Articles are disclosed in which an electrically conductive layer on a substrate exhibits a superconducting transition temperature in excess of 30.degree. K. Conductive layers are disclosed comprised of a crystalline rare earth alkaline earth copper oxide. Processes of preparing these articles are disclosed in which a mixed metal oxide precursor composition is coated and heated to its thermal decomposition temperature to create an amorphous mixed metal oxide layer. The amorphous layer is then heated to its crystallization temperature.
                            本文介绍了一种在基板上的电导层,其超导转变温度超过30度K。这些电导层由晶体稀土碱土
铜氧化物组成。本文还介绍了制备这些文章的过程,其中涂覆混合金属氧化物前体组成物,并加热至其热分解温度以创建非晶混合金属氧化物层。然后将非晶层加热至其结晶温度。