苯基乙基 beta-D-吡喃半乳糖苷 | 14861-16-6

• 物质功能分类: 生物化工 - 糖类化合物 - 单糖
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 苯基乙基 beta-D-吡喃半乳糖苷
• 中文别名: 苯基乙基BETA-D-吡喃半乳糖苷；苯基乙基beta-D-吡喃半乳糖苷
• 英文名称: 2-phenylethyl β-D-galactopyranoside
• 英文别名: Phenethyl beta-D-galactopyranoside；(2R,3R,4S,5R,6R)-2-(hydroxymethyl)-6-(2-phenylethoxy)oxane-3,4,5-triol
• CAS: 14861-16-6
• 化学式: C₁₄H₂₀O₆
• 分子量: 284.309
• InChiKey: MLRIJUWUQTVDQE-MBJXGIAVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  99.4
• 氢给体数：
  4
• 氢受体数：
  6

安全信息

• WGK Germany：
  3
• 海关编码：
  29389090

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 苯基乙基 beta-D-吡喃半乳糖苷 在 吡啶 作用下， 以1.3 mg的产率得到2-phenylethyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside
  参考文献：
  名称：

  Isolation of a Glucosidic β-Damascenone Precursor from Rose Petals

  摘要：

  The 9-O-beta-D-glucopyranoside of 3-hydroxy-7,8-didehydro-beta-ionol (1) has been isolated from a glycosidic XAD-2 extract obtained from rose petals. In addition to the beta-damascenone-generating compound 1, the following glycoconjugates have been isolated and characterized as peracetates: 3-hydroxy-7,8-dihydro-beta-ionol 9-O-beta-D-glucopyranoside (2), 3-hydroxy-7,8-dihydro-beta-ionol 3-O-beta-D-glucopyranoside (3), 2-phenylethyl-O-beta-D-glucopyranoside (4), 2-phenylethyl-O-beta-D-galactopyranoside (5), benzyl-O-beta-D-glucopyranoside (6), (2E)-2,6-dimethyl-6-hydroxyocta-2,7-dienyl-O-beta-D-glucopyranoside (7), (2Z)-2,6-dimethyl-6-hydroxyocta-2, 7-dienyl-O-beta-D-glucopyranoside (8), and (2E,6E)-2,6-dimethyl-1-hydroxyocta-2,6-dien-8-yl-O-beta-D-glucopyranoside (9).

  DOI：

  10.1021/jf970278j
• 作为产物：
  描述：

  2-phenylethyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside 在 甲醇 、 sodium methylate 作用下， 反应 2.0h， 以94%的产率得到苯基乙基 beta-D-吡喃半乳糖苷
  参考文献：
  名称：

  Synthesis, Biological Activity of Salidroside and Its Analogues

  摘要：

  红景天苷是从传统中草药红景天中分离得到的一种苯丙素苷类化合物，具有广泛的药理活性。本文通过Koenigs-Knorr方法合成了约18种新颖的红景天苷类似物，并利用3-(4,5-二甲基噻唑-2-基)-2,5-二苯基四唑溴盐（MTT）法评估了这些化合物对PC12细胞的影响。这些新颖化合物在苯环上的取代基或糖基供体方面有所不同。根据数据，苯环3和5位带有甲氧基的(3,5-二甲氧基苯基)甲基β-D-葡萄吡喃糖苷和(3,5-二甲氧基苯基)甲基β-D-半乳吡喃糖苷在浓度分别为300 μmol/L和60 μmol/L时显示出最高的细胞生存力。

  DOI：

  10.1248/cpb.58.1627

文献信息

• Method and culture device for detecting yeasts and molds
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10640743B2

  公开（公告）日：2020-05-05

  A thin film culture device for detecting yeast and mold microorganisms in a sample is provided. The culture device comprises a body comprising a self-supporting substrate having a first major surface and a second major surface; a first adhesive composition disposed on a portion of the first major surface of the substrate; a substantially dry, cold-water-soluble first hydrogel-forming composition adhered to the first adhesive composition; and a plurality of indicator agents. The plurality of indicator agents comprises three indicator agents for detecting distinct glycosidase enzyme activities, an indicator agent for detecting an alkyl esterase enzyme activity, and an indicator agent for detecting a phosphatase enzyme activity, wherein each of the plurality of indicator agents comprises a detectable reporter group. A method of using the culture device is also provided.

  提供了一种用于检测样品中酵母和霉菌微生物的薄膜培养装置。该培养装置包括一个主体，该主体包括具有第一大表面和第二大表面的自支撑基底；设置在基底第一大表面部分上的第一粘合剂组合物；粘附在第一粘合剂组合物上的基本干燥、冷水可溶的第一水凝胶形成组合物；以及多种指示剂。多种指示剂包括三种用于检测不同糖苷酶酶活性的指示剂、一种用于检测烷基酯酶酶活性的指示剂和一种用于检测磷酸酶酶活性的指示剂，其中多种指示剂中的每一种都包括可检测的报告基团。还提供了一种使用该培养装置的方法。
• Kinetic Products Under Thermal Conditions: Rapid Entry into α/β-D-Galactofuranosides Using Microwave Irradiation and Selective Lewis Acids
  作者：Soumava Santra、Emily Jonas、Jean-Paul Bourgault、Tarick El-Baba、Peter R. Andreana

  DOI：10.1080/07328303.2011.585259

  日期：2011.1.1

  A modified Fischer-Lubineau reaction, employing microwave irradiation and selected Lewis acids such as Mn(ClO4)(2), Mn(C2H3O2)(3), FeCl3, CoCl2, and AgF as independent additives, induces rapid entry into alpha/beta-D-galactofuranosides in very good yield and purity.
• METHODS FOR PROTEIN BINDING ENZYME COMPLEMENTATION ASSAYS
  申请人：MICROGENICS CORPORATION

  公开号：EP0199801A1

  公开（公告）日：1986-11-05
• EP0199801A4
  申请人：——

  公开号：EP0199801A4

  公开（公告）日：1988-12-15
• IMMOBILISATION OF LIGANDS BY RADIO-DERIVATIZED POLYMERS
  申请人：Epipharm Allergie-Service Gesellschaft mbh

  公开号：EP0439585A1

  公开（公告）日：1991-08-07