1,5-二甲基-1-乙烯基己-4-烯基特戊酸酯 | 83846-55-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 1,5-二甲基-1-乙烯基己-4-烯基特戊酸酯
• 英文名称: Linalyl pivalate
• 英文别名: 1,5-Dimethyl-1-vinylhex-4-enyl pivalate；3,7-dimethylocta-1,6-dien-3-yl 2,2-dimethylpropanoate
• CAS: 83846-55-3
• 化学式: C₁₅H₂₆O₂
• 分子量: 238.37
• InChiKey: ZZYCDPNQWULUFL-UHFFFAOYSA-N

物化性质

• LogP：
  5.062 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  芳樟醇 、 二碳酸二叔丁酯 在 alkyl terminated dendronized cyclocopolymer 三乙胺 作用下， 以 1,2,3,4-四氢萘 、 环己烷 为溶剂， 反应 168.0h， 生成 1,5-二甲基-1-乙烯基己-4-烯基特戊酸酯
  参考文献：
  名称：

  Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification

  摘要：

  含有吡咯烷基吡啶侧基的环状共聚物经过树状聚合物化，使用了以长链烷基末端为终止基团的聚酯树状聚合物，树状聚合物所创造的微环境被用于催化三级醇与派瓦酸酐的困难酯化反应。

  DOI：

  10.1039/b307425k

文献信息

• Insecticidal properties of monoterpenoid derivatives to the house fly (diptera: Muscidae) and red flour beetle (coleoptera: Tenebrionidae)
  作者：Pamela J. Rice、Joel R. Coats

  DOI：10.1002/ps.2780410305

  日期：1994.7

  AbstractMonoterpenoid derivatives were synthesized and their insecticidal activities were evaluated against red flour beetles, Tribolium castaneum (Herbst), in fumigant bioassays and against house flies Musca domestica (L.) in topical, fumigant, and ovicidal bioassays. Acetate derivatives and haloacetate derivatives were compared with each other, and with the parent monoterpenoid to determine structure‐activity relationships. Acetate derivatives were more active than the propionate derivatives of cyclic monoterpenoids in the topical, fumigant, and ovicidal bioassays. Pivalates were topically more insecticidal than acetates to adult house flies, while the acetates had the greater ovicidal activity. Acetates and pivalates were more effective than haloacetates in the topical, red flour beetle fumigation and ovicidal bioassays. Fluoroacetates of cyclic monoterpenoids were the most effective house fly fumigants, followed by acetates, and trichloroacetates. Several derivatives were produced that displayed enhanced activity relative to the parent alcohols or phenols.
• Effects of Polymer Architecture and Nanoenvironment in Acylation Reactions Employing Dendritic (Dialkylamino)pyridine Catalysts
  作者：Brett Helms、Catherine O. Liang、Craig J. Hawker、Jean M. J. Fréchet

  DOI：10.1021/ma050701m

  日期：2005.6.1

  The role of architecture and nanoenvironment in the catalytic properties of dendritic polymers containing 4-(dialkylamino)pyridines was investigated in the context of acylation reactions employing sterically demanding tertiary alcohols as substrates. Frechet-type benzyl ether and aliphatic ester dendrimers were prepared in a convergent manner from a common trivalent core containing three DMAP groups while a linear polymer was dendronized with aliphatic esters using a divergent growth scheme. Catalysis experiments clearly indicate that nanoenvironment plays the dominant role in determining the activity of the polymer catalysts, with the polyester platform being superior to the benzyl ether. Polymer architecture played little or no role in affecting catalysis. With respect to molecular transport and catalysis, this represents the first comparative study of the effect of architecture and nanoenvironment using structurally similar dendritic materials.
• Dendronized cyclocopolymers with a radial gradient of polarity and their use to catalyze a difficult esterification
  作者：Catherine O. Liang、Brett Helms、Craig J. Hawker、Jean M. J. Fréchet

  DOI：10.1039/b307425k

  日期：——

  A cyclocopolymer containing pyrrolidinopyridine pendant groups was dendronized with polyester dendrons terminated with long alkyl chain ends and the microenvironment created by the dendrons was used to catalyze the difficult esterification of a tertiary alcohol with pivalic anhydride.

  含有吡咯烷基吡啶侧基的环状共聚物经过树状聚合物化，使用了以长链烷基末端为终止基团的聚酯树状聚合物，树状聚合物所创造的微环境被用于催化三级醇与派瓦酸酐的困难酯化反应。