N,N’-二(12-羟基十八碳酰基)-1,6-己二胺 | 55349-01-4

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: N,N’-二(12-羟基十八碳酰基)-1,6-己二胺
• 中文别名: N,N'-1,6-己亚基-二(12羟基-十八烷酰胺)；N,N"-1,6-己亚基-二(12羟基-十八烷酰胺)；N,N"-二(12-羟基十八碳酰基)-1,6-己二胺
• 英文名称: N,N'-1,6-hexanediyl-bis-12-hydroxyoctadecanamide
• 英文别名: Hexamethylene bis-hydroxystearamide；12-hydroxy-N-[6-(12-hydroxyoctadecanoylamino)hexyl]octadecanamide
• CAS: 55349-01-4
• 化学式: C₄₂H₈₄N₂O₄
• 分子量: 681.14
• InChiKey: CXPIOTOKMJNFSA-UHFFFAOYSA-N

物化性质

• 熔点：
  132 °C
• 沸点：
  810.0±40.0 °C(Predicted)
• 密度：
  0.933±0.06 g/cm3(Predicted)
• LogP：
  6-12.3 at 25℃
• 物理描述：
  DryPowder; Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  48
• 可旋转键数：
  39
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  98.7
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,6-己二胺 、 12-羟基硬脂酸 在 吡啶 、 亚磷酸三苯酯 作用下， 生成 N,N’-二(12-羟基十八碳酰基)-1,6-己二胺
  参考文献：
  名称：

  三种能够形成基于氢键的结晶纳米纤维的双子型触变表面活性剂的结构/功能相关性比较——固态结构、二维分子成膜和外延生长行为——

  摘要：

  在这项研究中，我们比较和研究了三种双子型二酰胺表面活性剂的二维 (2D) 有组织的薄膜/三维 (3D) 固体中的微观分子堆积和介观形态发生行为，这些表面活性剂在化学性质方面存在系统差异。结构体。这些表面活性剂的结晶纳米纤维的生长促进了周围介质的凝胶化，而这些纳米纤维的消失和溶剂回流是由于在相应的凝胶上施加力而引起的，因为这些表面活性剂分子被认为是潜在的触变剂。表面活性剂的 3D 晶体中的层状结构和子细胞是由范德华力和氢键的结合形成的，因为导致晶体纳米纤维形成的机制是分子间氢键。在水面上的单分子层中，只有疏水链中具有羟基的表面活性剂分子形成结晶纳米纤维。介绍...

  DOI：

  10.1246/bcsj.20170406

文献信息

• PROCESS FOR PRODUCTION OF INJECTION-MOLDED ARTICLE OF POLYLACTIC ACID RESIN
  申请人：Takenaka Akira

  公开号：US20100201037A1

  公开（公告）日：2010-08-12

  A method of manufacturing a polylactic acid resin injection molded article, having the step (1): a step of melt-kneading a polylactic acid resin composition containing a polylactic acid resin and a specified organic crystal nucleus agent, while contacting the composition with a supercritical fluid; and step (2): a step of filling the melted product obtained in step (1) in a die to mold with injection-molding. The manufacturing method of the present invention is used as an advantageous technique as compared with the technique of achieving satisfactory moldability by the addition of plasticizer in the field, for example, which requires a polylactic acid resin molded article having high rigidity.

  一种制造聚乳酸树脂注塑制品的方法，包括步骤（1）：将含有聚乳酸树脂和指定有机晶核剂的聚乳酸树脂组合物与超临界流体接触时熔融混合；步骤（2）：将步骤（1）中获得的熔融产物填充到模具中进行注塑成型。与添加塑化剂以实现满意的成型性的技术相比，本发明的制造方法可用作一种有利的技术，例如需要具有高刚度的聚乳酸树脂注塑制品的领域。
• PROCESS FOR PRODUCING RESIN COMPOSITION
  申请人：Yoshino Taiki

  公开号：US20110196076A1

  公开（公告）日：2011-08-11

  A method for producing a resin composition, including the steps of melt-kneading a raw material A containing a polylactic acid resin, a crystal nucleating agent, and a plasticizer containing an ester compound formed between a polycarboxylic acid having a hydrocarbon group having 1 to 7 carbon atoms and a mono-alcohol having a hydrocarbon group having 1 to 7 carbon atoms, to prepare a polylactic acid-containing melt-kneaded mixture having a relative crystallinity of 70% or more (step A); and further melt-kneading the polylactic acid-containing melt-kneaded mixture obtained by the step A and a raw material B containing a polypropylene resin and a compatibilizing agent (step B). The resin composition obtainable by the method of the present invention can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.

