10-methylhexadecyl iodide | 147103-06-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 10-methylhexadecyl iodide
• 英文别名: 1-Iodo-10-methylhexadecane
• CAS: 147103-06-8
• 化学式: C₁₇H₃₅I
• 分子量: 366.369
• InChiKey: NBDHOSQHLDDDNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  18
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  10-methylhexadecyl iodide 在 chromium(VI) oxide 、 sodium methylate 、 silver(I) acetate 作用下， 以 甲醇 、 溶剂黄146 为溶剂， 反应 26.25h， 生成 10-methylhexadecanoic acid
  参考文献：
  名称：

  Isolation of five-membered cyclitol glycolipids, crasserides: unique glycerides from the sponge Pseudoceratina crassa

  摘要：

  Crasserides 1a-6a, six new glycolipid analogues in which the sugar moiety is replaced by an unprecedented five-membered cyclitol, were isolated as a mixture from the sponge Pseudoceratina crassa (Hyatt), and their structures were determined by spectroscopic and chemical analysis. Compounds 1a-6a showed a high antifeedant activity on the fish Carassius auratus, which suggests their potential role as natural feeding deterrents.

  DOI：

  10.1021/jo00053a034
• 作为产物：
  描述：

  1-O-(2',3',4',5'-tetrahydroxycyclopentyl)-3-O-(10''-methylhexadecyl)glycerol 在 氢碘酸 作用下， 以 水 为溶剂， 反应 12.0h， 以7.7 mg的产率得到10-methylhexadecyl iodide
  参考文献：
  名称：

  Isolation of five-membered cyclitol glycolipids, crasserides: unique glycerides from the sponge Pseudoceratina crassa

  摘要：

  Crasserides 1a-6a, six new glycolipid analogues in which the sugar moiety is replaced by an unprecedented five-membered cyclitol, were isolated as a mixture from the sponge Pseudoceratina crassa (Hyatt), and their structures were determined by spectroscopic and chemical analysis. Compounds 1a-6a showed a high antifeedant activity on the fish Carassius auratus, which suggests their potential role as natural feeding deterrents.

  DOI：

  10.1021/jo00053a034

文献信息

• Isolation of five-membered cyclitol glycolipids, crasserides: unique glycerides from the sponge Pseudoceratina crassa
  作者：Valeria Costantino、Ernesto Fattorusso、Alfonso Mangoni

  DOI：10.1021/jo00053a034

  日期：1993.1

  Crasserides 1a-6a, six new glycolipid analogues in which the sugar moiety is replaced by an unprecedented five-membered cyclitol, were isolated as a mixture from the sponge Pseudoceratina crassa (Hyatt), and their structures were determined by spectroscopic and chemical analysis. Compounds 1a-6a showed a high antifeedant activity on the fish Carassius auratus, which suggests their potential role as natural feeding deterrents.