丙烯酸羟丙酯 | 999-61-1

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 丙烯酸羟丙酯
• 中文别名: 2-丙烯酸-2-羟基丙基酯；丙烯酸-β-羟丙酯；2-羟基丙基丙烯酸酯；丙烯酸2-羟丙酯；丙烯酸-&beta；-羟丙酯；丙烯酸-2-羟基丙酯
• 英文名称: 2-hydroxypropyl acrylate
• 英文别名: 2-hydroxypropyl prop-2-enoate
• CAS: 999-61-1
• 化学式: C₆H₁₀O₃
• mdl: MFCD00021900
• 分子量: 130.144
• InChiKey: GWZMWHWAWHPNHN-UHFFFAOYSA-N

物化性质

• 沸点：
  77°C 5mm
• 密度：
  1.06 g/cm3
• 溶解度：
  氯仿（微溶）、甲醇（微溶）
• 物理描述：
  Clear to light-yellow liquid with a sweetish, solvent odor; [NIOSH]
• 颜色/状态：
  Liquid
• 熔点：
  Vapor pressure
• 闪点：
  65 °C
• 蒸汽密度：
  Relative vapor density (air = 1): 4.5
• 蒸汽压力：
  0.174 mm Hg at 25 °C (est)
• 亨利常数：
  Henry's Law constant = 1.7X10-9 atm-cu m/mol at 25 °C (est)
• 稳定性/保质期：
  本品有毒。皮肤或眼睛接触时会引起中毒。在生产操作过程中必须佩戴防毒面具。工作环境中的允许浓度为3毫克/立方米。
• 分解：
  When heated to decomposition it emits acrid smoke and fumes.
• 聚合：
  If the material is subject to heat or becomes contaminated, it is liable to polymerize with the release of heat.
• 折光率：
  Index of refraction: 1.4470 at 20 °C/D

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

ADMET

毒理性

• 毒性总结

鉴定和使用：2-羟基丙基丙烯酸酯（HPA）是一种无色液体。它用于制造用于表面涂层的热固性树脂。人体研究：无数据可用。动物研究：向兔眼内滴入0.1毫升可迅速引起严重的眼部刺激和角膜损伤。在兔子上涂抹HPA会导致中度烧伤（即使是接触10%的水溶液）。在室温下7到8小时吸入饱和HPA蒸汽的大鼠存活下来，但在大约650 ppm HPA蒸汽（在100°C下产生）中暴露4小时的大鼠在暴露期间或暴露停止后1小时内死亡。在暴露期间注意到明显的眼部、鼻腔和呼吸道刺激迹象。当狗通过吸入5 ppm，每天6小时，每周5天，总共20或21天，在1个月期间内反复暴露时，观察到眼部、鼻腔和呼吸道刺激的迹象，并且在4只暴露动物中的3只中看到了组织学上的睾丸变化。对HPA进行了在Salmonella typhimurium TA102和TA2638菌株（使用代谢激活）和Escherichia coli WP2/pKM101和WP2 uvrA/pKM101菌株中的诱变性测试。它在Escherichia coli菌株中呈阳性。

IDENTIFICATION AND USE: 2-Hydroxypropyl acrylate (HPA) is a colorless liquid. It is used in manufacture of thermosetting resins for surface coatings. HUMAN STUDIES: There are no data available. ANIMAL STUDIES: Instillation of 0.1 mL in rabbit eye produced prompt, severe ocular irritation and corneal injury. In rabbits topical HPA application causes moderate burns (even when contacted as a 10% aqueous solution). Rats inhaling saturated HPA vapor generated at room temperature for 7 to 8 hours survived, but those exposed for 4 hours at approximately 650 ppm HPA vapor (generated at 100 °C) died either during exposure or within 1 hour after cessation of exposure. Marked signs of eye, nasal, and respiratory irritation were noted during the exposure period. When dogs were repeatedly exposed by inhalation at 5 ppm 6 hours/day, 5 days/week for a total of 20 or 21 days during a 1-month period, signs of ocular, nasal, and respiratory tract irritation were observed, and histologic testicular changes were seen in 3 of the 4 exposed animals. HPA was tested for mutagenicity in Salmonella typhimurium strains TA102 and TA2638 (with metabolic activation) and Escherichia coli strains WP2/pKM101 and WP2 uvrA/pKM101. It was found positive in the Escherichia coli strains.

