(4-甲氧基苯基)苯基对甲苯胺 | 97126-56-2

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: (4-甲氧基苯基)苯基对甲苯胺
• 英文名称: 4-methoxy-N-phenyl-N-(p-tolyl)aniline
• 英文别名: N-(4-methoxyphenyl)-4-methyl-N-phenylaniline
• CAS: 97126-56-2
• 化学式: C₂₀H₁₉NO
• 分子量: 289.377
• InChiKey: KXPUYDGZOZPPLU-UHFFFAOYSA-N

物化性质

• 沸点：
  435.5±38.0 °C(Predicted)
• 密度：
  1.109±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2922299090

反应信息

• 作为反应物：
  描述：

  (4-甲氧基苯基)苯基对甲苯胺 在 sodium hydroxide 、 三氯氧磷 作用下， 以 乙醇 、 水 为溶剂， 生成 1-(2,5-dimethylthiophen-3-yl)-3-(4-(N-(4-methylphenyl)-N-(4-methoxyphenyl)amino)phenyl)prop-2-en-1-one
  参考文献：
  名称：

  Electrochromic properties of novel chalcones containing triphenylamine moiety

  摘要：

  A series of novel electrochromic chalcones containing triphenylamine units were synthesized by Aldol reaction and characterized by NMR, IR and MS. Their optical, electrochemical properties were investigated using UV-vis, photoluminescence spectra and cyclic voltammetry. The molecular orbital energy levels and excitation energies were calculated by quantum chemical calculation. It was found that the fluorescence intensity is decreasing with formation of charge-transfer state. The existence of electron donating group on triphenylamine unites caused a significant bathochromic shift of the UV absorption maximum and increased E-HOMO and E-LUMO. The electrochromic property of the synthesized compounds was studied by spectroelectrochemical experiments. The results showed that the chalcones containing triphenylamine moiety presented good electrochromic stability, with a color change from yellow to blue as applied potentials ranging from 0.0 to 2.8 V. The coloring and bleaching time was in the range of 2.9 -4.2 s and 1.7-3.3 s, respectively. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.02.018
• 作为产物：
  描述：

  N-(4-methoxyphenyl)cyclohexanimine 在 铬 、 氢气 、 silica gel 、 镍 、 铜 、 sodium sulfate potassium carbonate 作用下， 以 硝基苯 为溶剂， 反应 15.0h， 生成 (4-甲氧基苯基)苯基对甲苯胺
  参考文献：
  名称：

  Tarasievich; Mikhalevskaya; Kozlov, Russian Journal of Organic Chemistry, 1997, vol. 33, # 8, p. 1100 - 1102

  摘要：

  DOI：

文献信息

• Selective Monoarylation of Primary Anilines Catalyzed by Pd(dippf) and its Application in OLED Component Synthesis
  作者：Matthias F. Grünberg、Fan Jia、Andreas Rivas-Nass、Lukas J. Gooßen

  DOI：10.1002/adsc.201501160

  日期：2016.5.19

  Palladium 1,1′‐bis(diisopropylphosphino)‐ferrocene [Pd(dippf)] complexes were found to promote the monoarylation of primary anilines with unprecedented selectivities. They also allow the sequential arylation of primary anilines with two different aryl bromides in one pot. The reactions can be performed at low catalyst loadings (0.2 mol%) and high substrate concentrations. The synthetic utility of the

  发现钯1,1'-双（二异丙基膦基）-二茂铁[Pd（dippf）]配合物以前所未有的选择性促进伯苯胺的单芳基化。它们还允许在一个罐中用两种不同的芳基溴将芳基苯胺依次芳基化。该反应可以在低催化剂负载量（0.2mol％）和高底物浓度下进行。各种二-和三芳基胺的合成证明了最佳催化剂的合成效用。特别关注的是最先进的小分子有机发光二极管（OLED）中使用的具有咔唑和芴部分的化合物。
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  公开号：EP3522191A1

  公开（公告）日：2019-08-07

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  申请人：Universal Display Corporation

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  公开（公告）日：2017-02-01
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  公开号：EP3352185B1

  公开（公告）日：2021-10-27
• ORGANIC ELECTROLUMINESCENT DEVICES, AMINOSTYRLNAPHTHALENE COMPOUNDS AND SYNTHESIS INTERMEDIATES THEREOF, AND PRODUCTION PROCESSES OF THE SAME
  申请人：Ichimura Mari

  公开号：US20080051607A1

  公开（公告）日：2008-02-28

  An organic electroluminescent device includes an anode, a cathode, and an organic layer having a light-emitting area and arranged between the anode and the cathode. The organic layer contains in at least a part thereof at least one aminostyrylnaphthalene compound represented by the following formula [I], [II] or [III]: wherein R 1 , R 2 , R 11 , R 12 , R 23 and R 24 are each a phenyl or naphthyl group, R 3 , R 4 , R 13 , R 14 , R 25 and R 26 are each an electron attracting group such as a cyano group, and R 5 , R 15 and R 27 are each a substituent group such as an alkyl group.