1-acetoxy-2,3-bis-(p-methoxyphenyl)-cyclopentane | 144074-89-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮
• 英文名称: 1-acetoxy-2,3-bis-(p-methoxyphenyl)-cyclopentane
• CAS: 144074-89-5
• 化学式: C₂₁H₂₄O₄
• 分子量: 340.419
• InChiKey: DJERSCNAMAMFJM-UHFFFAOYSA-N

物化性质

• 沸点：
  451.2±45.0 °C(Predicted)
• 密度：
  1.15±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  25.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  44.76
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  2,3-bis-(p-methoxyphenyl)-2-cyclopentene-1-one 在 palladium on activated charcoal 吡啶 、 氢气 作用下， 以 乙醇 为溶剂， 生成 1-acetoxy-2,3-bis-(p-methoxyphenyl)-cyclopentane
  参考文献：
  名称：

  Norlignan from the knot resin of Araucaria angustifolia

  摘要：

  A new norlignan, 2,3-bis-(p-hydroxyphenyl)-2-cyclopentene-1-one, was isolated from the knot resin powder of Araucaria angustifolia. The structure was elucidated by spectroscopic chemical analyses. In addition 4,4'-dihydroxychalcone, cryptoresinol (norlignan), four known lignans and one known norlignan, were isolated for the first time from the resin. A qualitative and quantitative comparison of these compounds in knot, heartwood and sapwood of A. angustifolia was performed from the viewpoint of plant chemistry. Detectable amounts of the new compound were present in both knot and heartwood.

  DOI：

  10.1016/0031-9422(92)80293-n