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 暴露途径

这种物质可以通过皮肤接触和摄入被身体吸收，通过所有接触途径都可能导致严重的局部影响。

The substance can be absorbed into the body through the skin and by ingestion. Serious local effects by all routes of exposure.

来源:ILO-WHO International Chemical Safety Cards (ICSCs)

毒理性

• 暴露途径

吸入，皮肤吸收，吞食，皮肤和/或眼睛接触

inhalation, skin absorption, ingestion, skin and/or eye contact

来源:The National Institute for Occupational Safety and Health (NIOSH)

毒理性

• 症状

眼睛、皮肤、呼吸系统刺激；眼睛、皮肤烧伤；咳嗽、呼吸困难

irritation eyes, skin, respiratory system; eye, skin burns; cough, dyspnea (breathing difficulty)

来源:The National Institute for Occupational Safety and Health (NIOSH)

毒理性

• 吸入症状

咳嗽。喉咙痛。灼热感。呼吸急促。呼吸困难。

Cough. Sore throat. Burning sensation. Shortness of breath. Laboured breathing.

来源:ILO-WHO International Chemical Safety Cards (ICSCs)

吸收、分配和排泄

这些研究的目标是测量和解释2-羟基丙烯酸乙酯（HPA）作为与水完全混溶的模型化合物的皮肤透过性特征。方法：测量了HPA-H2O二元混合物通过人表皮和硅膜的物质传递。确定了这些混合物中HPA和H2O的热力学活度。还从具有恒定HPA活度但不同H2O活度的供体溶液中测量了透过表皮和硅胶的物质传递。确定了HPA-H2O混合物平衡时脱水人角质层（SC）的水摄取量。结果：HPA通过硅胶的稳态流量是HPA活度的线性函数，但与HPA浓度无关。另一方面，对于表皮来说，只有在HPA活度=0.35时，流量才会随着HPA活度的增加而增加。在恒定HPA活度下，当水活度从1降低到0.8时，流量减少了4.5倍。将SC与HPA-H2O混合物孵化导致SC水分含量发生显著变化，这取决于混合物的水活度，并与测量的SC水吸附数据一致。结论：这些实验为表皮屏障功能因SC脱水而显著增加提供了明确的证据。SC因脱水引起的改变似乎对观察到的流量特征负责。

The goal of these studies was to measure and interpret the skin permeability characteristics of 2-hydroxypropyl acrylate (HPA) as a model compound that is completely miscible with water. METHODS: In vitro permeation from HPA-H2O binary mixtures through human epidermis and silicone membranes was measured. Thermodynamic activities of HPA and H2O in these mixtures were determined. Permeation was also measured through epidermis and silicone from donor solutions with constant HPA activity but different H2O activities. Water uptake into desiccated human stratum corneum (SC) equilibrated with HPA-H2O mixtures was determined. RESULTS: Steady-state flux of HPA through silicone was a linear function of HPA activity but not HPA concentration. For epidermis on the other hand, flux increased with HPA activity only for HPA activities = 0.35. At constant HPA activity, flux decreased 4.5-fold as water activity decreased from 1 to 0.8. Incubation of SC with HPA-H2O mixtures resulted in substantial changes in SC water content, dependent on the water activity of the mixture and consistent with measured SC water sorption data. CONCLUSIONS: These experiments provide unequivocal evidence of a substantial increase in epidermal barrier function resulting from SC dehydration. Dehydration-related alterations in the SC appear responsible for the observed flux characteristics.

