(-)-perillyl formate | 29621-55-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (-)-perillyl formate
• 英文别名: 4-(1-Methylvinyl)cyclohex-1-ene-1-methyl formate；(4-prop-1-en-2-ylcyclohexen-1-yl)methyl formate
• CAS: 29621-55-4
• 化学式: C₁₁H₁₆O₂
• 分子量: 180.247
• InChiKey: MMMXGGXIIWGLRU-UHFFFAOYSA-N

物化性质

• 沸点：
  240.4±29.0 °C(Predicted)
• 密度：
  0.976±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (-)-perillyl formate 在 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 反应 0.08h， 生成 1-亚甲基-4-(1-甲基乙烯基)环己烷 、 limonene.
  参考文献：
  名称：

  Chemoselective Removal of Allylic Formyloxy Group Using Sml₂

  摘要：

  A variety of allylic formates are chemoselectively transformed into the corresponding olefins in excellent yields on treatment with Sml2 in THF-HMPA-H2O (20:5:1), even though allylic acetate and allylic ether groups are present in the same molecule.

  DOI：

  10.1080/00397919508011375
• 作为产物：
  描述：

  紫苏醇 、 甲乙酐 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 0.83h， 以97%的产率得到(-)-perillyl formate
  参考文献：
  名称：

  Chemoselective Removal of Allylic Formyloxy Group Using Sml₂

  摘要：

  A variety of allylic formates are chemoselectively transformed into the corresponding olefins in excellent yields on treatment with Sml2 in THF-HMPA-H2O (20:5:1), even though allylic acetate and allylic ether groups are present in the same molecule.

  DOI：

  10.1080/00397919508011375

文献信息

• PRODUCTION OF A POLYMER EMULSION
  申请人：COATEX

  公开号：US20190264019A1

  公开（公告）日：2019-08-29

  The invention relates to a method for producing a polymer in water, comprising the preparation of an emulsion comprising a HASE-type copolymer and a mixture of a monomer comprising at least one polymerisable olefinic unsaturation and a radical-generating compound, followed by the polymerisation of the emulsified monomer by heating to a temperature higher than the temperature required for the polymerisation reaction. The invention also relates to the polymer produced in this way and to the use thereof.
• Chemoselective Removal of Allylic Formyloxy Group Using Sml₂
  作者：K. Shibuya、M. Shiratsuchi

  DOI：10.1080/00397919508011375

  日期：1995.2

  A variety of allylic formates are chemoselectively transformed into the corresponding olefins in excellent yields on treatment with Sml2 in THF-HMPA-H2O (20:5:1), even though allylic acetate and allylic ether groups are present in the same molecule.