6a,12a-dehydrosumatrol

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 异黄酮类化合物
• 英文名称: 6a,12a-dehydrosumatrol
• 英文别名: 6a,12-Didehydrosumatrol；10-hydroxy-16,17-dimethoxy-6-prop-1-en-2-yl-2,7,20-trioxapentacyclo[11.8.0.03,11.04,8.014,19]henicosa-1(13),3(11),4(8),9,14,16,18-heptaen-12-one
• 化学式: C₂₃H₂₀O₇
• 分子量: 408.408
• InChiKey: STFNGWNFASVBRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  83.4
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  6a,12a-dehydrosumatrol 在 selenium(IV) oxide 、 溶剂黄146 、 silver(l) oxide 作用下， 以 丙酮 为溶剂， 反应 4.0h， 生成 Villinol
  参考文献：
  名称：

  来自长毛毛茛的脱氢-6-羟基类胡萝卜素和羽扇豆酮

  摘要：

  摘要 从长毛毛茛全株中分离得到一种新的脱氢-6-羟基类胡萝卜素、12a-脱氢-6-羟基苏马醇和羽扇豆酮。从化学和光谱证据中阐明了它们的结构。新的类胡萝卜素结构通过其从 6a, 12a-dehydrosumatrol 的部分合成得到证实。

  DOI：

  10.1016/s0031-9422(00)95025-8

文献信息

• EP2727473A2
  申请人：——

  公开号：EP2727473A2

  公开（公告）日：2014-05-07
• Iridoid Based Formulations
  申请人：West Brett Justin

  公开号：US20110217394A1

  公开（公告）日：2011-09-08

  Embodiments of the invention relate to fortified food and dietary supplement products which may be administered to produce desirable physiological improvement. In particular, embodiments of the invention relates to the administration of products enhanced with plant products and iridoids.
• Acai and Iridoid Based Formulations
  申请人：West Brett Justin

  公开号：US20110206786A1

  公开（公告）日：2011-08-25

  Embodiments of the invention relate to fortified food and dietary supplement products, which may be administered to produce desirable physiological improvement. In particular, embodiments of the invention relate to the administration of products enhanced with Acai and iridoids.
• Morinda Citrifolia and Iridoid Based Formulations
  申请人：West Brett Justin

  公开号：US20110206787A1

  公开（公告）日：2011-08-25

  Embodiments of the invention relate to fortified food and dietary supplement products which may be administered to produce desirable physiological improvement. In particular, embodiments of the invention relates to the administration of products enhanced with Morinda citrifolia and iridoids.
• Garcinia Mangostana L. and Iridoid Based Formulations
  申请人：West Brett Justin

  公开号：US20120021079A1

  公开（公告）日：2012-01-26

  Embodiments of the invention relate to fortified food and dietary supplement products, which may be administered to produce desirable physiological improvement. In particular, embodiments of the invention relate to the administration of products enhanced with Garcinia mangostana L. and iridoids.