  一种生产树脂组合物的方法，包括以下步骤：熔融混炼原料A，该原料A包含聚乳酸树脂、晶核剂和含有1至7个碳原子的烃基的聚羧酸和含有1至7个碳原子的单醇之间形成的酯类增塑剂，以制备相对结晶度为70％或更高的含有聚乳酸的熔融混炼物（步骤A）；进一步熔融混炼步骤A获得的含有聚乳酸的熔融混炼物和原料B，该原料B包含聚丙烯树脂和相容剂（步骤B）。本发明的方法可获得的树脂组合物可适用于各种工业应用，例如日用杂品、家用电器零部件和汽车零部件。
• METHOD FOR PROMOTING CRYSTALLIZATION OF BIODEGRADABLE RESIN COMPOSITION
  申请人：Sawada Hiroki

  公开号：US20120016065A1

  公开（公告）日：2012-01-19

  A method for promoting crystallization of a biodegradable resin composition, including the step of melt-kneading a raw material containing ethylenebis 12-hydroxystearic amide having an amine value of 1.0 mg KOH/g or less and a biodegradable resin. Since the biodegradable resin composition obtainable by the method for promoting crystallization of the present invention has favorable crystallization velocity, a time period required upon molding the composition is shortened, whereby a molded article can be produced productively. The biodegradable resin composition can be suitably used in, for example, in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.

  一种促进可生物降解树脂组合物结晶的方法，包括熔融混炼含有乙撑二酸十二羟基硬脂酰胺原料，其胺值小于等于1.0毫克KOH/克和可生物降解树脂的步骤。由于本发明促进结晶的方法所得到的可生物降解树脂组合物具有良好的结晶速度，因此在成型该组合物时所需的时间缩短，从而可以高效地生产成型品。该可生物降解树脂组合物可以适用于各种工业应用，例如日用杂品、家用电器零件和汽车零件等。
• RESIN COMPOSITION
  申请人：Sawada Hiroki

  公开号：US20130137802A1

  公开（公告）日：2013-05-30

  A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.

  一种树脂组合物，包括：酯化合物，包括通过使用（1）具有1至4个碳原子的烷基基团的单元醇；（2）具有2至4个碳原子的亚烷基基团的二羧酸；和（3）具有2至6个碳原子的亚烷基基团的二元醇得到的羧酸酯，所述酯化合物的酸值为1.00 mgKOH/g或以下，羟值为5.0 mgKOH/g或以下，数均分子量为300至700；以及脂肪族聚酯。由于本发明的树脂组合物抑制了挥发化合物的生成，因此该树脂组合物可适用于各种工业应用，例如日用品、家用电器零件和汽车零件。
• BIODEGRADABLE RESIN COMPOSITION
  申请人：KAO CORPORATION

  公开号：EP1746136A1

  公开（公告）日：2007-01-24

  The present invention relates to a method of producing a biodegradable resin composition, which includes step (1) of mixing a biodegradable resin, a plasticizer, and a crystal nucleating agent with one another at the melting point (Tm) of the biodegradable resin or more, wherein the crystal nucleating agent is an aliphatic compound having, in its molecule, two or more of at least one group selected from an ester group, a hydroxyl group and an amide group, and step (2) of thermally treating the resulting biodegradable resin composition at a temperature of from the glass transition temperature (Tg) to less than Tm of the composition, as well as a biodegradable resin composition, which contains a biodegradable resin, a plasticizer, and the above crystal nucleating agent, and which satisfies the following conditions: the haze thereof with a thickness of 0.5 mm after thermal treatment at 60°C for 36 or 60 hours is 20% or less; the storage elastic modulus (E') at a temperature of 25°C and a frequency of 50 Hz is 1 × 108 to 2 × 109 Pa; and the storage elastic modulus (E') at a temperature of 60°C and a frequency of 50 Hz is 1 × 107 to 1 × 109 Pa.

  本发明涉及一种生产可生物降解树脂组合物的方法，该方法包括步骤(1)在可生物降解树脂的熔点(Tm)或更高的温度下将可生物降解树脂、增塑剂和晶核剂相互混合，其中晶核剂是一种脂肪族化合物，在其分子中至少有两个或更多的基团，这些基团选自酯基，羟基和酰胺基；以及步骤(2)在组合物的玻璃化温度(Tg)至低于Tm的温度下对所得到的可生物降解树脂组合物进行热处理、步骤(2)在该组合物的玻璃化温度（Tg）至低于 Tm 的温度下热处理得到的可生物降解树脂组合物，以及可生物降解树脂组合物，该组合物包含可生物降解树脂、增塑剂和上述晶核剂，并满足以下条件：在 60°C 热处理后，其雾度厚度为 0.5 mm 的雾度为 20% 或更小；在温度为 25°C 和频率为 50 Hz 时，储存弹性模量（E'）为 1 × 108 至 2 × 109 Pa；在温度为 60°C 和频率为 50 Hz 时，储存弹性模量（E'）为 1 × 107 至 1 × 109 Pa。