来源:Hazardous Substances Data Bank (HSDB)

安全信息

• 职业暴露等级：
  B
• 职业暴露限值：
  TWA: 0.5 ppm (3 mg/m3) [skin]
• 危险等级：
  8
• 安全说明：
  S26,S36/37/39,S45
• 危险类别码：
  R23/24/25
• 包装等级：
  II
• 危险类别：
  8
• 危险品运输编号：
  2927
• 储存条件：
  室温

SDS

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SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name : Hydroxypropyl acrylate
REACH No. : A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
CAS-No. : 999-61-1
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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SECTION 2: Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Category 1B), H314
Skin sensitisation (Category 1), H317
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
T Toxic R23/24/25
C Corrosive R34
R43
For the full text of the R-phrases mentioned in this Section, see Section 16.
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Danger
Hazard statement(s)
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
Precautionary statement(s)
P261 Avoid breathing vapours.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazard none
Statements
Other hazards - none

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SECTION 3: Composition/information on ingredients
Substances
Molecular Weight : 130,14 g/mol
CAS-No. : 999-61-1
EC-No. : 213-663-8
Index-No. : 607-108-00-2
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Hydroxypropyl acrylate
CAS-No. 999-61-1 Acute Tox. 3; Skin Corr. 1B; <= 100 %
EC-No. 213-663-8 Skin Sens. 1; H301 + H311 +
Index-No. 607-108-00-2 H331, H314, H317
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Hydroxypropyl acrylate
CAS-No. 999-61-1 T, R23/24/25 - R34 - R43 <= 100 %
EC-No. 213-663-8
Index-No. 607-108-00-2
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

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SECTION 4: First aid measures
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take
victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
no data available

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SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon dioxide (CO2)
Nature of decomposition products not known.
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
Use water spray to cool unopened containers.

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SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove
all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form
explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13). Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

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SECTION 7: Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.

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SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and 77 °C at 7 hPa
boiling range
g) Flash point 89 °C - closed cup
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower Lower explosion limit: 1,8 %(V)
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density 4,49 - (Air = 1.0)
m) Relative density 1,044 g/cm3
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
Relative vapour density 4,49 - (Air = 1.0)

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SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
Heat, flames and sparks.
Incompatible materials
Strong oxidizing agentsStrong oxidizing agents, Strong acids, Nitrates
Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5

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SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 250 mg/kg
LD50 Oral - mouse - 1.056 mg/kg
LD50 Dermal - rabbit - 167 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
May cause sensitisation by skin contact.
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and
skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,
pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,
Headache, Nausea

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SECTION 12: Ecological information
Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 3,1 mg/l - 96 h
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
Toxic to aquatic life.
no data available

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SECTION 13: Disposal considerations
Waste treatment methods
Product
This combustible material may be burned in a chemical incinerator equipped with an afterburner and
scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

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SECTION 14: Transport information
UN number
ADR/RID: 2922 IMDG: 2922 IATA: 2922
UN proper shipping name
ADR/RID: CORROSIVE LIQUID, TOXIC, N.O.S. (Hydroxypropyl acrylate)
IMDG: CORROSIVE LIQUID, TOXIC, N.O.S. (Hydroxypropyl acrylate)
IATA: Corrosive liquid, toxic, n.o.s. (Hydroxypropyl acrylate)
Transport hazard class(es)
ADR/RID: 8 (6.1) IMDG: 8 (6.1) IATA: 8 (6.1)
Packaging group
ADR/RID: II IMDG: II IATA: II
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

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SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

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SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
Acute Tox. Acute toxicity
H301 Toxic if swallowed.
H301 + H311 + Toxic if swallowed, in contact with skin or if inhaled
H331
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
Full text of R-phrases referred to under sections 2 and 3
T Toxic
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
Further information
Copyright 2013 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

制备方法与用途

化学性质
本品为色度低于30的透明液体，相对密度1.0536，沸点77℃（666.61Pa），折射率1.4443，闪点（开杯）100℃，凝固点低于-60℃。聚合物玻璃化温度为-70℃。它能溶解于水和一般有机溶剂，并且可以与水以任意比例混溶。

