Isolation of OH-bridged Ag(<scp>i</scp>)/Cu(<scp>iii</scp>) and ion-pair Cu(<scp>i</scp>)/Cu(<scp>iii</scp>) trifluoromethyl complexes with monophosphines
作者:Chang Xiao、Song-Lin Zhang
DOI:10.1039/c8dt03876g
日期:——
complex 3 exhibits a novel OH-bridged Ag(I)–Cu(III) dinuclear structure with XPhos-coordinated linear Ag(I) and square planar Cu(III) components. This is the first heterobimetallic Cu(III)–CF3 complex confirmed by both solution-phase NMR spectroscopy and solid state X-ray crystal structure analysis. Complex 3 is found to have the LUMO orbital of major σ*(Cu–CF3) nature and electrophilic CF3 ligands. Accordingly
[EN] SUBSTITUTED BENZAMIDES AND METHODS OF USE THEREOF<br/>[FR] BENZAMIDES SUBSTITUÉS ET LEURS MÉTHODES D'UTILISATION
申请人:GENENTECH INC
公开号:WO2015078374A1
公开(公告)日:2015-06-04
The invention provides compounds having the general formula I, and pharmaceutically acceptable salts thereof, wherein the variables RA, RAA, subscript n, ring A, X2, L, subscript m, X1, R1, R2, R3, R4, R5, and RN have the meaning as described herein, and compositions containing such compounds and methods for using such compounds and compositions.
Fluoroform-Derived CuCF<sub>3</sub>for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air
作者:Petr Novák、Anton Lishchynskyi、Vladimir V. Grushin
DOI:10.1002/anie.201201613
日期:2012.7.27
Easy does it: Arylboronicacids undergo smooth and selective trifluoromethylation with low‐cost fluoroform‐derived CuCF3 in DMF in non‐dried air. The reaction occurs under mild conditions (1 atm, room temperature), exhibits unprecedented functional‐group tolerance, and affords trifluoromethylated aromatic compounds in up to 99 % yield.
The present invention relates to compounds which are of use in the field of agriculture as fungicides.
本发明涉及在农业领域作为杀菌剂使用的化合物。
Substituted 3-Amino-Pyrrolidino-4-Lactams
申请人:Piotrowski David W.
公开号:US20070299076A1
公开(公告)日:2007-12-27
The invention provides compounds of formula (1),
and the pharmaceutically acceptable salt thereof, wherein R
1
, n and R
2
are as described herein; compositions thereof; and uses thereof.