2-甲基戊烷-2,4-二基二乙酸酯 | 1637-24-7

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-甲基戊烷-2,4-二基二乙酸酯
• 英文名称: 2,4-diacetoxy-2-methylpentan
• 英文别名: 2,4-diacetoxy-2-methyl-pentane；2,4-Diacetoxy-2-methyl-pentan；2-methylpentane-2,4-diyl diacetate；2-methyl-2,4-pentanediyl diacetate；hexylene glycol diacetate；2-Methyl-2,4-pentanediol diacetate；(4-acetyloxy-4-methylpentan-2-yl) acetate
• CAS: 1637-24-7
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: PTPLKZHLDXVIBT-UHFFFAOYSA-N

物化性质

• 沸点：
  260.37°C (rough estimate)
• 密度：
  0.9751 (rough estimate)
• LogP：
  1.678 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2915390090

反应信息

• 作为产物：
  描述：

  2-甲基-2,4-戊二醇 、 乙酸酐 在 CoCl₂ 作用下， 以 乙腈 为溶剂， 反应 3.0h， 以79%的产率得到2-甲基戊烷-2,4-二基二乙酸酯
  参考文献：
  名称：

  新型酰化催化剂

  摘要：

  氯化钴（II）以优异的产率催化醇和胺与酸酐的酰化反应。

  DOI：

  10.1039/c39870000114

文献信息

• Iodine as an Acetyl Transfer Catalyst†
  作者：Ruli Borah、Nabajyoti Deka、Jadab C. Sarma

  DOI：10.1039/a605061a

  日期：——

  Iodine catalyses the acetylation of amines, phenols and alcohols, including tertiary ones, with acetic anhydride in excellent yield.

  碘催化胺类、酚类和醇类（包括叔醇）与乙酸酐的乙酰化反应，产率极高。
• LITHOGRAPHIC PRINTING PLATE PRECURSORS AND PROCESSES FOR PREPARING LITHOGRAPHIC PRINTING PLATES
  申请人：FUJIFILM Corporation

  公开号：US20150044612A1

  公开（公告）日：2015-02-12

  Lithographic printing plates and processes for preparing the lithographic printing plates are provided. The plates have excellent printing durability, staining resistance and staining resistance over time. The lithographic printing plate precursor includes: a substrate; a photosensitive layer provided on the substrate; and an extra layer optionally provided between the substrate and the photosensitive layer. The photosensitive layer or the extra layer adjacent to the substrate contains (A) a copolymer. The copolymer (A) includes: (a1) a repeating unit of formula (a1-1) below in a side chain, and (a2) a repeating unit having at least one of the structures represented by formulae (a2-1) to (a2-6) shown in the specification in a side chain. L 1 , Z 1 , R 1 , and R 21 , R 22 and R 23 in formula (a1-1) and the variables in formulae (a2-1) to (a2-6) are as defined in the specification.

  提供了用于制备平版印刷版和制备平版印刷版的过程。该版具有良好的印刷耐久性、耐污染性和随时间的污染性。平版印刷版的前体包括：基板；设置在基板上的感光层；以及可选地设置在基板和感光层之间的额外层。感光层或靠近基板的额外层包含(A)共聚物。共聚物(A)包括：(a1)公式(a1-1)的重复单元在侧链中，以及(a2)重复单元在侧链中至少具有公式(a2-1)到(a2-6)所表示的结构中的一个。公式(a1-1)中的L1、Z1、R1和R21、R22和R23以及公式(a2-1)到(a2-6)中的变量如规范中所定义。
• Cobalt(II) chloride catalyzed acylation of alcohols with acetic anhydride: scope and mechanism
  作者：Javed Iqbal、Rajiv Ranjan Srivastava

  DOI：10.1021/jo00033a020

  日期：1992.3

  Cobalt(II) chloride catalyzes the acetylation of a variety of alcohols with acetic anhydride in excellent yield. Primary hydroxyl groups can be selectively acylated in the presence of secondary and tertiary ones while the secondary hydroxyl groups can be preferentially acetylated in the presence of tertiary ones. Tertiary alcohols have been found to give ketones, acetoacetates, olefins, and diketene in addition to the acetate. The beta-hydroxy esters and ketones can be acylated under these conditions without any elimination, and this reaction has been compared with 4-(dimethylamino)pyridine (DMAP)-mediated acylations where elimination of the resulting beta-acetoxy carbonyl compound is observed. A detailed investigation of the acylation of tertiary alcohols has revealed that these reactions proceed via a tertiary alkoxy radical and ketene. A mechanism for these acylations is proposed by invoking an electron-transfer process.
• Process for producing esters
  申请人：STANDARD OIL DEV CO

  公开号：US02476053A1

  公开（公告）日：1949-07-12
• Esters of 2-Methyl-2,4-pentanediol¹
  作者：Philip F. Tryon

  DOI：10.1021/ja01196a510

  日期：1947.4