用途
本品可用于生产热固性涂料、胶粘剂、纤维处理剂以及合成树脂共聚物的改性剂，也可用作丙烯酸类树脂的主要交联性官能团单体之一。

生产方法
通过在催化剂和阻聚剂存在下将丙烯酸与环氧丙烷进行加成反应生成粗成品，再经过脱气、精馏过程得到最终产品。而丙烯酸则可通过丙烯的氧化或丙烯腈的水解制得。

反应信息

• 作为反应物：
  描述：

  丙烯酸羟丙酯 在 sodium hydroxide 、 叔丁醇 作用下， 以 水 为溶剂， 生成 2-hydroxypropyl acrylic acid ester radical anion
  参考文献：
  名称：

  Protonation kinetics of acrylate radical anions

  摘要：

  丙烯酰胺、甲基丙烯酰胺和丙烯酸 2-羟丙酯的自由基阴离子是通过脉冲辐射分解远低于自由基阴离子 pKa 的中等酸性水溶液产生的。质子化的速率系数是在质子化形式和离子形式的吸光度相差很大的波长下通过紫外动力学光谱测定的。测得的质子化速率系数分别为 (6.0±0.9)×1010、(6.6±1.0)×1010 和 (5.0±1.0)×1010 mol-1 dm3 s-1。利用这些速率系数和自由基阴离子的 pKa 值（7.9、8.0 和 5.5），确定了去质子化的速率系数分别为 7.5×102、6.6×102 和 1.6×105 s-1。结果清楚地表明，在酸性溶液中，质子化是与 H3O+ 而不是与 H2O 发生的。对测定的速率系数进行了讨论，并与文献中的相关数据进行了比较。

  DOI：

  10.1039/b000222o
• 作为产物：
  描述：

  2-乙烯基-4-甲基-1,3-二氧戊环 在 phthalic acid butyl ester 、 氧气 作用下， 生成 丙烯酸羟丙酯
  参考文献：
  名称：

  Autoxidation of 2-Alkenyldioxolanes and 2-Alkenyl-1,3-dioxanes

  摘要：

  DOI：

  10.1021/jo01025a007

文献信息

• QUENCHER
  申请人：Wako Pure Chemical Industries, Ltd.

  公开号：US20170342031A1

  公开（公告）日：2017-11-30

  A quencher is disclosed having a compound represented by the following general formula (1): wherein R 5 each independently represent a halogen atom, an alkyl group, an alkoxy group, an alkylthio group, an amino group having a substituent or not having a substituent, a hydroxy group, an aryl group, an aryloxy group, or an arylalkyl group; R 6 represents a group having a polymerizable unsaturated group, a hydroxy group, or the like; Y 1 represents an oxygen atom, or the like; An − represents an anion; Ar 1 represents a specific ring structure; * and ** represent binding positions; Ar 2 represents a benzene ring, a naphthalene ring, or an anthracene ring; n 1 represents a specific integer; and the following structure (1-10) in the general formula (1) is an asymmetric structure; (wherein R 5 , Y 1 , Ar 1 , Ar 2 , n 1 , * and ** are the same as described above.).

  一种淬灭剂被公开，该淬灭剂具有以下一般公式(1)表示的化合物： 其中R5各自独立代表一个卤素原子、一个烷基团、一个烷氧基团、一个烷硫基团、一个带有或不带有取代基的氨基团、一个羟基、一个芳基团、一个芳氧基团或一个芳烷基团；R6代表一个具有可聚合不饱和基团、一个羟基或类似基团的集团；Y1代表一个氧原子或类似；An代表一个阴离子；Ar1代表一个特定的环结构；*和**代表结合位置；Ar2代表一个苯环、一个萘环或一个蒽环；n1代表一个特定的整数； 并且一般公式(1)中的以下结构(1-10)是一个不对称结构； (其中R5、Y1、Ar1、Ar2、n1、*和**与上述描述相同)。
• PHENYL ISOCYANATE-BASED URETHANE ACRYLATES, PROCESSES FOR PRODUCING AND METHODS OF USING THE SAME
  申请人：Roelle Thomas

