N,N'-二甲基喹吖啶酮 | 19205-19-7

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: N,N'-二甲基喹吖啶酮
• 中文别名: N,N’-二甲基喹吖啶酮；5,12-二氢-5,12-二甲基喹[2,3-b]吖啶-7,14-二酮；N,N-二甲基喹吖啶酮；5,12-二氢-5,12-二甲基喹啉并[2,3-b]吖啶-7,14-二酮；DMQA；LT-E503
• 英文名称: 5,12-dihydro-5,12-dimethylquino[2,3-b]acridine-7,14-dione
• 英文别名: N,N’-dimethylquinacridone；N,N′-dimethylquinacridone；N,N'(trans)-dimethylquinacridone；N,N'-dimethylquinacridone；5,12-dimethyl-5,12-dihydro-quino[2,3-b]acridine-7,14-dione；N,N'-dimethyl-quinacridone；5,12-dimethylquinolino[2,3-b]acridine-7,14-dione
• CAS: 19205-19-7
• 化学式: C₂₂H₁₆N₂O₂
• mdl: MFCD00683078
• 分子量: 340.381
• InChiKey: SCZWJXTUYYSKGF-UHFFFAOYSA-N

物化性质

• 熔点：
  286 °C (dec.)(lit.)
• 沸点：
  576.7±50.0 °C(Predicted)
• 密度：
  1.45 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 安全说明：
  S22,S24/25
• WGK Germany：
  3
• 海关编码：
  2933990090

SDS

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Section I.Chemical Product and Company Identification
Chemical Name N.N'-Dimethylquinacridone
Portland OR
Synonym 5,12-Dimethylaquin[2,3-b]acridine-7,14-dione
C22H16N2O2
Chemical Formula
CAS Number 19205-19-7

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Section II. Composition and Information on Ingredients
Chemical Name CAS Number Percent (%) TLV/PEL Toxicology Data
N.N'-Dimethylquinacridone 19205-19-7 ---------- Not available. Not available.

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Section III. Hazards Identification
Acute Health Effects No specific information is available in our data base regarding the toxic effects of this material for humans. However,
exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound.
CARCINOGENIC EFFECTS : Not available.
Chronic Health Effects
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

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Section IV. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
improve.
Ingestion INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the
toxic material was ingested; the absence of such signs, however, is not conclusive.

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Section V. Fire and Explosion Data
Auto-Ignition Not available.
Flammability May be combustible at high temperature.
Flammable Limits
Flash Points Not available.
Not available.
Combustion Products These products are toxic carbon oxides (CO, CO 2), nitrogen oxides (NO, NO2).
Fire Hazards
Not available.
Risks of explosion of the product in presence of mechanical impact: Not available.
Explosion Hazards
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media
SMALL FIRE: Use DRY chemical powder.
and Instructions LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Consult with local fire authorities before attempting large scale fire-fighting operations.
Continued on Next Page
N.N'-Dimethylquinacridone

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Section VI. Accidental Release Measures
Spill Cleanup Light Sensitive Material.
Instructions Use a shovel to put the material into a convenient waste disposal container. Finish cleaning the spill by rinsing any
contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on
disposal.

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Section VII. Handling and Storage
Handling and Storage LIGHT SENSITIVE. Keep away from heat. Mechanical exhaust required. When not in use, tightly seal the container and
store in a dry, cool place. Avoid excessive heat and light. Do not breathe dust.
Information
Always store away from incompatible compounds such as oxidizing agents.

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Section VIII. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection Splash goggles. Lab coat. Dust respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult
a specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
Exposure Limits Not available.

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Section IX. Physical and Chemical Properties
Solubility
Physical state @ 20°C Solid. (Yellowish-Red Powder) Not available.
Not available.
Specific Gravity
Molecular Weight 340.37 Partition Coefficient Not available.
Boiling Point Not available. Vapor Pressure Not applicable.
Melting Point 285.8°C (546.4°F) Vapor Density Not available.
Not available. Volatility Not available.
Refractive Index
Critical Temperature Odor Not available.
Not available.
Not available. Not available.
Viscosity Taste

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Section X. Stability and Reactivity Data

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This material is stable if stored under proper conditions. (See Section VII for instructions)
Stability
Conditions of Instability
Avoid excessive heat and light.
Incompatibilities
Reactive with strong oxidizing agents.

