[(1H-苯并三唑-1-基)甲基]三苯基氯化鏻 | 111198-09-5

• 物质功能分类: 有机原料
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [(1H-苯并三唑-1-基)甲基]三苯基氯化鏻
• 英文名称: [(benzotriazol-1-yl)-methyl]triphenyl phosphonium chloride
• 英文别名: [(1H-Benzotriazol-1-yl)methyl]triphenylphosphonium Chloride；benzotriazol-1-ylmethyl(triphenyl)phosphanium;chloride
• CAS: 111198-09-5
• 化学式: C₂₅H₂₁N₃P*Cl
• 分子量: 429.889
• InChiKey: YEEGDMCFIRPFRB-UHFFFAOYSA-M

物化性质

• 熔点：
  279 °C(dec.)

计算性质

• 辛醇/水分配系数(LogP)：
  1.39
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  [(1H-苯并三唑-1-基)甲基]三苯基氯化鏻 在 正丁基锂 、 二甲基亚砜 作用下， 以 二甲基亚砜 为溶剂， 反应 4.0h， 生成 1-styryl-benzotriazole
  参考文献：
  名称：

  Katritzky, Alan R.; Offerman, Rick J.; Cabildo, Pilar, Recueil des Travaux Chimiques des Pays-Bas, 1988, vol. 107, # 11, p. 641 - 646

  摘要：

  DOI：
• 作为产物：
  描述：

  1H-苯并三唑-1-甲醇 在 氯化亚砜 作用下， 以 甲苯 为溶剂， 反应 48.0h， 生成 [(1H-苯并三唑-1-基)甲基]三苯基氯化鏻
  参考文献：
  名称：

  Katritzky, Alan R.; Offerman, Rick J.; Cabildo, Pilar, Recueil des Travaux Chimiques des Pays-Bas, 1988, vol. 107, # 11, p. 641 - 646

  摘要：

  DOI：

文献信息

• One-Carbon Homologation of Aldehydes to <i>N</i>-(α-Haloacyl)benzotriazoles
  作者：Alan Katritzky、Srinivasa Tala、Sandeep Singh

  DOI：10.1055/s-2006-950183

  日期：——

  One-carbon homologated N-(α-haloacyl)benzotriazoles have been synthesized from the corresponding aromatic and aliphatic aldehydes. Vinylbenzotriazoles, prepared by the reaction of aldehydes with the one-carbon synthon BtCH 2 P + Ph 3 Cl - , were subsequently treated with Br 2 /Et 3 N to give 1-bromovinylbenzotriazoles. These were then treated with NBS/NIS in CH 3 CN-H 2 O to furnish one-carbon homologated

  由相应的芳香族和脂肪族醛合成了单碳同系的 N-(α-卤代酰基)苯并三唑。通过醛与单碳合成子BtCH 2 P + Ph 3 Cl - 反应制备的乙烯基苯并三唑随后用Br 2 /Et 3 N 处理得到1-溴乙烯基苯并三唑。然后将它们在 CH 3 CN-H 2 O 中用 NBS/NIS 处理，以 53-77% 的产率提供单碳同系化 N-(α-卤代酰基)苯并三唑。我们还展示了这些新试剂在有机合成中的实用性。
• TWO-PACK TYPE EPOXY RESIN COMPOSITION FOR FIBER-REINFORCED COMPOSITE MATERIAL, AND FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：Toray Industries, Inc.

