13-(trifluoromethyl)retinal | 79849-51-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 13-(trifluoromethyl)retinal
• 英文别名: 20,20,20-trifluororetinal；(2Z,4E,6E,8E)-7-methyl-3-(trifluoromethyl)-9-(2,6,6-trimethylcyclohexen-1-yl)nona-2,4,6,8-tetraenal
• CAS: 79849-51-7
• 化学式: C₂₀H₂₅F₃O
• 分子量: 338.413
• InChiKey: LIPUOAYEGBQNOV-RKAKCNBESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (7E,9E)-beta-离子亚基乙醛 在 manganese(IV) oxide 、 正丁基锂 、 二异丁基氢化铝 、 lithium cyclohexylisopropylamide 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 生成 13-(trifluoromethyl)retinal
  参考文献：
  名称：

  Preparation of 20,20,20-trifluororetinal(13-trifluoromethylretinal)

  摘要：

  DOI：

  10.1016/s0040-4039(00)98860-9

文献信息

• Preparation of 20,20,20-trifluororetinal(13-trifluoromethylretinal)
  作者：Yuji Hanzawa、Kei-ichi Kawagoe、Nobuo Kobayashi、Toshihide Oshima、Yoshiro Kobayashi

  DOI：10.1016/s0040-4039(00)98860-9

  日期：1985.1
• 13-(Trifluoromethyl)retinal forms an active and far-red-shifted chromophore in bacteriorhodopsin
  作者：Wolfgang Gaertner、Dieter Oesterhelt、Paul Towner、Henning Hopf、Ludger Ernst

  DOI：10.1021/ja00415a037

  日期：1981.12
• COMPOSITIONS COMPRISING VARIOUS PROTEORHODOPSINS AND/OR BACTERIORHODOPSINS AND USE THEREOF
  申请人：Danisco US Inc.

  公开号：EP1753448B1

  公开（公告）日：2012-04-25
• PHOTOCHROMIC MATERIAL COMPRISING A PROTEORHODOPSIN APOPROTEIN AND RETINAL ANALOG
  申请人：GENENCOR INTERNATIONAL, INC.

  公开号：EP1753997B1

  公开（公告）日：2009-10-28
• Photochromic Material Comprising a Proteorhodopsin Apoprotein and a Retinal Analog
  申请人：Jensen Rasmus B.

  公开号：US20080290328A1

  公开（公告）日：2008-11-27

  The present invention relates to a photochromic material comprising a proteorhodopsin apoprotein and a retinal analog. In one embodiment, the retinal analog is an azulenic retinoid compound. In another embodiment, the retinal analog is a compound that is structurally similarly to all-trans-retinal. The proteorhodopsin apoprotein and the retinal analog form a photochromic material having different spectral properties from those of a corresponding photochromic material formed by the same proteorhodopsin apoprotein and all-trans-retinal. In one embodiment of the application, the retinal analog-containing proteorhodopsin has an absorbance spectrum that does not overlap significantly with that of all-trans-retinal-containing proteorhodopsin. In another embodiment of the application, the retinal analog-containing proteorhodopsin yields a red-shifted visual chromophore compared with the all-trans-retinal-containing proteorhodopsin chromophore. The photochromic material of the present invention is useful as an optical data storage carrier, a fraud-proof optical data carrier, security ink, and in other optical applications.