heneicosa-6c,9c,12c,15c-tetraene | 54542-68-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: heneicosa-6c,9c,12c,15c-tetraene
• 英文别名: (6Z,9Z,12Z,15Z)-henicosa-6,9,12,15-tetraene
• CAS: 54542-68-6
• 化学式: C₂₁H₃₆
• 分子量: 288.517
• InChiKey: CVBGPGIEPHKALM-MAZCIEHSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  顺-3-壬烯-1-醇 在 六甲基磷酰三胺 、 lithium hexamethyldisilazane 作用下， 以 四氢呋喃 为溶剂， 生成 heneicosa-6c,9c,12c,15c-tetraene
  参考文献：
  名称：

  A convenient strategy for the synthesis of β,γ-unsaturated aldehydes and acids. A construction of skipped dienes

  摘要：

  A novel strategy is described for the synthesis of beta,gamma-unsaturated aldehydes which are the useful synthons for the synthesis of arachidonic acid and other eicosanoid products. These beta,gamma-unsaturated aldehydes have been used in the total synthesis of arachidonic acid. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01498-7

文献信息

• A convergent strategy toward linear cis-skipped polyenes
  作者：Jacqueline Sandri、Thierry Soto、Jean-Louis Gras、Jacques Viala

  DOI：10.1016/s0040-4039(97)01524-4

  日期：1997.9

  An easy preparation of symmetric Cis-skipped polyenic hydrocarbons 1 to 5 combining the controlled classical Wittig reaction or the oxidative dimerization of phosphoranes is described. (C) 1997 Elsevier Science Ltd.
• A convenient strategy for the synthesis of β,γ-unsaturated aldehydes and acids. A construction of skipped dienes
  作者：Goutam Saha、Manas K. Basu、Seongjin Kim、Young-Ju Jung、Yurdanur Adiyaman、Mustafa Adiyaman、William S. Powell、Garret A. FitzGerald、Joshua Rokach

  DOI：10.1016/s0040-4039(99)01498-7

  日期：1999.10

  A novel strategy is described for the synthesis of beta,gamma-unsaturated aldehydes which are the useful synthons for the synthesis of arachidonic acid and other eicosanoid products. These beta,gamma-unsaturated aldehydes have been used in the total synthesis of arachidonic acid. (C) 1999 Elsevier Science Ltd. All rights reserved.