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Section XI. Toxicological Information
RTECS Number Not available.
Routes of Exposure Eye Contact. Ingestion. Inhalation.
Not available.
Toxicity Data
Chronic Toxic Effects CARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
No specific information is available in our data base regarding the toxic effects of this material for humans. However,
Acute Toxic Effects
exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound.
Continued on Next Page
N.N'-Dimethylquinacridone

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Section XII. Ecological Information
Ecotoxicity Not available.
Environmental Fate Not available.

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Section XIII. Disposal Considerations
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
Waste Disposal
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
federal, state and local regulations when disposing of the substance.

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Section XIV. Transport Information
DOT Classification Not a DOT controlled material (United States).
PIN Number Not applicable.
Proper Shipping Name
Not applicable.
Packing Group (PG) Not applicable.
DOT Pictograms

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Section XV. Other Regulatory Information and Pictograms
TSCA Chemical Inventory This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.
(EPA)
WHMIS Classification
Not available.
(Canada)
EINECS Number (EEC) Not available.
EEC Risk Statements Not available.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  N,N-二甲基甲酰胺 、 N,N'-二甲基喹吖啶酮 在 三氯氧磷 作用下， 反应 2.0h， 以53%的产率得到N,N'-dimethyl-2,9-diformylquinacridone
  参考文献：
  名称：

  QUINACRIDONE DERIVATIVE, AND PHOTOACTIVE LAYER AND PHOTOELECTRIC CONVERSION DEVICE INCLUDING SAME

  摘要：

  一种喹喔啉衍生物可以用化学式1表示，并且光敏层和光电转换装置可以包括它。

  公开号：

  US20130048958A1
• 作为产物：
  描述：

  喹吖啶酮 、 苯磺酸甲酯 在 sodium hydroxide 、 苄基三甲基氯化铵 作用下， 以 氯苯 为溶剂， 反应 7.0h， 以94%的产率得到N,N'-二甲基喹吖啶酮
  参考文献：
  名称：

  Pushkina, L. L.; Dubovaya, L. V.; Shelyapin, O. P., Journal of Organic Chemistry USSR (English Translation), 1984, vol. 20, p. 1771 - 1775

  摘要：

  DOI：

文献信息

• PHOTOELECTRIC CONVERSION FILM, PHOTOELECTRIC CONVERSION ELEMENT AND ELECTRONIC DEVICE
  申请人：SONY SEMICONDUCTOR SOLUTIONS CORPORATION

  公开号：US20170054089A1

  公开（公告）日：2017-02-23

  There is provided a photoelectric conversion film including a quinacridone derivative represented by the following General formula (1) and a subphthalocyanine derivative represented by the following General formula (2).

  提供了一种光电转换膜，包括以下通式(1)表示的喹吖啶酮衍生物和以下通式(2)表示的亚酞菁衍生物。
• PHOTOELECTRIC CONVERSION ELEMENT, OPTICAL SENSOR, AND IMAGING ELEMENT
  申请人：FUJIFILM Corporation

  公开号：US20200035932A1

  公开（公告）日：2020-01-30

  The present invention provides a photoelectric conversion element exhibiting excellent responsiveness, and excellent dark current characteristics in a case of high-speed photoelectric conversion film formation, an optical sensor, an imaging element, and a compound which include the photoelectric conversion element. The photoelectric conversion element of the present invention includes a conductive film, a photoelectric conversion film, and a transparent conductive film, in this order, in which the photoelectric conversion film contains a compound represented by Formula (1), and an n-type organic semiconductor having a predetermined structure.

