(3Z)-3-癸烯-1-醇乙酸酯 | 81634-99-3

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (3Z)-3-癸烯-1-醇乙酸酯
• 英文名称: (Z)-3-decen-1-yl acetate
• 英文别名: (Z)-3-decen-1-ol acetate；Z-3-decen-1-yl acetate；(Z)-3-decenyl acetate；Z-3-decenyl acetate；(Z)-3-decen-1-yl-acetate；3-Decen-1-ol, acetate, (3Z)-；[(Z)-dec-3-enyl] acetate
• CAS: 81634-99-3
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: HYSSAOQHKOCKIC-HJWRWDBZSA-N

物化性质

• 沸点：
  256.2±19.0℃ (760 Torr)
• 密度：
  0.886±0.06 g/cm3 (20 ºC 760 Torr)
• 闪点：
  86.7±19.9℃
• LogP：
  4.541 (est)
• 保留指数：
  1376;1373.6

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sodium chlorodifluoroacetate 、 (3Z)-3-癸烯-1-醇乙酸酯 以89%的产率得到
  参考文献：
  名称：

  TAGUCHI, TAKEO;MORIKAWA, TSUTOMU;TAKIGAWA, TOMOYUKI;YOSHIZAWA, ATSUKO;TAW+, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1985, N 11, 2177-2184

  摘要：

  DOI：
• 作为产物：
  描述：

  辛烯 、 乙酸 -3-丁烯酯 在 C₃₅H₄₅N₃O₄Ru 作用下， 以 四氢呋喃 为溶剂， 50.0 ℃ 、2.5 kPa 条件下， 反应 2.0h， 以39%的产率得到(3Z)-3-癸烯-1-醇乙酸酯
  参考文献：
  名称：

  连续流动 Z-立体选择性烯烃复分解：在信息素和大环气味分子合成中的发展和应用**

  摘要：

  报道了第一个连续流动 Z-选择性烯烃复分解过程。Key to realizing this process was the adequate choice of stereoselective catalysts combined with the design of an appropriate continuous reactor setup. 设计的连续工艺允许各种自、交叉和大环闭环复分解反应，以高选择性和短停留时间提供产品。该技术通过直接应用于一系列信息素和大环气味分子的制备来举例说明，并在一个伸缩的 Z 选择性交叉复分解/迪克曼环化序列中达到高潮，以获取 ( Z )-Civetone，并结合一系列连续搅拌罐反应堆。

  DOI：

  10.1002/anie.202106410

文献信息

• Sexual attracting mixtures for Cossus cossus and their use
  申请人：Montedison S.p.A.

  公开号：EP0055475B1

  公开（公告）日：1985-11-21
• PHEROMONE DISPENSER
  申请人：Harmsen Sven

  公开号：US20110266361A1

  公开（公告）日：2011-11-03

  The present invention relates to a pheromone dispenser, filled with pheromone or a pheromone-comprising liquid and comprising (a) a deep-drawn plastic film made of a thermoplastic film material and featuring at least one dish-shaped zone for receiving a pheromone, and a planar plastic film made of a thermoplastic film material and which is connected with the deep-drawn plastic film, the planar plastic film together with the at least one dish-shaped zone of the deep-drawn plastic film forming a durably sealed chamber which comprises the pheromone or the pheromone-comprising liquid, and (c) a recess in the zone of the interconnected plastic films, the planar plastic film being permeable to the pheromone. The invention also relates to a process for producing such a pheromone dispenser.
• MICROORGANISMS FOR THE PRODUCTION OF INSECT PHEROMONES AND RELATED COMPOUNDS
  申请人：Provivi, Inc.

  公开号：US20220053774A1

  公开（公告）日：2022-02-24

  The present application relates to recombinant microorganisms useful in the biosynthesis of unsaturated C 6 -C 24 fatty alcohols, aldehydes, and acetates which may be useful as insect pheromones, fragrances, flavors, and polymer intermediates. The C 6 -C 24 fatty alcohols, aldehydes, and acetates described herein may be used as substrates for metathesis reactions to expand the repertoire of target compounds and pheromones. The application further relates to recombinant microorganisms co-expressing a pheromone pathway and a pathway for the production of a toxic protein, peptide, oligonucleotide, or small molecule suitable for use in an attract-and-kill pest control approach. Also provided are methods of producing unsaturated C 6 -C 24 fatty alcohols, aldehydes, and acetates using the recombinant microorganisms, as well as compositions comprising the recombinant microorganisms and/or optionally one or more of the product alcohols, aldehydes, or acetates.
• US4656032A
  申请人：——

  公开号：US4656032A

  公开（公告）日：1987-04-07
• US4715536A
  申请人：——

  公开号：US4715536A

  公开（公告）日：1987-12-29