1-碘-2-己基癸烷 | 1044598-79-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 中文名称: 1-碘-2-己基癸烷
• 英文名称: 1-iodo-2-hexyldecane
• 英文别名: 2-hexyldecyl iodide；7-(iodomethyl)pentadecane
• CAS: 1044598-79-9
• 化学式: C₁₆H₃₃I
• 分子量: 352.343
• InChiKey: ISRPCLCPFYVEHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  17
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  1-碘-2-己基癸烷 在 一氯化碘 、 potassium carbonate 、 potassium iodide 作用下， 以 甲醇 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Arm Dissociation in Molecular Stars with a Spoked Wheel Core and Bottlebrush Arms

  摘要：

  Unique star-like polymeric architectures composed of bottlebrush arms and a molecular spoked wheel (MSW) core were prepared by atom transfer radical polymerization (ATRP). A hexahydroxy-functionalized MSW (MSW(6-OH)) was synthesized and converted into a six-fold ATRP initiator (MSW(6-Br)). Linear chain arms were grafted from MSW(6-Br) and subsequently functionalized with ATRP moieties to form six-arm macroinitiators. Grafting of side chains from the macroinitiators yielded four different star-shaped bottlebrushes with varying lengths of arms and side chains, i.e., (450-g-20)6, (450-g-40)6, (300-g-60)6, and (300-g-150)6. Gel permeation chromatography analysis and molecular imaging by atomic force microscopy confirmed the formation of well-defined macromolecules with narrow molecular weight distributions. Upon adsorption to an aqueous substrate, the bottlebrush arms underwent prompt dissociation from the MSW core, followed by scission of covalent bonds in the bottlebrush backbones. The preferential cleavage of the arms is attributed to strong steric repulsion between bottlebrushes at the MSW branching center. Star-shaped macroinitiators may undergo aggregation which can be prevented by sonication.

  DOI：

  10.1021/ja506780y
• 作为产物：
  描述：

  2-己基癸醇 在 咪唑 、 碘 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到1-碘-2-己基癸烷
  参考文献：
  名称：

  Synthesis and Arm Dissociation in Molecular Stars with a Spoked Wheel Core and Bottlebrush Arms

  摘要：

  Unique star-like polymeric architectures composed of bottlebrush arms and a molecular spoked wheel (MSW) core were prepared by atom transfer radical polymerization (ATRP). A hexahydroxy-functionalized MSW (MSW(6-OH)) was synthesized and converted into a six-fold ATRP initiator (MSW(6-Br)). Linear chain arms were grafted from MSW(6-Br) and subsequently functionalized with ATRP moieties to form six-arm macroinitiators. Grafting of side chains from the macroinitiators yielded four different star-shaped bottlebrushes with varying lengths of arms and side chains, i.e., (450-g-20)6, (450-g-40)6, (300-g-60)6, and (300-g-150)6. Gel permeation chromatography analysis and molecular imaging by atomic force microscopy confirmed the formation of well-defined macromolecules with narrow molecular weight distributions. Upon adsorption to an aqueous substrate, the bottlebrush arms underwent prompt dissociation from the MSW core, followed by scission of covalent bonds in the bottlebrush backbones. The preferential cleavage of the arms is attributed to strong steric repulsion between bottlebrushes at the MSW branching center. Star-shaped macroinitiators may undergo aggregation which can be prevented by sonication.

  DOI：

  10.1021/ja506780y

文献信息

• NON-FULLERENE ACCEPTOR COMPOUND CONTAINING BENZOSELENADIAZOLE AND ORGANIC OPTOELECTRONIC DEVICE INCLUDING THE SAME
  申请人：RAYNERGY TEK INCORPORATION

  公开号：US20210230130A1

  公开（公告）日：2021-07-29

  The present invention relates to a non-fullerene acceptor compound containing benzoselenadiazole, and organic optoelectronic devices comprising the same.

  这项发明涉及一种含苯硒二唑的非富勒烯受体化合物，以及包括该化合物的有机光电子器件。
• Asymmetric Isomer Effects in Benzo[ <i>c</i>  ][1,2,5]thiadiazole‐Fused Nonacyclic Acceptors: Dielectric Constant and Molecular Crystallinity Control for Significant Photovoltaic Performance Enhancement
  作者：Wei Gao、Baobing Fan、Feng Qi、Francis Lin、Rui Sun、Xinxin Xia、Jinhua Gao、Cheng Zhong、Xinhui Lu、Jie Min、Fujun Zhang、Zonglong Zhu、Jingdong Luo、Alex K.‐Y. Jen

  DOI：10.1002/adfm.202104369

  日期：2021.9

  Moreover, the weaker crystallization behavior enables a significantly enhanced miscibility between PM6 and ABP6T-4F than that between PM6 and BP6T-4F, which leads to an optimized micromorphology with smooth surface, suitable domain size, and ordered π–π stacking. Organic solar cells (OSCs) based on PM6:ABP6T-4F achieve a 15.8% power conversion efficiency (PCE), which is remarkably higher than that of

