Isobomyl acrylate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Isobomyl acrylate
• 英文别名: 2-[(1R,4R)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl]prop-2-enoate
• 化学式: C13H19O2-
• 分子量: 207.29
• InChiKey: LUQCMFNLYPBEBV-NDAPUWOLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  对叔丁氧基苯乙烯 、 Isobomyl acrylate 、 2,2'-Azobis(methyl 2-methylpropanate) 、 甲醇 在 氮气 作用下， 以 1,4-二氧六环 为溶剂， 反应 6.0h， 以to give 105.4 g of poly(p-tert-butoxystyrene/isobornyl acrylate) as white powdery crystal的产率得到p-Tert-butoxystyrene isobomyl acrylate
  参考文献：
  名称：

  Resist composition

  摘要：

  本发明涉及一种聚合物，能够在使用化学增感型抗蚀剂组成的单层或多层中的最上层作为硅化表面分辨率过程中形成具有优异矩形形状的超细图案，并涉及使用该聚合物的抗蚀剂组成物。该聚合物和抗蚀剂组成物在硅化表面分辨率过程中非常有用，通过使用该抗蚀剂组成物进行硅化表面分辨率过程，硅化对比度更高，无论曝光能量的种类如何，都可以获得超细图案。

  公开号：

  US20030039920A1
• 作为试剂：
  描述：

  丙烯酸异丁酯 、 丙烯酸苄酯 、 丙烯酸羟乙酯 、 Isobomyl acrylate 、 丙烯腈 在 氮气 、 Luperox®-554 M75 、 丁酮 、 偶氮二异丁腈 、 丙烯酸异丁酯 、 丙烯酸苄酯 、 丙烯酸羟乙酯 、 Isobomyl acrylate 、 丙烯腈 作用下， 以 丁酮 为溶剂， 反应 8.83h， 生成 (1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acrylate
  参考文献：
  名称：

  Halo resistent, photoimagable coverlay compositions, having, advantageous application and removal properties, and methods relating thereto

  摘要：

  一种灵活、水溶性、光敏覆盖层组合物，具有优异的粘附和释放性能以及抗（不需要的）晕影性能。本发明的覆盖层组合物包括具有耐碱骨架段和含亲水性基团的悬臂臂段的丙烯酸低Tg嫁接共聚物粘合剂组分。可选地，覆盖层进一步包括一种噻吩型粘附促进剂，以进一步改善粘附性能。

  公开号：

  US20040058276A1

文献信息

• Alternating copolymers of isobutylene type monomers
  申请人：——

  公开号：US20030170394A1

  公开（公告）日：2003-09-11

  A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

  一种共聚物组成物，包括至少30摩尔％的残基的共聚物，该残基来自给体单体和受体单体的以下交替残基。 该共聚物含有至少15摩尔％的异丁烯型给体单体和至少15摩尔％的丙烯酸单体作为受体单体。 该共聚物基本上不含马来酸或富马酸单体片段，且该共聚物组成物基本上不含路易斯酸和过渡金属。 还披露了一种热固性组合物，其中包括具有功能基的反应物，具有至少两个与第一反应物中的功能基反应的交联剂，以及包括共聚物组成物的共聚物流控制剂，以及用热固性组合物涂覆的基板。
• Thermosetting compositions containing alternating copolymers of isobutylene type monomers
  申请人：——

  公开号：US20030171497A1

  公开（公告）日：2003-09-11

  A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

  一种热固性组合物，包括未胶凝的共聚物组合物和交联剂。未胶凝的共聚物组合物包括一个含有功能性基团的共聚物，其中包括从给体单体组成中得到的交替残基段，该给体单体组成包括受体单体组成。给体单体组成包括异丁烯和二异丁烯中的至少一种，而受体单体组成包括丙烯酸单体和含有功能性基团的单体。未胶凝的共聚物组合物基本上不含过渡金属和路易斯酸，而共聚物基本上不含马来酸型单体残基和富马酸型单体残基。交联剂具有至少两个与共聚物的功能性基团反应的功能性基团。热固性组合物可以是液体、粉末或分散形式，并且可以通过传统或电泳涂覆方法应用。
• Method of making alternating copolymers of isobutylene type monomers
  申请人：——