  公开号：EP3476877A1

  公开（公告）日：2019-05-01

  There is provided a two-pack epoxy resin composition that is excellent in viscosity stability at a low temperature (40°C) of an epoxy resin composition after mixing preparation, retains low viscosity at the time of injection into reinforcing fiber and is excellent in impregnation property, and controls resin flow by appropriate increase in the resin viscosity after the impregnation, for example, can reduce burrs on the formed product, cures in a short time at the time of formation, and gives a fiber-reinforced composite material high in transparency of a cured product and excellent in formed product quality, and a fiber-reinforced composite material made by using the same. The two-pack epoxy resin composition for a fiber-reinforced composite material of the present invention is a two-pack epoxy resin composition for a fiber-reinforced composite material containing the following components [A] to [E], in which the content of the component [A] is 5 to 45 parts by mass, the content of the component [B] is 5 to 50 parts by mass, and the content of the component [C] is 5 to 50 parts by mass, relative to 100 parts by mass of the total of the components [A], [B] and [C], and the fiber-reinforced composite material of the present invention is a fiber-reinforced composite material obtained by combining the two-pack epoxy resin composition for a fiber-reinforced composite material and a reinforcing fiber, and curing them. • component [A]: an alicyclic epoxy resin • component [B]: an aliphatic epoxy resin • component [C]: a bisphenol type epoxy resin • component [D]: an acid anhydride • component [E]: a compound selected from the group consisting of quaternary ammonium salts, quaternary phosphonium salts, and imidazolium salts.

  本发明提供了一种双组分环氧树脂组合物，该组合物在混合制备后的低温（40°C）下具有优异的粘度稳定性，在注入增强纤维时保持低粘度，并具有优异的浸渍特性，在浸渍后通过适当提高树脂粘度来控制树脂流动、例如，可减少成型产品上的毛刺，在成型时可在短时间内固化，固化产品的透明度高，成型产品的质量优异，可获得纤维增强复合材料和使用该材料制成的纤维增强复合材料。 本发明的纤维增强复合材料用双组分环氧树脂组合物是一种纤维增强复合材料用双组分环氧树脂组合物，含有以下组分[A]至[E]，其中组分[A]的含量为 5 至 45 份（按质量计），组分[B]的含量为 5 至 50 份（按质量计），组分[C]的含量为 5 至 50 份（按质量计）、相对于组分[A]、[B]和[C]总质量的 100 重量份，组分[C]的含量为 5 至 50 重量份，本发明的纤维增强复合材料是将纤维增强复合材料用双组分环氧树脂组合物和增强纤维混合并固化后得到的纤维增强复合材料。 - 组分[A]：脂环族环氧树脂 - 组分[B]：脂肪族环氧树脂 - 组分[C]：双酚型环氧树脂 - 组分[D]：酸酐 - 组分[E]：从季铵盐、季鏻盐和咪唑盐组成的组中选出的化合物。
• Covered particle
  申请人：Nippon Chemical Industrial Co., Ltd.

  公开号：US11311934B2

  公开（公告）日：2022-04-26

  The present invention provides covered particles wherein insulating layers cover the surfaces of electroconductive particles, and the covered particles are excellent in the adhesion between the surfaces of the electroconductive particles and the insulating layers. The covered particles includes: electroconductive particles in which metal films are formed on the surfaces of core materials, and a triazole-based compound is disposed on the outer surfaces on the sides opposite to the core materials in the metal films; and insulating layers covering the electroconductive particles, and the insulating layers comprise a compound having phosphonium groups.

  本发明提供了覆盖颗粒，其中绝缘层覆盖在导电颗粒的表面，并且覆盖颗粒在导电颗粒表面和绝缘层之间的附着力极佳。被覆颗粒包括：导电颗粒，其中在核心材料表面形成金属膜，在金属膜中与核心材料相对的两侧的外表面上放置三唑基化合物；以及覆盖导电颗粒的绝缘层，绝缘层包括具有鏻基团的化合物。
• Aitken, R. Alan; Fairhurst, Ian M.; Ford, Adrian, Journal of the Chemical Society. Perkin transactions I, 1997, # 20, p. 3107 - 3112
  作者：Aitken, R. Alan、Fairhurst, Ian M.、Ford, Adrian、Milne, Paul E. Y.、Russell, Duncan W.、Whittaker, Martin

  DOI：——

  日期：——
• Katritzky, Alan R.; Rachwal, Stanislaw; Caster, Kenneth C., Journal of the Chemical Society. Perkin transactions I, 1987, p. 781 - 790
  作者：Katritzky, Alan R.、Rachwal, Stanislaw、Caster, Kenneth C.、Mahni, Fatma、Law, Kam Wah、Rubio, Olga

  DOI：——

  日期：——