benzo[h]quinoline-2-carboxamide hydrazone

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: benzo[h]quinoline-2-carboxamide hydrazone
• 英文别名: Benzo[h]quinoline-2-carboxamide hydrazone；N'-aminobenzo[h]quinoline-2-carboximidamide
• 化学式: C₁₄H₁₂N₄
• 分子量: 236.276
• InChiKey: SASJERUGFQDXCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  benzo[h]quinoline-2-carboxamide hydrazone 以 乙醇 为溶剂， 反应 15.0h， 生成 6-(benzo[h]quinolin-2-yl)-8,9-dihydro-7H-dibenzo[f,h]cyclopenta[c]quinoline
  参考文献：
  名称：

  (Benzo[h])Quinolinyl-Substituted Monoazatriphenylenes: Synthesis and Photophysical Properties

  摘要：

  We propose a method for the synthesis of quinolinyl- and benzo[h]quinolinylmonoazatriphenylenes through 1,2,4-triazine intermediates with subsequent transformations in aza-Diels-Alder reaction. The photophysical properties of these new compounds were examined, and the effects due to additional fused aromatic rings were explored.

  DOI：

  10.1007/s10593-014-1540-1
• 作为产物：
  描述：

  benzo[h]quinoline 1-oxide 在 一水合肼 、 二甲氨基甲酰氯 作用下， 以 四氢呋喃 、 乙醇 、 1,2-二氯乙烷 为溶剂， 反应 183.0h， 生成 benzo[h]quinoline-2-carboxamide hydrazone
  参考文献：
  名称：

  (Benzo[h])Quinolinyl-Substituted Monoazatriphenylenes: Synthesis and Photophysical Properties

  摘要：

  We propose a method for the synthesis of quinolinyl- and benzo[h]quinolinylmonoazatriphenylenes through 1,2,4-triazine intermediates with subsequent transformations in aza-Diels-Alder reaction. The photophysical properties of these new compounds were examined, and the effects due to additional fused aromatic rings were explored.

  DOI：

  10.1007/s10593-014-1540-1

文献信息

• (Benzo[h])Quinolinyl-Substituted Monoazatriphenylenes: Synthesis and Photophysical Properties
  作者：D. S. Kopchuk、A. F. Khasanov、I. S. Kovalev、G. A. Kim、I. L. Nikonov、G. V. Zyryanov、V. L. Rusinov、O. N. Chupakhin

  DOI：10.1007/s10593-014-1540-1

  日期：2014.9

  We propose a method for the synthesis of quinolinyl- and benzo[h]quinolinylmonoazatriphenylenes through 1,2,4-triazine intermediates with subsequent transformations in aza-Diels-Alder reaction. The photophysical properties of these new compounds were examined, and the effects due to additional fused aromatic rings were explored.