  公开号：US20030171515A1

  公开（公告）日：2003-09-11

  A method of making a copolymer composition containing a copolymer, which includes the steps of (a) providing a donor monomer composition that includes an isobutylene type monomer; (b) mixing the donor monomer composition with an ethylenically unsaturated monomer composition that includes one or more ethylenically unsaturated acceptor monomers, and is substantially free of maleate type monomers and fumarate type monomers, and (c) polymerizing the mixture resulting from step (b) in the presence of a free radical polymerization initiator. The polymerization is carried out in the substantial absence of Lewis acids and/or transition metals. The isobutylene type monomer is present at a molar excess of at least 10 mol % based on the molar concentration of monomers in the ethylenically unsaturated monomer composition. The ethylenically unsaturated acceptor monomers are present in an amount of at least 15 mol % of the total monomer composition.

  一种制备共聚物组合物的方法，包括以下步骤：(a)提供包括异丁烯型单体的供体单体组合物；(b)将供体单体组合物与包括一种或多种乙烯基不饱和受体单体且基本上不含马来酸酯型单体和富马酸酯型单体的乙烯基不饱和单体组合物混合；(c)在自由基聚合引发剂的存在下聚合步骤(b)得到的混合物。聚合在基本上不含路易斯酸和/或过渡金属的情况下进行。异丁烯型单体的摩尔过量至少为乙烯基不饱和单体组合物中单体的摩尔浓度的10摩尔％。乙烯基不饱和受体单体的量至少为总单体组合物的15摩尔％。
• U.V. curable laminating adhesive composition
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：US05475038A1

  公开（公告）日：1995-12-12

  A print laminating adhesive composition comprising a selected acrylate terminated photopolymerizable oligomer of the formula: ##STR1## where A is the residue of a diisocyanate selected from the group consisting of diphenylmethane 4,4.sup.1 diisocyanate and 4,4.sup.1 dicyclohexylmethane diisocyanate; X is the residue of polypropylene glycol having a molecular weight of from about 150 to 4000; R is alkyl or hydroxyalkyl of 2 to 10 carbons; R.sup.1 is alkylene of 2 to 3 carbons; and R.sup.2 is hydrogen or methyl.

  一种印刷层压粘合剂组合物，包括选择的丙烯酸酯终止的光聚合可聚物，其化学式为：##STR1## 其中，A是从二苯基甲烷4,4'-二异氰酸酯和4,4'-二环己基甲烷二异氰酸酯组成的二异氰酸酯残基；X是分子量约为150至4000的聚丙烯醚的残基；R是2至10个碳的烷基或羟基烷基；R.sup.1是2至3个碳的亚烷基；R.sup.2是氢或甲基。
• Novel block polymers and cosmetic compositions and processes comprising them
  申请人：——

  公开号：US20040120920A1

  公开（公告）日：2004-06-24

  The present invention relates to novel block polymers comprising at least one first block and at least one second block that are incompatible with each other, have different glass transition temperatures (Tg), and are linked together via an intermediate segment comprising at least one constituent monomer of the at least one first block and at least one constituent monomer of the at least one second block. The block polymer has a polydispersity index I of greater than 2. The invention also relates to cosmetic compositions comprising the block polymers and processes for their use.

  本发明涉及一种新型块状聚合物，包括至少一个第一块和至少一个与第一块不相容且具有不同玻璃转移温度（Tg）的第二块，并通过中间段连接在一起，该中间段包括至少一个第一块的组成单体和至少一个第二块的组成单体。该块状聚合物的聚分散度指数I大于2。本发明还涉及包含该块状聚合物的化妆品组合物以及它们的使用方法。