cheilanthenetriol | 35940-57-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: cheilanthenetriol
• CAS: 35940-57-9
• 化学式: C₂₅H₄₄O₃
• 分子量: 392.623
• InChiKey: QVSOUBMAPDSQTQ-MWVDJROQSA-N

反应信息

• 作为反应物：
  描述：

  cheilanthenetriol 在 platinum(IV) oxide chromium(VI) oxide 、 氢气 作用下， 以 吡啶 、 溶剂黄146 、 乙酸乙酯 为溶剂， 反应 3.7h， 生成 (1S,2S,4bR,10aR)-2-Hydroxy-2,4b,8,8,10a-pentamethyl-1-(3-methyl-pentyl)-dodecahydro-phenanthren-9-one
  参考文献：
  名称：

  Fern constituents: Cheilanthenetriol and cheilanthenediol. Sesterterpenoids isolated from the leaves of aleuritopteris khunii.

  摘要：

  Two sesterterpenoids, cheilanthenetriol (1) and cheilanthenediol (2), were isolated from the leaves of Aleuritopteris Khunii together with hop-22(29)-ene, adiantone, hydroxyhopane, a mixture of sterols, 3, 5-dihydroxy-7, 4'-dimethoxyflavone, 5-hudroxy-3, 7, 4'-trimethoxyflavone and 4-methoxybenzoic acid. Cheilanthenetriol was found to be identical with authentic samples of cheilanthatriol and cheilarinosin isolated from Indian ferns. The new sesterterpenoid, cheilanthenediol, wes established as (17Z)-13α, 19-dihydroxycheilanth-17-ene.

  DOI：

  10.1248/cpb.38.342