乙烯基异丁酸酯 | 2424-98-8

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 乙烯基异丁酸酯
• 英文名称: vinyl isobutyrate
• 英文别名: isobutyric acid vinyl ester；Isobuttersaeure-vinylester；2-methyl-propanoic acid, ethenyl ester；ethenyl 2-methylpropanoate
• CAS: 2424-98-8
• 化学式: C₆H₁₀O₂
• mdl: MFCD00152947
• 分子量: 114.144
• InChiKey: WNMORWGTPVWAIB-UHFFFAOYSA-N

物化性质

• 熔点：
  37.22°C (estimate)
• 沸点：
  123.66°C (estimate)
• 密度：
  0.8932

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  乙烯基异丁酸酯 、 苯硫酚 在 pseudomonas lipase 作用下， 以 甲苯 为溶剂， 反应 72.0h， 以66%的产率得到1-(phenylthio)ethyl 2-methylpropionate
  参考文献：
  名称：

  Synthesis of α-Arylthioalkyl Esters: The Addition Reactions of Vinyl Esters with Arylthiols Catalyzed by Lipase

  摘要：

  Abstractα‐Arylthioalkyl esters can be prepared by the addition reactions of vinyl esters with arylthiols in the presence of Pseudomonas lipase (PSL) as catalyst. In the toluene, the reaction mixtures were stirred at 60 °C for three days, the chemical yields up to 85% were obtained.

  DOI：

  10.1002/jccs.199700012
• 作为产物：
  描述：

  2-Acetyloxyethyl 2-methylpropanoate 在 methanolate 作用下， 以 gas 为溶剂， 生成 乙酸乙烯酯 、 乙烯基异丁酸酯
  参考文献：
  名称：

  Competitive reactivity as a probe for reaction coordinates in gas-phase ion-molecule chemistry

  摘要：

  Using the method of competitive reactivity of two functional groups in the same molecule, anionic elimination reactions show considerable kinetic selectivity for small differences in leaving group thermochemistry, in structures of the general type YCH(2)CH(2)CH(2)Z, where Y and Z are good anionic leaving groups. (C) 1997 by John Wiley & Sons, Ltd.

  DOI：

  10.1002/(sici)1099-1395(199707)10:7<585::aid-poc921>3.0.co;2-v

文献信息

• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• [EN] LIGHT HARVESTING ARRAY<br/>[FR] RÉSEAU COLLECTEUR DE LUMIÈRE
  申请人：FLUROSOL IND PTY LTD

  公开号：WO2015024064A1

  公开（公告）日：2015-02-26

  The invention relates to a light harvesting array or dye comprising an acceptor linked to a donor, wherein at least one of the acceptor or the donor is an oligomeric unit comprising a first optionally substituted rylene linked via a linker group to a second optionally substituted rylene, the first optionally substituted rylene is linked to the acceptor or the donor and the second optionally substituted rylene is capable of energy transfer to at least one of the first optionally substituted rylene, the acceptor or the donor. The invention also relates to compounds which may be used as light harvesting arrays, methods for their manufacture, and devices and materials comprising the light harvesting array or dye, for example, chromophoric materials, light guides, photobioreactors, photoluminescent algae systems, photodetectors, photovoltaic devices and luminescent/fluorescent solar concentrators.

  该发明涉及一种光收集阵列或染料，包括一个与给体相连的受体，其中受体或给体中至少有一个是包含第一可选择取代的芳香烃单元通过连接基团连接到第二可选择取代的芳香烃的寡聚单元，第一可选择取代的芳香烃与受体或给体相连，第二可选择取代的芳香烃能够将能量传递至第一可选择取代的芳香烃、受体或给体中的至少一个。该发明还涉及可用作光收集阵列的化合物，其制造方法，以及包括光收集阵列或染料的设备和材料，例如，色素材料、光导管、光生物反应器、光致发光藻类系统、光探测器、光伏器件和发光/荧光太阳能聚光器。
• [EN] PROCESSES AND INTERMEDIATES FOR PREPARING MCL1 INHIBITORS<br/>[FR] PROCÉDÉS ET INTERMÉDIAIRES POUR LA PRÉPARATION D'INHIBITEURS DE MCL1
  申请人：GILEAD SCIENCES INC

  公开号：WO2021108254A1

  公开（公告）日：2021-06-03

  The present disclosure provides methods for preparing MCL1 inhibitors or a salt thereof and related key intermediates.

  本公开提供了制备MCL1抑制剂或其盐及相关关键中间体的方法。
• NITRILEOXIDE COMPOUND
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US20180050983A1

  公开（公告）日：2018-02-22

  The present invention provides a compound of the formula (I): wherein, R 1 is a hydrogen atom or a hydrocarbon group; R 2 is —R 4 —R 5 ; R 3 is —R 4 —R 5 or —R 4 —R 6 ; R 4 is a divalent organic group; R 5 is OH, SH, COOH or NHR 9 ; R 9 is a hydrogen atom or an alkyl group having 1-6 carbon atoms; and R 6 is a hydrogen atom or an alkyl group having 1-6 carbon atoms.

  本发明提供了一种具有以下式（I）的化合物：其中，R1是氢原子或烃基；R2是—R4—R5；R3是—R4—R5或—R4—R6；R4是二价有机基；R5是OH、SH、COOH或NHR9；R9是氢原子或具有1-6个碳原子的烷基基团；R6是氢原子或具有1-6个碳原子的烷基基团。
• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。

表征谱图