1-氯-3-(3-氯苯氧基)苯 | 6903-62-4

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 芳香烃
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-氯-3-(3-氯苯氧基)苯
• 英文名称: 3,3'-dichlorodiphenyl ester
• 英文别名: 3,3'-dichlorodiphenyl ether；3,3'-Dichlordiphenylether；Benzene, 1,1'-oxybis[3-chloro-；1-chloro-3-(3-chlorophenoxy)benzene
• CAS: 6903-62-4
• 化学式: C₁₂H₈Cl₂O
• 分子量: 239.101
• InChiKey: RQMZSXZFMWCEET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-氯-3-(3-氯苯氧基)苯 在 四(三苯基膦)钯 、 potassium acetate 、 potassium carbonate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 三环己基膦 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 水 为溶剂， 反应 18.0h， 生成 2-[3-[3-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenoxy]phenyl]-4,6-diphenyl-1,3,5-triazine
  参考文献：
  名称：

  Compound and organic light-emitting element comprising same

  摘要：

  The present specification relates to a compound and an organic light emitting device comprising the same.

  公开号：

  US11730009B2
• 作为产物：
  描述：

  N-hydroxy-N'-[(2-oxoindol-3-yl)amino]methanimidamide 以1%的产率得到
  参考文献：
  名称：

  NORSTROEM A.; CHAUDHARY S. K.; ALBRO P. W.; MCKINNEY J. D., CHEMOSPHERE, 1979, 8, NO 6, 331-343

  摘要：

  DOI：

文献信息

• NHC–palladium-catalyzed ionic liquid-accelerated regioselective oxyarylation of alkynes with diaryl ethers
  作者：Jianxiao Li、Dan He、Zidong Lin、Liying Cen、Wanqing Wu、Huanfeng Jiang

  DOI：10.1039/d1gc04556c

  日期：——

  task-specific ionic liquid via C(sp3)–O and C(sp2)–O bond cleavage of two different types of ethers for the assembly of structurally diverse 4-arylisoxazoles is described. Both the basic ionic liquid [C3NH2mim]Br and NHC–Pd catalyst IPr–Pd–Im–Cl2 played an important role in this transformation. Notably, this new approach provides a practical and straightforward route to access a broad range of privileged 4-arylisoxazole

  第一次 NHC 钯催化的肟醚在特定任务的离子液体中通过C(sp 3 )-O 和 C(sp 2 )-O 键裂解两种不同类型的醚进行区域选择性氧芳基化，用于组装结构多样的 4描述了-芳基异恶唑。碱性离子液体 [C 3 NH 2 mim]Br 和 NHC-Pd 催化剂 IPr-Pd-Im-Cl 2在这一转变中发挥了重要作用。值得注意的是，这种新方法提供了一种实用且直接的途径，可以以良好的收率和出色的区域选择性获得广泛的特权 4-芳基异恶唑结构。值得注意的是，这种催化系统可以循环使用多达八次，而不会显着降低催化活性。
• Process for producing aromatic polyether ketones and polythioether ketones
  申请人：MITSUBISHI KASEI CORPORATION

  公开号：EP0135938A2

  公开（公告）日：1985-04-03

  A process for producing aromatic polyether ketones and polythioether ketones, which comprises reacting aromatic ethers or thioethers represented by the general formula: where each of R1 to R12 is a hydrogen atom, a halogen atom, a hydrocarbon group or an alkoxy group, n is an integer of 0 to 5, and X is an oxygen atom or a sulfur atom, with phosgene in aprotic solvent having a dielectric constant of lower than 20 and a dipole moment of lower than 3.0 in the presence of anhydrous halides of metals of Group III in the periodic table as a catalyst.

  一种生产芳香族聚醚酮和聚硫醚酮的工艺，它包括使通式所代表的芳香族醚或硫醚反应： 其中 R1 至 R12 各为氢原子、卤素原子、烃基或烷氧基，n 为 0 至 5 的整数，X 为氧原子或硫原子，在介电常数低于 20 和偶极矩低于 3.0 的无水光气溶剂中，以元素周期表中第 III 族金属的卤化物为催化剂进行反应。
• Large-diameter optical disk substrate made of polycarbonate, process for its production and mold therefore
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0155452A1

  公开（公告）日：1985-09-25

  The invention concerns a large-diameter optical disk substrate, a process for its production and an injection mold therefore.

  本发明涉及一种大直径光盘基板、其生产工艺和注塑模具。
• Process for the preparation of polyarylene sulfide and an apparatus for the preparation thereof
  申请人：Tonen Chemical Corporation

  公开号：EP0547718A2

  公开（公告）日：1993-06-23

  High molecular weight polyarylene sulfide is prepared by reacting an alkali metal sulfide with a dihaloaromatic compound in an organic amide solvent, wherein a gaseous phase part of a reactor is cooled to thereby condense a part of a gaseous phase in the reactor, and the condensed liquid is refluxed to a liquid phase in the reactor. Higher molecular weight is attained by copolymerization with 0.005 to 1.5 mole percent, based on the alkali metal sulfide, of a polyhaloaromatic compound.

  高分子量聚芳基硫醚的制备方法是：在有机酰胺溶剂中，使碱金属硫化物与二卤代芳香族化合物反应，冷却反应器的气相部分，从而冷凝反应器中的部分气相，冷凝液回流至反应器中的液相。通过与 0.005 至 1.5 摩尔百分数（以碱金属硫化物为基准）的多卤芳香族化合物共聚，可获得更高的分子量。
• Process for controlling a particle size of polyarylene sulfide and polyarylene sulfide thus produced
  申请人：Tonen Chemical Corporation

  公开号：EP0598449A2

  公开（公告）日：1994-05-25

  A particle size of polyarylene sulfide obtained in polymerization is controlled by a process characterized in that a gaseous phase part of a reactor is cooled or heated after starting decreasing a temperature of a reaction system o an end of precipitation of polyarylene sulfide formed In an embodiment, a water content in the reaction system is 0.8 to 1.7 moles per mole of the alkali metal sulfide; the gaseous phase part of the reactor is cooled in a polymerization stage to thereby condense a part of a gaseous phase in the reactor and the condensed liquid is refluxed to a liquid phase in the reactor; and the gaseous phase part is only cooled after starting decreasing the temperature of the reaction system, whereby high molecular weight polyarylene sulfide suitable for powder coating is formed, which has a weight average molecular weight of at least 30,000 and an average particle size of 50 to 80 µm, wherein particles of 40 to 150 µm account for at least 90 % by weight of the whole particles in a particle size distribution, and the amount of particles of 180 µm or more is 0.5 % 1by weight or less.

  聚合过程中获得的聚芳基硫醚的粒度由一种工艺控制，该工艺的特征在于，在开始降低反应体系的温度后，冷却或加热反应器的气相部分，直到形成的聚芳基硫醚沉淀结束。7摩尔/摩尔碱金属硫化物；在聚合阶段冷却反应器的气相部分，从而冷凝反应器中的部分气相，冷凝液在反应器中回流至液相；在开始降低反应系统的温度后才冷却气相部分，由此形成适合粉末涂料的高分子量聚芳基硫醚，其重量平均分子量至少为 30,000 和平均粒径为 50 至 80 微米，其中 40 至 150 微米的颗粒在粒径分布中至少占整个颗粒重量的 90%，180 微米或以上的颗粒量为 0.5 % 1 （按重量计）或更少。