  本发明提供了一种光电转换元件，其在高速光电转换薄膜形成的情况下表现出优异的响应性和优秀的暗电流特性，以及包括该光电转换元件的光学传感器、成像元件和化合物。本发明的光电转换元件包括一个导电膜、一个光电转换膜和一个透明导电膜，按照这个顺序排列，其中光电转换膜含有一个由式（1）表示的化合物和一个具有预定结构的n型有机半导体。
• ORGANIC COMPOUND, ORGANIC LIGHT-EMITTING ELEMENT, DISPLAY APPARATUS, PHOTOELECTRIC CONVERSION APPARATUS, ELECTRONIC APPARATUS, LIGHTING APPARATUS, MOVING OBJECT, AND EXPOSURE LIGHT SOURCE
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20210070677A1

  公开（公告）日：2021-03-11

  An organic compound represented by formula [1] is provided. Ring A is a polycyclic aromatic hydrocarbon ring having a fluoranthene skeleton and having 16 to 60 carbon atoms and optionally has, as a substituent, a substituted or unsubstituted alkyl group or the like. Rings B 1 and B 2 are aromatic hydrocarbon rings having 6 to 18 carbon atoms and each have two or more electron withdrawing groups. Q 1 and Q 2 respectively represent one of the electron withdrawing groups of the ring B 1 and one of the electron withdrawing groups of the ring B 2 , and are respectively located at an ortho position of the ring B 1 and at an ortho position of the ring B 2 with respect to the ring A.

  提供了一个由化学式[1]表示的有机化合物。环A是一个具有芴骨架的多环芳烃环，含有16至60个碳原子，并且可选地具有取代或未取代的烷基基团等作为取代基。环B1和B2是具有6至18个碳原子的芳香烃环，每个环具有两个或更多的电子吸引基团。Q1和Q2分别表示环B1和环B2的一个电子吸引基团，并且分别位于环A相对于环B1的邻位和环B2的邻位。
• Open versus Closed Polyaromatic Nanocavity: Enhanced Host Abilities toward Large Dyes and Pigments
  作者：Takahiro Tsutsui、Shunsuke Kusaba、Masahiro Yamashina、Munetaka Akita、Michito Yoshizawa

  DOI：10.1002/chem.201806409

  日期：2019.3.21

  of the cage exhibited enhanced binding abilities toward large dyes and pigments in water. For example, two molecules of coumarin dyes were bound in the nanocavity and showed strong whitish emission (up to ΦF=34 %). Furthermore, metallopigments, the sizes of which are larger than the inner cavities of the cage and capsule, were bound only in the open polyaromatic nanocavity of the cage to give water‐soluble

  通过使用M 2 L 4分子笼和胶囊揭示了多芳香族纳米腔的宿主功能。在先前报道的带有封闭的多芳族腔的M 2 L 4胶囊的基础上，通过定量组装两个金属离子和四个具有非对称性的双吡啶配体，制备了一个新的M 2 L 4笼（作为异构体的混合物）。单聚芳烃板。所获得的开放的笼状纳米腔展示了对水中大型染料和颜料的增强的结合能力。例如，香豆素染料的两个分子在纳腔被束缚并表现出强烈的白色发射（最高Φ ˚F= 34％）。此外，金属色素的大小大于笼子和胶囊的内腔，仅结合在笼子的敞开的多环芳烃纳米腔中，以形成水溶性1：1的宿主-客体复合物。
• ORGANIC COMPOUND AND PHOTOELECTRIC CONVERSION ELEMENT
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20190119258A1

  公开（公告）日：2019-04-25

  An organic compound represented by the following general formula [1] is excellent in thermal stability. In the general formula [1], R 1 to R 12 are each independently selected from the group consisting of a hydrogen atom and a substituent. Symbol A is selected from the group consisting of a divalent residue of naphthalene, phenanthrene, fluorene, benzofluorene, dibenzofluorene or spirofluorene, and a heteroarylene group having 4 to 12 carbon atoms. Symbol B is selected from the group consisting of an arylene group having 6 to 25 carbon atoms and a heteroarylene group having 4 to 12 carbon atoms. Symbol n is an integer of 0 to 3.

  以下通用公式[1]所代表的有机化合物在热稳定性方面表现出色。在通用公式[1]中，R1到R12分别独立地选择自氢原子和取代基组成的群体。符号A从萘、菲、芴、苯并芴、二苯并芴或螺芴的双价残基，以及具有4到12个碳原子的杂芳基团中选择。符号B从具有6到25个碳原子的芳基团和具有4到12个碳原子的杂芳基团中选择。符号n为0到3之间的整数。