(2R/S,6R/S,10R/S)-2,6,10-trimethyldodecan-1-ol | 3511-93-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2R/S,6R/S,10R/S)-2,6,10-trimethyldodecan-1-ol
• 英文别名: 2,6,10-trimethyl-1-dodecanol；2,6,10-trimethyl-dodecan-1-ol；Octahydrosinensol；1-3h-Farnesol；2,6,10-trimethyldodecan-1-ol
• CAS: 3511-93-1
• 化学式: C₁₅H₃₂O
• 分子量: 228.418
• InChiKey: PSGOFVRXLFMCOL-UHFFFAOYSA-N

物化性质

• 沸点：
  279.2±8.0 °C(Predicted)
• 密度：
  0.831±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (2R/S,6R/S,10R/S)-2,6,10-trimethyldodecan-1-ol 在 chromium(VI) oxide 作用下， 以 乙醚 、 丙酮 为溶剂， 反应 1.0h， 生成 (2R/S,6R/S,10R/S)-methyl-2,6,10-trimethyldodecanoate
  参考文献：
  名称：

  摘要：

  Methyl 2,6,10-trimethyltridecanoate (1) and methyl 2,6,10-trimethyldodecanoate (2) have been identified as male-produced sex pheromones of the Brazilian soybean stink bugs Euschistus heros (F.) and Piezodorus guildinii (Westwood). In order to establish a defined attractive blend for both species, compounds 1 and 2 were synthesized as mixtures of stereoisomers to be employed in behavior bioassays. (+/-)-Citronellol (3) was utilized as starting material. and the syntheses was carried out in six steps with good overall yield. When tested alone, synthetic compounds 1 and 2 proved to be active in a two-choice olfactometer: however, a 20:1 mixture of 1 and 2 was much more attractive to E. heros females. A similar blend had been found among the headspace volatiles of males.

  DOI：

  10.1023/a:1026433608967
• 作为产物：
  描述：

  2-甲基丁醇 在 platinum(IV) oxide 叔丁基过氧化氢 、 sodium tetrahydroborate 、 selenium(IV) oxide 、 溴 、 magnesium 、 三苯基膦 、 水杨酸 作用下， 以 四氢呋喃 、 甲醇 、 正己烷 、 二氯甲烷 为溶剂， 20.0 ℃ 、172.37 kPa 条件下， 反应 37.25h， 生成 (2R/S,6R/S,10R/S)-2,6,10-trimethyldodecan-1-ol
  参考文献：
  名称：

  摘要：

  Methyl 2,6,10-trimethyltridecanoate (1) and methyl 2,6,10-trimethyldodecanoate (2) have been identified as male-produced sex pheromones of the Brazilian soybean stink bugs Euschistus heros (F.) and Piezodorus guildinii (Westwood). In order to establish a defined attractive blend for both species, compounds 1 and 2 were synthesized as mixtures of stereoisomers to be employed in behavior bioassays. (+/-)-Citronellol (3) was utilized as starting material. and the syntheses was carried out in six steps with good overall yield. When tested alone, synthetic compounds 1 and 2 proved to be active in a two-choice olfactometer: however, a 20:1 mixture of 1 and 2 was much more attractive to E. heros females. A similar blend had been found among the headspace volatiles of males.

  DOI：

  10.1023/a:1026433608967

文献信息

• Dry deodorant containing a sesquiterpene alcohol and zinc oxide
  申请人：Brahms John

  公开号：US20050191257A1

  公开（公告）日：2005-09-01

  A suspension product for reducing wetness under the arm which product comprises in % by weight based on the entire weight of the product: (a) 0.01-20% of a superabsorbent polymer with water absorbing capacity between 10-1000 g water/g superabsorber in the absence of added sodium chloride; (b) 0.05-10% of a sesquiterpene material; (c) 0.05-10% of a small particle size zinc oxide having a particle size range of 0.02-200 microns; (d) 2-88% of a volatile silicone, wherein the product is not made with any separately added water.

  一种用于减少腋下潮湿的悬浮产品，该产品按重量计，以产品总重量的百分比计， 包括：(a) 0.01-20%的超吸收聚合物，在不添加氯化钠的情况下，其吸水能力在 10-1000 克水/克超吸收剂之间；(b) 0.05-10%的倍半萜材料；(c) 0.05-10%的小粒径氧化锌，其粒径范围为 0.02-200 微米；(d) 2-88% 的挥发性有机硅，其中该产品不使用任何单独添加的水。
• Nakajima, Kenji; Sato, Akio; Takahara, Yoshimasa, Agricultural and Biological Chemistry, 1985, vol. 49, # 7, p. 1993 - 2002
  作者：Nakajima, Kenji、Sato, Akio、Takahara, Yoshimasa、Iida, Takeo

  DOI：——

  日期：——
• Volatiles from Oranges. III. The Structure of Sinensal¹
  作者：K. L. Stevens、R. E. Lundin、R. Teranishi

  DOI：10.1021/jo01016a529

  日期：1965.5
• [EN] DRY DEODORANT CONTAINING A SESQUITERPENE ALCOHOL AND ZINC OXIDE<br/>[FR] DESODORANT SEC CONTENANT UN ALCOOL DE SESQUITERPENE ET UN OXYDE DE ZINC
  申请人：COLGATE PALMOLIVE CO

  公开号：WO2005087181A2

  公开（公告）日：2005-09-22

  A suspension product for reducing wetness under the arm which product comprises in % by weight based on the entire weight of the product: (a) 0.01-20 % of a superabsorbent polymer with water absorbing capacity between 10-1000 g water/g superabsorber in the absence of added sodium chloride; (b) 0.05-10 % of a sesquiterpene material; (c) 0.05-10 % of a small particle size zinc oxide having a particle size range of 0.02-200 microns; (d) 2-88 % of a volatile silicone, wherein the product is not made with any separately added water.