6-苄氧基-2,6-二甲基-2,7-辛二烯 | 77611-58-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 6-苄氧基-2,6-二甲基-2,7-辛二烯
• 英文名称: O-benzyl rac-linalool
• 英文别名: 6-benzyloxy-2,6-dimethyl-2,7-octadiene；O-benzyllinalool；benzyl-(1,5-dimethyl-1-vinyl-hex-4-enyl)-ether；Benzyl-(1,5-dimethyl-1-vinyl-hex-4-enyl)-aether；Benzene, [[(1-ethenyl-1,5-dimethyl-4-hexenyl)oxy]methyl]-；3,7-dimethylocta-1,6-dien-3-yloxymethylbenzene
• CAS: 77611-58-6
• 化学式: C₁₇H₂₄O
• 分子量: 244.377
• InChiKey: KSXDSBMDJLSLSH-UHFFFAOYSA-N

物化性质

• 沸点：
  101 °C(Press: 0.2 Torr)
• 密度：
  0.919±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-苄氧基-2,6-二甲基-2,7-辛二烯 在 N-甲基二苯胺 [(PPP)PtMe]BF₄ 、 双三氟甲烷磺酰亚胺 、 丙酮 作用下， 以 硝基甲烷-d3 为溶剂， 反应 5.0h， 以5%的产率得到cis-4-(1-benzyloxy-1-methyl-ethyl)-1-methyl-bicyclo[3.1.0]hexane
  参考文献：
  名称：

  Cycloisomerization of Dienes with Carbophilic Lewis Acids:  Mimicking Terpene Biosynthesis with Pt(II) Catalysts

  摘要：

  Dicationic Pt(II) complexes containing triphosphine pincer ligands are excellent catalysts for the cycloisomerization of 1,6- and 1,7-dienes into bicyclopropane carbocycles. In analogy to the biosynthetic route to these monoterpene-like compounds, carbocation intermediates are proposed and supported by trapping experiments. Reactivation of the trapped intermediates indicates that cation generation by C-C bond formation is both rapid and reversible.

  DOI：

  10.1021/ol051277c
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 Lindlar's catalyst 、 lead containing palladium 、 Petroleum ether 作用下， 生成 6-苄氧基-2,6-二甲基-2,7-辛二烯
  参考文献：
  名称：

  Unsaturated tertiary ethers and preparation thereof

  摘要：

  公开号：

  US02841620A1

文献信息

• A regiospecific method for the hydrocyanation of olefins
  作者：Stephen L. Buchwald、Susan J. LaMaire

  DOI：10.1016/s0040-4039(00)95711-3

  日期：1987.1

  A convenient method for the anti-Markovnikov hydrocyanation of olefins utilizing organozirconium chemistry has been developed. This method has been shown to tolerate a wide range of functionality in the substrate olefin.

  已开发出一种利用有机锆化学方法进行烯烃抗马氏复合氢氰化的简便方法。已表明该方法可耐受底物烯烃中的多种官能度。
• BUCHWOLD S. L.; LA MAIRE S. J., TETRAHEDRON LETT., 28,(1987) N 3, 295-298
  作者：BUCHWOLD S. L.、 LA MAIRE S. J.

  DOI：——

  日期：——
• [EN] SAFE, ECO-FRIENDLY, HEALTH PROTECTIVE HERBAL COLOURS AND AROMA USEFUL FOR COSMACEUTICAL APPLICATIONS<br/>[FR] COLORANTS ET AROMES D'ORIGINE VEGETALE, ECOLOGIQUES ET SANS DANGER, PRESENTANT UN EFFET PROTECTEUR POUR LA SANTE, ET UTILES DANS DES APPLICATIONS COSMECEUTIQUES
  申请人：COUNCIL SCIENT IND RES

  公开号：WO2002078652A1

  公开（公告）日：2002-10-10

  The invention relates to a novel safe and eco-friendly health protective and beauty enhancing herbal compositions having various cosmetic applications such as lipsticks, eye shadows, glow-glitters and rouges, said compositions containing colourants from plants of the family Boraginaceae, the invention also provides a method for preparing the said compositions. The invention also relates the use of lipsticks as a medium of aromatherapy.
• Unsaturated tertiary ethers and preparation thereof
  申请人：HOFFMANN LA ROCHE

  公开号：US02841620A1

  公开（公告）日：1958-07-01
• Cycloisomerization of Dienes with Carbophilic Lewis Acids:  Mimicking Terpene Biosynthesis with Pt(II) Catalysts
  作者：William D. Kerber、Michel R. Gagné

  DOI：10.1021/ol051277c

  日期：2005.7.1

  Dicationic Pt(II) complexes containing triphosphine pincer ligands are excellent catalysts for the cycloisomerization of 1,6- and 1,7-dienes into bicyclopropane carbocycles. In analogy to the biosynthetic route to these monoterpene-like compounds, carbocation intermediates are proposed and supported by trapping experiments. Reactivation of the trapped intermediates indicates that cation generation by C-C bond formation is both rapid and reversible.