  公开号：US20100036013A1

  公开（公告）日：2010-02-11

  Urethane acrylates of the general Formula (I), corresponding salts, solvates or solvates of a salt thereof: wherein R 1 , R 2 , R 3 , R 4 and R 5 each independently represent a substituent selected from the group consisting of hydrogen, halogens, C 1-6 -alkyls, trifluoromethyl, C 1-6 -alkylthios, C 1-6 -alkylselenos, C 1-6 -alkyltelluros, and nitro groups, with the proviso that at least one of R 1 , R 2 , R 3 , R 4 and R 5 is not hydrogen; R 6 and R 7 each independently represent a substituent selected from the group consisting of hydrogen and C 1-6 -alkyls; and A represents a saturated or unsaturated or linear or branched C 1-6 -alkyl radical or a polyalkylene oxide radical having 2-6 ethylene oxide or propylene oxide units; processes for producing and methods of using the same.

  聚氨酯丙烯酸酯的通用公式(I)，相应的盐、溶剂或盐的溶剂： 其中R1、R2、R3、R4和R5各自独立地代表由氢、卤素、C1-6-烷基、三氟甲基、C1-6-硫代烷基、C1-6-亚磺酰基、C1-6-亚碲酰基和硝基组成的取代基，条件是至少R1、R2、R3、R4和R5中有一个不是氢；R6和R7各自独立地代表由氢和C1-6-烷基组成的取代基；A代表饱和或不饱和或直线或支链的C1-6-烷基自由基或具有2-6个环氧乙烷或环氧丙烷单元的聚醚自由基；以及生产和使用它们的方法。
• [EN] METALOXYPHTHALOCYANINE COMPOUNDS<br/>[FR] COMPOSES DE METALOXYPHTALOCYANINE
  申请人：AVECIA LTD

  公开号：WO2004020529A1

  公开（公告）日：2004-03-11

  A phthalocyanine compound of Formula (I) wherein M is an oxymetal group, methods and uses involving these compounds.

  一种配方（I）的邻苯二甲酸酞菁化合物，其中M是一个氧化金属基团，涉及这些化合物的方法和用途。
• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• [EN] POLYMERIZABLE COMPOSITION COMPRISING AN OXIME SULFONATE AS THERMAL CURING AGENT<br/>[FR] COMPOSITION POLYMÉRISABLE COMPRENANT UN SULFONATE D'OXIME EN TANT QU'AGENT DE DURCISSEMENT THERMIQUE
  申请人：BASF SE

  公开号：WO2012101245A1

  公开（公告）日：2012-08-02

  The present invention relates to a polymerizable composition comprising at least one ethylenically unsaturated, polymerizable compound and at least one oxime sulfonate compound of the formula (I) QAaBbCc where a is 0, 1, 2, 3, 4 or 6, b is 0, 1, 2, 3, 4 or 6, and c is 0, 1, 2, 3, 4 or 6, where the sum of a + b + c is 1, 2, 3, 4 or 6 where (A) is a group (B) is a group (C) is a group where # denotes the point of attachment to Q; X is S or NR14 and Q, R1, R2, R3 and R14 are as defined in claim 1 and in the description. The present invention also relates to the use of the this composition, to novel oxime sulfonates and the use of the oxime sulfonates as thermal curing promoter.

  本发明涉及一种可聚合的组成，包括至少一种乙炔基不饱和的可聚合化合物和至少一种具有公式（I）QAaBbCc的亚硝基亚磺酸酯化合物，其中a为0、1、2、3、4或6，b为0、1、2、3、4或6，c为0、1、2、3、4或6，其中a+b+c的总和为1、2、3、4或6，其中（A）是一个基团，（B）是一个基团，（C）是一个基团，其中#表示与Q连接的点；X是S或NR14，Q、R1、R2、R3和R14如权利要求1和说明书中所定义。本发明还涉及使用这种组成物，新型亚硝基亚磺酸酯及其作为热固化促进剂的应用。

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