endo,exo-7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboxylic anhydride | 66212-72-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: endo,exo-7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboxylic anhydride
• 英文别名: (3aS,4aS,8aR,9aR)-5,6,7,8-tetrachloro-3a,4,4a,8a,9,9a-hexahydrobenzo[f][2]benzofuran-1,3-dione
• CAS: 66212-72-4
• 化学式: C₁₂H₈Cl₄O₃
• 分子量: 342.006
• InChiKey: HIWKGVRUHMIOJI-FBXFSONDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.72
• 重原子数：
  19.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  四氢化邻苯二甲酸酐 、 endo,exo-7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboxylic anhydride 以 丙酮 为溶剂， 反应 12.0h， 以90%的产率得到endo,exo,exo,endo-1,8,15,16-tetrachlorotetracyclo[6.6.2.0(2,7).0(9,14)]hexadec-15-ene-4,5:11,12-tetracarboxylic dianhydride
  参考文献：
  名称：

  Synthesis of polychlorinated unsaturated cyclic dicarboxylic acid imides

  摘要：

  A procedure has been developed for the synthesis of 3,4,5,6-tetrachlorocyclohexa-3,5-diene-1,2- and 7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboximides from the corresponding 3,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3- and 1,8,9,10,11,11-hexachlorotricyclo[6.2.1.02,7]undec-9-ene-4,5-dicarboxylic anhydrides and pyridine in dimethylformamide. Steric structure of the products has been studied.

  DOI：

  10.1134/s1070428008100072
• 作为产物：
  描述：

  endo,exo-1,2,3,4,11,11-hexachlorotricyclo[6.2.1.0^5,10]undec-2-ene-7,8-dicarboxylic acid anhydride 在 吡啶 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以90%的产率得到endo,exo-7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboxylic anhydride
  参考文献：
  名称：

  Synthesis of polychlorinated unsaturated cyclic dicarboxylic acid imides

  摘要：

  A procedure has been developed for the synthesis of 3,4,5,6-tetrachlorocyclohexa-3,5-diene-1,2- and 7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboximides from the corresponding 3,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3- and 1,8,9,10,11,11-hexachlorotricyclo[6.2.1.02,7]undec-9-ene-4,5-dicarboxylic anhydrides and pyridine in dimethylformamide. Steric structure of the products has been studied.

  DOI：

  10.1134/s1070428008100072

文献信息

• Synthesis and stereochemistry of N,N’-oxy(methylene)-diphenylene-bridged polychlorinated cage-like tetracarboxylic acid imides
  作者：M. S. Salakhov、V. S. Umaeva、A. I. Alikhanova

  DOI：10.1134/s1070428010100106

  日期：2010.10

  N,N'-[Oxy(or methylene)di-p-phenylene]bis(4,10,11,12-tetrachlorodecahydro-1H-4,10-etheno[2]-benzofuro[5,6-f]isoindole-1,3,6,8-tetraones) were synthesized by the Diels-Alder reaction of N,N'-[oxy(or methylene)di-p-phenylene]bis(endo,exo-7,8,9,10-tetrachlorobicyclo[4.4.0]deca-7,9-diene-3,4-dicarboximide) with maleic anhydride, and stereochemical structure of the products was studied.
• Zul'faliev; Salakhov; Pirgulieva, Russian Journal of Organic Chemistry, 1999, vol. 35, # 8, p. 1247 - 1248
  作者：Zul'faliev、Salakhov、Pirgulieva、Efendiev

  DOI：——

  日期：——