  本文通过设计合成二苯并[ c]系统地探索了不对称异构体效应。][1,2,5] 噻二唑 (BT) 稠合非环电子受体。通过将 BP6T-4F 改为不对称 ABP6T-4F，可以显着提高介电常数并抑制过度分子聚集和不利的边缘取向。与具有相同能量偏移的 PM6:BP6T-4F 相比，降低的激子结合能也促进了 PM6:ABP6T-4F 中更有效的解离过程。此外，较弱的结晶行为使得 PM6 和 ABP6T-4F 之间的混溶性比 PM6 和 BP6T-4F 之间的混溶性显着提高，从而导致具有光滑表面、合适的域尺寸和有序 π-π 堆积的优化微形态。基于 PM6:ABP6T-4F 的有机太阳能电池 (OSC) 实现了 15.8% 的功率转换效率 (PCE)，明显高于基于 PM6:BP6T-4F 的 OSC (6.4%)。此外，考虑到 ABP6T-4F 和 CH1007 之间的良好兼容性，还制造了三元器件，以提供超过
• Cobalt-Catalyzed Reductive Alkylation of Heteroaryl Bromides: One-Pot Access to Alkylthiophenes, -furans, -selenophenes, and -pyrroles
  作者：Deng-Jhou Cai、Po-Han Lin、Ching-Yuan Liu

  DOI：10.1002/ejoc.201500784

  日期：2015.8

  A practical and convenient Co-catalyzed alkylation method for the facile introduction of various alkyl chains into organic electronically significant heteroaryl compounds, including thiophenes, furans, selenophenes, and pyrroles, is reported. Under well-optimized reaction conditions, a wide range of alkylated heteroaryl compounds have beeen efficiently prepared in moderate to good isolated yields.

  报道了一种实用且方便的共催化烷基化方法，可将各种烷基链轻松引入具有电子意义的有机杂芳基化合物，包括噻吩、呋喃、硒吩和吡咯。在充分优化的反应条件下，广泛的烷基化杂芳基化合物已以中等至良好的分离产率有效制备。值得注意的是，在聚合物化学和有机材料中起决定性作用的 2- 或 3- 烷基噻吩首次通过这种使用廉价钴盐作为催化剂的还原偶联方法逐步经济地合成。这种简单的合成过程避免了传统烷基化方案所需的水分不稳定有机金属试剂（RMgX 或 RZnX）的制备。
• 非富勒烯电子受体材料与有机光伏电池
  申请人：位速科技股份有限公司

  公开号：CN112390813B

  公开（公告）日：2022-06-03

  一种如式(I)所示的非富勒烯电子受体材料与一种其有源层包括前述非富勒烯电子受体材料的有机光伏电池。以本发明的非富勒烯电子受体材料作为电子受体时，能有效提升有机光伏电池的能量转换效率(PCE)。
• Regioisomeric π-conjugated terpolymers bearing carboxylate substituted thienothiophenyl quarterthiophene and their application to fullerene-free polymer solar cells
  作者：Chang Geun Park、Gi Eun Park、Ji Hyung Lee、Aesun Kim、Young Un Kim、Seo Yeon Park、Su Hong Park、Min Ju Cho、Dong Hoon Choi

  DOI：10.1016/j.polymer.2018.05.027

  日期：2018.6

  Two regioisomeric π-conjugated terpolymers bearing carboxylated thiophene (CT) as electron accepting unit and thienothiophene (TT) and bithiophene (BT) as electron donating units were successfully synthesized for enhancing the performance of polymer solar cells (PSCs). Regio-regular and regio-random binary copolymers based on CT and BT were also prepared as control polymers. All polymers showed unique

  为了增强聚合物太阳能电池（PSCs）的性能，成功地合成了两种以羧化噻吩（CT）为电子接受单元和硫代噻吩（TT）和联噻吩（BT）为电子给体的区域异构π共轭三元共聚物。还制备了基于CT和BT的区域规则的和区域随机的二元共聚物作为对照聚合物。所有聚合物均表现出独特的光学性质和结晶行为。在本研究中制造的PSC器件中，基于区域随机三元共聚物（Ran-TT）和3,9-双（2-亚甲基-（3-（1,1-二氰基亚甲基）-茚满酮））-5的PSC ，5,11,11-四（4-己基苯基）二噻吩并[2,3-d：2'，3'- d ']- s-indaceno [1,2-b：5,6b']-二噻吩（ITIC）的最高功率转换效率为5.65％，具有12.63 mA cm -2的高短路电流密度（J sc）和开路电压（V oc）为0.81V。有希望的PCE值归因于Ran-TT的低位最高占据分子轨道（HOMO），有效的互补吸收光谱和