respect to their chemical, luminescence, film-forming and thermal properties. The anthracene derivatives are strongly blue fluorescent (lambda(f) = 435-445 nm) with high fluorescence quantum yields (Phi(f) = 0.71-0.85). All of these compounds have excellent film-forming properties and thermal properties. Organic light-emitting devices (OLEDs) fabricated using these three compounds as blue host emitter and using 0.5-wt% tetra (t-butyl) perylene (TBPe) dopant in the emitting layer exhibit good light emitting performance with bright blue emission. (c) 2006 Elsevier B.V. All rights reserved.