di-n-butylstannyl bis[3-amino-4-chlorophenylcarboxylate] | 1306700-55-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di-n-butylstannyl bis[3-amino-4-chlorophenylcarboxylate]
• CAS: 1306700-55-9
• 化学式: C₂₂H₂₈Cl₂N₂O₄Sn
• 分子量: 574.091
• InChiKey: MKHKDXYAJRPSGL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-氨基-4-氯苯甲酸 、 二正丁基氧化锡 以84%的产率得到di-n-butylstannyl bis[3-amino-4-chlorophenylcarboxylate]
  参考文献：
  名称：

  Self-assembled pentagonal bipyramidal and skew trapezoidal organotin(IV) complexes of substituted benzoic acids: Their antibacterial, antifungal, cytotoxic, insecticidal and urease inhibition activities

  摘要：

  Fourteen di- and triorganotin(IV) derivatives with pentagonal bipyramidal and skew trapezoidal geometries have been synthesized and characterized. Dimethylstannyl bis[3-amino-4-chlorophenylcarboxylate] (1), bis[3-amino-4-chlorophenylcarboxylato] tetraethyldistannoxane] (2) and bis[3,5-dinitro-4-chlorophenylcarboxylato] tetra-n-butyldistannoxane (10) are dinuclear and tetranuclear complexes of bidentate ligands. The crystal structure of (1) is dimeric in which each Sn atom is seven coordinated. Study of weak intramolecular Sn center dot center dot center dot O interactions is very important to decide geometry around tin. Furthermore, it has been investigated that these compounds exhibit fairly good antibacterial, antifungal, cytotoxic, insecticidal and antiurease activities. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.007