N,N'-di(1-hexyl)perylene-3,4:9,10-bis(dicarboximid) | 25811-56-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-di(1-hexyl)perylene-3,4:9,10-bis(dicarboximid)
• 英文别名: N,N'-Dihexyl-3,4:9,10-perylenbis(dicarboximid)；N,N’-bis(hexyl)-3,4:9,10-perylenebis(dicarboximide)；2,9-Dihexylanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)tetrone；7,18-dihexyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 25811-56-7
• 化学式: C₃₆H₃₄N₂O₄
• 分子量: 558.677
• InChiKey: DAMUEXRCHXVMQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  42
• 可旋转键数：
  10
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  hexanal oxime 在 咪唑 、 红铝 作用下， 以 甲苯 为溶剂， 反应 8.0h， 生成 N,N'-di(1-hexyl)perylene-3,4:9,10-bis(dicarboximid)
  参考文献：
  名称：

  Demming, Stefan; Langhals, Heinz, Chemische Berichte, 1988, vol. 121, p. 225 - 230

  摘要：

  DOI：

文献信息

• Organic Light-Emitting Element, Organometallic Complex, Light-Emitting Device, Electronic Appliance, and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120264936A1

  公开（公告）日：2012-10-18

  Disclosed is a phosphorescent organometallic complex having: a 6-membered aromatic heterocycle having a nitrogen atom; iridium or platinum to which the nitrogen atom coordinates; and an aryl group which is bonded to an α-carbon of the nitrogen atom and is ortho-metalated with the iridium or platinum, where at least one of the aromatic heterocycle and the aryl group has an alicyclic hydrocarbon having an intramolecular carbon-carbon bridged bond as a substituent. The ability of the bulky structure of the alicyclic hydrocarbon to inhibit aggregation of the organometallic complex, concerted with the strong electron-donating property of the alicyclic hydrocarbon to the aromatic heterocycle or the aryl group, contributes to the increase in absorption coefficient and phosphorescent efficiency of the organometallic complex. The improved absorption coefficient and the phosphorescent efficiency allow the formation of a light-emitting element with excellent external quantum efficiency over 25%.

  本发明揭示了一种磷光有机金属配合物，其具有：含有氮原子的6元芳香杂环；氮原子与铱或铂配位；以及与氮原子的α-碳键合并与铱或铂发生邻位金属化的芳基基团，其中至少有芳香杂环和芳基基团中的一个具有作为取代基的脂环烃，其具有分子内碳-碳桥键。脂环烃的臃肿结构能够抑制有机金属配合物的聚集，与脂环烃对芳香杂环或芳基基团的强电子给体性质协同作用，有助于提高有机金属配合物的吸收系数和磷光效率。改进的吸收系数和磷光效率使得形成的发光元件具有优异的外部量子效率超过25%。
• HETEROCYCLIC COMPOUND
  申请人：Osaka Harue

  公开号：US20120197020A1

  公开（公告）日：2012-08-02

  Provided is a novel heterocyclic compound which can be used for a light-emitting element, as a host material of a light-emitting layer in which a light-emitting substance is dispersed. A heterocyclic compound represented by a general formula (G1) is provided. In the formula, A represents any of a substituted or unsubstituted dibenzothiophenyl group, a substituted or unsubstituted dibenzofuranyl group, and a substituted or unsubstituted carbazolyl group, R 11 to R 19 separately represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 14 carbon atoms, and Ar represents a substituted or unsubstituted arylene group having 6 to 13 carbon atoms.

  提供了一种新颖的杂环化合物，可用作发光元件，作为发光物质分散的发光层中的主体材料。提供了一个由通式（G1）表示的杂环化合物。在该式中，A代表取代或未取代的二苯并噻吩基团、取代或未取代的二苯并呋喃基团和取代或未取代的咔唑基团，R11至R19分别代表氢、具有1至4个碳原子的烷基基团，以及具有6至14个碳原子的取代或未取代的芳基基团，Ar代表具有6至13个碳原子的取代或未取代的芳基烯基团。
• Green and highly efficient synthesis of perylene and naphthalene bisimides in nothing but water
  作者：Bettina Baumgartner、Anastasiya Svirkova、Johannes Bintinger、Christian Hametner、Martina Marchetti-Deschmann、Miriam M. Unterlass

  DOI：10.1039/c6cc06567h

  日期：——

  A green one-pot hydrothermal route quantitatively generates high-purity fluorescence bisimide dyes without the need for catalysts or organic solvents.

  绿色的一锅法水热路线可定量生成高纯度的荧光双酰亚胺染料，而无需催化剂或有机溶剂。
• COMPOSITE MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, LIGHTING DEVICE, AND ORGANIC COMPOUND
  申请人：SEO Hiromi

  公开号：US20130009138A1

  公开（公告）日：2013-01-10

  A composite material including an organic compound and an inorganic compound, which has a high carrier-transport property; a composite material having an excellent property of carrier injection to an organic compound; a composite material in which light absorption due to charge transfer interaction is unlikely to occur; and a composite material having a high visible-light-transmitting property are provided. A composite material which includes an organic compound and an inorganic compound exhibiting an electron-accepting property with respect to the organic compound, in which the rings of the organic compound are all benzene rings and the number of the benzene rings of the organic compound is greater than or equal to 4 and less than or equal to 25, is provided.

  提供了一种复合材料，其中包括一种有机化合物和一种无机化合物，具有高载流子传输性能；一种具有对有机化合物的载流子注入性能的优异性能的复合材料；一种不太可能因电荷转移相互作用而发生光吸收的复合材料；以及一种具有高可见光透过性能的复合材料。提供了一种复合材料，其中包括一种有机化合物和一种对有机化合物具有电子受体性质的无机化合物，有机化合物的环都是苯环，有机化合物的苯环数大于或等于4且小于或等于25。
• Synthesis and Reactions of Perylenecarboxylic Acid Derivatives. VIII. Synthesis of<i>N</i>-Alkyl-3,4:9,10-Perylenetetracarboxylic Monoanhydride Monoimide
  作者：Yukinori Nagao、Takahisa Misono

  DOI：10.1246/bcsj.54.1191

  日期：1981.4

  The condensations of 3,4 : 9,10-perylenetetracarboxylic dianhydride with alkylamines (isobutyl-, pentyl-, hexyl-, and octylamines) were spectroscopically determined. Under all of the reaction conditions employed, N-alkyl-3,4 : 9,10-perylenetetracarboxylic monoanhydride monoimide (2a–d) (alkyl=a; isobutyl, b; pentyl, c; hexyl, d; octyl) were obtained. As the reaction proceeded, the yield of 2a–d increased at an initial stage but decreased gradually after reaching a maximum. This maximum yield of 2a–d was: 2a; 85–88%, 2b; 85–89%, 2c; 78–84%, 2d; 79–85%. The kinetics of the reaction were also examined.

  通过光谱测定3,4 : 9,10-苝四甲酸二酐与烷基胺（异丁基、戊基、己基和辛基胺）的缩合物。在所有反应条件下，均获得了N-烷基-3,4 : 9,10-苝四甲酸单酐单酰亚胺（2a–d）（烷基=a；异丁基、b；戊基、c；己基、d；辛基）。随着反应的进行，2a–d的产量在初始阶段增加，但在达到最大值后逐渐下降。2a–d的最大产量为：2a；85–88%，2b；85–89%，2c；78–84%，2d；79–