2-(3-氯苯氧基)丙酰胺 | 5825-87-6

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 2-(3-氯苯氧基)丙酰胺
• 英文名称: 2-(3-chlorophenoxy)propanamide
• 英文别名: 2-[3-chlorophenoxy]propionamide；2-(3-Chlorophenoxy)propionamide
• CAS: 5825-87-6
• 化学式: C₉H₁₀ClNO₂
• mdl: MFCD00128023
• 分子量: 199.637
• InChiKey: QVTINYNCTADMES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(3-氯苯氧基)丙酰胺 在 potassium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 反应 6.0h， 以71%的产率得到3-氯苯胺
  参考文献：
  名称：

  Metal-free C–N bond-forming reaction: straightforward synthesis of anilines, through cleavage of aryl C–O bond and amide C–N bond

  摘要：

  An efficient metal-free C-N bond forming reaction through cleavage of aryl C-O bond and amide C-N bond has been developed. This process represents a practical method for the facile construction of anilines with a broad substrate scope and wide functional group tolerance in moderate to excellent yields. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.04.028

文献信息

• [EN] FUNGICIDAL 4-SUBSTITUTED-3-{PHENYL[(HETEROCYCLYLMETHOXY)IMINO]METHYL}-1,2,4-OXADIZOL-5(4H)-ONE DERIVATIVES<br/>[FR] DÉRIVÉS DE 3-{PHÉNYL[(HÉTÉROCYCLYLMÉTHOXY)IMINO]MÉTHYL}-1,2,4-OXADIZOL-5(4H)-ONE 4-SUBSTITUÉE FONGICIDES
  申请人：BAYER IP GMBH

  公开号：WO2013037717A1

  公开（公告）日：2013-03-21

  The present invention provides fungicidal 4-substituted-3-phenyl[(heterocyclylmethoxy)imino]methyl}-1,2,4-oxadiazol-5(4H)-one derivatives of formula (I) wherein A represents a pyridyl or thiazole group and X1, Y1 to Y5 represent independently different substituents.

  本发明提供了式(I)的杀真菌4-取代-3-苯基[(杂环甲氧基)亚胺]甲基}-1,2,4-噁二唑-5(4H)-酮衍生物，其中A代表吡啶基或噻唑基，X1、Y1至Y5代表独立不同的取代基。
• FUNGICIDAL 4-SUBSTITUTED-3--1,2,4-OXADIZOL-5(4H)-ONE DERIVATIVES
  申请人：Braun Christoph

  公开号：US20140349848A1

  公开（公告）日：2014-11-27

  The present invention provides fungicidal 4-substituted-3-phenyl[(heterocyclylmethoxy)imino]methyl}-1,2,4-oxadiazol-5(4H)-one derivatives of formula (I) wherein A represents a pyridyl or thiazole group and X1, Y1 to Y5 represent independently different substituents.

  本发明提供了式（I）的杀真菌4-取代-3- 苯基 [（杂环甲氧基）亚胺]甲基} -1,2,4-噁唑-5（4H）-酮衍生物，其中A代表吡啶基或噻唑基，X1，Y1至Y5分别代表不同的取代基。
• Intercalates and exfoliates formed with organic pesticide compounds and compositions containing the same
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0808568A1

  公开（公告）日：1997-11-26

  Intercalates formed by contacting an activated layered material, e.g., an activated phyllosilicate, with an intercalant pesticide to intercalate an intercalant pesticide between adjacent platelets of the layered material are disclosed. Sufficient intercalant pesticide is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water) up to about 100 Å, and preferably in the range of about 10 to about 45 Å, so that, if desired, the intercalate can be exfoliated into individual platelets. The intercalate can be combined with an organic liquid to form a viscous composition for delivery of a pesticide compound. Alternatively, the intercalate can be exfoliated prior to combination with the organic liquid. The intercalated complex also can be admixed with solid particles to provide a granular, dust, or wettable powder pesticide composition.

  本发明公开了通过将活化的层状材料（例如活化的叶硅酸盐）与插层剂杀虫剂接触，使插层剂杀虫剂在层状材料的相邻小板之间插层而形成的互化物。相邻小板之间吸附了足够的插层农药，使相邻小板之间的间距扩大到至少约 5 Å（按除水至最多 5%（重量）水后的测量值）至约 100 Å，最好在约 10 Å 至约 45 Å 的范围内，这样，如果需要，插层可以剥离成单个小板。夹层可以与有机液体结合，形成一种粘性组合物，用于输送农药化合物。或者，也可以在与有机液体结合之前将中间产物剥离。夹层复合物还可以与固体颗粒混合，形成颗粒状、粉尘状或可湿性粉末状农药组合物。
• Method and compositions for controlling release of organic compositions
  申请人：Boyd A. Stephen

  公开号：US20060157667A1

  公开（公告）日：2006-07-20

  A method and compositions using layered clays with monovalent potassium, ammonium or cesium ions in the galleries of the clay which are also occupied by a preferably polar or semi polar organic compound. The method and compositions are particularly useful for controlled release of pesticides, insecticides, herbicides, fungicides, nematocides and contaminants in the presence of calcium or magnesium, or other naturally occurring inorganic cations as divalent displacement ions providing the release.

  一种使用层状粘土的方法和组合物，粘土的廊道中含有单价钾离子、铵离子或铯离子，这些离子也被优选的极性或半极性有机化合物占据。在有钙或镁或其他天然存在的无机阳离子作为二价置换离子提供释放的情况下，这种方法和组合物特别适用于杀虫剂、杀虫剂、除草剂、杀真菌剂、杀线虫剂和污染物的控制释放。
• Novel herbicide resistance genes
  申请人：Dow AgroSciences, LLC

  公开号：EP1740039B1

  公开（公告）日：2012-06-27