chrysanthenone | 473-06-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: chrysanthenone
• 英文别名: 2-pinen-7-one；chrysanthenon；2,7,7-trimethylbicyclo[3.1.1]hept-2-en-6-one
• CAS: 473-06-3
• 化学式: C₁₀H₁₄O
• mdl: MFCD24392744
• 分子量: 150.221
• InChiKey: IECBDTGWSQNQID-UHFFFAOYSA-N

物化性质

• 沸点：
  231.78°C (rough estimate)
• 密度：
  0.9108 (rough estimate)
• LogP：
  1.648 (est)
• 保留指数：
  1099;1103;1088;1106;1092;1100;1102;1089;1094;1089;1103;1101;1110;1122;1105;1099;1110;1122;1122;1111;1111;1111;1100

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  chrysanthenone 在 lithium aluminium tetrahydride 作用下， 生成 1,8-menthadien-5-ol
  参考文献：
  名称：

  Cant,P.A.E. et al., Australian Journal of Chemistry, 1975, vol. 28, p. 621 - 630

  摘要：

  DOI：
• 作为产物：
  描述：

  7,7-dimethyl-2-methylenebicyclo<3.1.1>heptan-6-one 在 Lindlar's catalyst 氢气 作用下， 以 正己烷 为溶剂， 反应 0.17h， 以95%的产率得到chrysanthenone
  参考文献：
  名称：

  Synthesis of terpenes containing the bicyclo[3.1.1]heptane ring system by the intramolecular [2 + 2] cycloaddition reaction of vinylketenes with alkenes. Preparation of chrysanthenone, .beta.-pinene, .beta.-cis-bergamotene, .beta.-trans-bergamotene, .beta.-copaene, and .beta.-ylangene and lemnalol

  摘要：

  DOI：

  10.1021/jo00384a035

文献信息

• TWO-PHASE FERMENTATION PROCESS FOR THE PRODUCTION OF AN ORGANIC COMPOUND
  申请人：JANSSEN Antonius Cornelis Johannes Matheus

  公开号：US20160168595A1

  公开（公告）日：2016-06-16

  The invention relates to a two phase fermentation process for producing an organic compound, in particular an isoprenoid and to a bioreactor comprising a two phase fermentation system for producing an organic compound.

  本发明涉及一种用于生产有机化合物的两相发酵过程，特别是一种异戊二烯类化合物的生产方法，以及一种包括两相发酵系统的生物反应器，用于生产有机化合物。
• PERFUME COMPOSITIONS
  申请人：SHISEIDO COMPANY LIMITED

  公开号：EP1424071A1

  公开（公告）日：2004-06-02

  The present invention provides a perfume composition for mental control, the composition containing one or more components acknowledged as having a psycho-sedative effect selected from the group consisting of terpinyl butyrate, γ-nonalactone, acetyl isoeugenol, methyl anisate, terpineol, nerol, chrysanthenone, lyral, lilial, β-phenylethyl alcohol, γ-methyl ionone, Iso E Super, Z-3-hexenyl salicylate, p-methylphenylacetaldehyde, limonene, ocimene, helional, linalyl acetate, geranyl acetate, geraniol, hedione, linalool, citronellol, and γ-hexalactone and/or one or more components acknowledged as having a psycho-stimulative effect selected from the group consisting of piperitone, isoamyl angelate, phenylethyl angelate, cuminyl alcohol, menthalactone, ethyl myristate, and perilla aldehyde. The invention also provides an external composition and daily-use goods, containing the perfume composition for mental control.

  本发明提供了一种用于精神控制的香水组合物，该组合物含有一种或多种公认具有精神镇静作用的成分，这些成分选自以下组别：丁酸萜品酯，γ-纳内酯，乙酰异丁香酚，甲基苯甲醚，松油醇，橙花醇，菊甾酮，lyral，lilial，β-苯乙醇，γ-甲基离子酮，Iso E Super，Z-3-己烯基水杨酸酯、对甲基苯乙醛、柠檬烯、欧茜烯、氦醛、乙酸芳樟酯、乙酸香叶酯、香叶醇、香叶酮、芳樟醇、香茅醇和 γ-己内酯，以及/或一种或多种公认具有精神刺激作用的成分，这些成分选自胡椒酮、天使酸异戊酯、天使酸苯乙酯、小茴香醇、薄荷内酯、肉豆蔻酸乙酯和紫苏醛组成的组。本发明还提供了一种含有该香水组合物的外用组合物和日用品，用于精神控制。
• Perfume Composition comprising perilla aldehyde
  申请人：Shiseido Co., Ltd.

  公开号：EP1941870A2

  公开（公告）日：2008-07-09

  The present invention provides a perfume composition for mental control, the composition containing one or more components acknowledged as having a psycho-stimulative effect selected from the group consisting of perilla aldehyde or a combination of perilla aldehyde and perilla alcohol.

  本发明提供了一种用于精神控制的香水组合物，该组合物含有一种或多种公认具有精神刺激作用的成分，这些成分选自紫苏醛或紫苏醛和紫苏醇的组合物。
• DEGRADATION ODOR-INHIBITING AGENT AND ANTIBACTERIAL AGENT
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2140887A1

  公开（公告）日：2010-01-06

  The object of the present invention is to provide a deterioration smell inhibitor capable of effectively inhibiting deterioration smell generating form various products such as foods and cosmetics. The present invention relates to a deterioration smell inhibitor comprising a plant extract and isothiocyanate. As preferred embodiments, the plant extract is a labiatae plant extract, further the labiatae plant extract is an oil-insoluble labiatae plant extract, still further the weight ratio of the oil-insoluble labiatae plant extract/isothiocyanate is 1/1 to 99/1. In other preferred embodiments, the plant extract is a terpenoid alcohol or terpenoid ketone, further the weight ratio of the terpenoid alcohol or terpenoid ketone/isothiocyanate is 0.4/1 to 40/1.

  本发明的目的是提供一种变质气味抑制剂，能够有效抑制食品和化妆品等各种产品产生的变质气味。本发明涉及一种由植物提取物和异硫氰酸盐组成的变质气味抑制剂。在优选的实施方案中，植物提取物是一种唇形科植物提取物，唇形科植物提取物是一种油不溶性唇形科植物提取物，油不溶性唇形科植物提取物/异硫氰酸酯的重量比为 1/1 至 99/1。在其他优选的实施方案中，植物提取物是萜醇或萜酮，萜醇或萜酮/异硫氰酸酯的重量比为 0.4/1 至 40/1。
• AIR PURIFYING AGENT COMPOSITION
  申请人：Wang, Jingning

  公开号：EP3388088A1

  公开（公告）日：2018-10-17

  The present invention provides an air scavenger composition comprising by weight at least: extracts of sanguisorba officinalis and melia azadarach 10-30 parts, extract of sophora flavescens 10-30 parts, extract of robinia pseudoacacia 5-10 parts, extract of eucalyptus leaves 1-5 parts, extract of chrysanthemum 10-15 parts, extract of aloe vera 10-15 parts, nanosilver 0.1-1 parts, and artemisinin 0.5-2 parts.

  本发明提供了一种空气清净剂组合物，按重量计，至少包括：山银花和楝树提取物 10-30 份、槐树提取物 10-30 份、知更鸟提取物 5-10 份、桉树叶提取物 1-5 份、菊花提取物 10-15 份、芦荟提取物 10-15 份、纳米银 0.1-1 份和青蒿素 0.5-2 份。

表征谱图