癸二酸二癸酯 | 2432-89-5

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 癸二酸二癸酯
• 英文名称: Decanedioic acid didecyl ester
• 英文别名: Di-n-decyl sebacate；didecyl sebacate；decanedioic acid bis-decyl ester；Decandisaeure-bis-decylester；decanedioic acid, didecyl ester；Sebacinsaeure-di-n-decylester；didecyl decanedioate
• CAS: 2432-89-5
• 化学式: C₃₀H₅₈O₄
• 分子量: 482.788
• InChiKey: HTMDHERCQUESGS-UHFFFAOYSA-N

物化性质

• 沸点：
  500.02°C (rough estimate)
• 密度：
  0.9428 (rough estimate)
• 保留指数：
  3443

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  34
• 可旋转键数：
  29
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.933
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2917131000

反应信息

• 作为产物：
  描述：

  癸二酸 、 癸醇 在 对甲苯磺酸 作用下， 生成 癸二酸二癸酯
  参考文献：
  名称：

  Physical Constants and Infrared Spectra of a Homologous Series of Dialkyl Sebacates

  摘要：

  DOI：

  10.1021/ja01141a077

文献信息

• Waterproof plastic foam
  申请人：INOAC CORPORATION

  公开号：EP0714929A1

  公开（公告）日：1996-06-05

  The present invention provides a waterproof plastic foam such as waterproof polyurethane foam which can keep the inherent properties of the foam and exhibit low gas permeability and water absorption, excellent water-sealing properties and hence a stable waterproofness. A waterproof plastic foam obtained by a process which comprises foaming a foamable composition comprising a polyisocyanate, a compound containing at least two active hydrogen groups, a compound containing at least one ester bond, a catalyst, a blowing agent and a foam stabilizer, and then curing the foam is described, wherein the compound containing at least one ester bond is a product of the reaction of any one of a monocarboxylic acid having not less than 9 carbon atoms, an aliphatic dicarboxylic acid having not less than 8 carbon atoms and an alicyclic dicarboxylic acid having not less than 8 carbon atoms with a monoalcohol having not less than 10 carbon atoms, and the compound containing at least one ester bond is incorporated in an amount of from 7 to 100 parts by weight based on 100 parts by weight of the compound containing at least two active hydrogen groups. A waterproof plastic foam obtained by a process which comprises foaming a foamable composition comprising a polyisocyanate, a compound containing at least two active hydrogen groups, a compound containing ester bonds, a catalyst, a blowing agent and a foam stabilizer, and then curing the foam is also described, wherein the compound containing ester bonds is made of oleic acid and one component selected from the group consisting of butadiene polyol, adduct of bisphenol A with propylene oxides and castor oil, and the compound containing ester bonds is incorporated in an amount of from 7 to 100 parts by weight based on 100 parts by weight of the compound containing at least two active hydrogen groups.

  本发明提供了一种防水塑料泡沫塑料，如防水聚氨酯泡沫塑料，它能保持泡沫塑料的固有特性，并表现出低气体渗透性和低吸水性、优异的水封性能，因而具有稳定的防水性。本发明描述了一种防水塑料泡沫，其工艺包括发泡由多异氰酸酯、含有至少两个活泼氢基的化合物、含有至少一个酯键的化合物、催化剂、发泡剂和泡沫稳定剂组成的可发泡组合物，然后固化泡沫，其中含有至少一个酯键的化合物是具有不少于 9 个碳原子的单羧酸中任何一种的反应产物、不小于 8 个碳原子的脂肪族二羧酸和不小于 8 个碳原子的脂环族二羧酸与不小于 10 个碳原子的一元醇中的任意一种反应的产物，且含有至少一个酯键的化合物的掺入量为 7 至 100 重量份（以含有至少两个活性氢基的化合物的 100 重量份计）。还描述了一种防水塑料泡沫，其工艺包括发泡一种可发泡组合物，该组合物包括多异氰酸酯、含有至少两个活性氢基的化合物、含有酯键的化合物、催化剂、发泡剂和泡沫稳定剂，然后固化泡沫、其中，含酯键的化合物是由油酸和一种选自丁二烯多元醇、双酚 A 与氧化丙烯的加合物和蓖麻油组成的组的组分制成，含酯键的化合物的加入量为 7 至 100 重量份（以 100 重量份含至少两个活性氢基的化合物为基准）。
• Intercalates and exfoliates formed with oligomers and polymers and composite materials containing same
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0747451A2

  公开（公告）日：1996-12-11

  Nanocomposites are manufactured by combining a host material, such as an organic solvent or a matrix polymer and exfoliated intercalates formed by contacting a phyllosilicate with a polymer to adsorb or intercalate the polymer between adjacent phyllosilicate platelets. Sufficient polymer is adsorbed between adjacent phyllosilicate platelets to expand the adjacent platelets to a spacing of at least about 5 Å, preferably at least about 10 Å (as measured after water removal), up to about 100 Å and preferably in the range of about 30-40 Å, so that the intercalate easily can be exfoliated, e.g., when mixed with an organic solvent or a polymer melt, to provide a carrier material for drugs and the like, or to provide a matrix polymer/platelet composite (nanocomposite) material - the platelets being exfoliated from the intercalate.

  纳米复合材料的制造方法是将有机溶剂或基质聚合物等主体材料与剥离的插层材料相结合，剥离的插层材料是通过将植硅酸盐与聚合物接触，使聚合物吸附或插层在相邻的植硅酸盐小板之间而形成的。在相邻的纤维硅酸盐小板之间吸附足够的聚合物，使相邻的小板之间的间距扩大到至少约 5 Å，最好至少约 10 Å（脱水后测量），最大约 100 Å，最好在约 30-40 Å 的范围内，这样夹杂物就很容易剥离，例如、当与有机溶剂或聚合物熔体混合时，提供药物等的载体材料，或提供基质聚合物/小板复合（纳米复合）材料--小板从中间产物中剥离。
• Intercalates; exfoliates; process for manufacturing intercalates and exfoliates and composite materials containing same
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0747323A1

  公开（公告）日：1996-12-11

  Intercalates formed by mixing the phyllosilicate with a polymer and a liquid carrier, and extruding the mixture through a die-opening to adsorb or intercalate the polymer between adjacent phyllosilicate platelets. Sufficient polymer is adsorbed between adjacent phyllosilicate platelets to expand the adjacent platelets to a spacing of at least about 10 Å (as measured after water removal), up to about 55 Å and preferably in the range of about 30-40 Å, so that the intercalate easily can be exfoliated into individual platelets by heating the polymer to its melting point, to provide a matrix polymer/platelet composite material.

  将植硅酸盐与聚合物和液体载体混合，然后通过模头开口挤出混合物，使聚合物吸附或插层在相邻的植硅酸盐小板之间。 相邻的纤维硅酸盐小板之间吸附足够的聚合物，使相邻小板的间距扩大到至少约 10 Å（脱水后测量），最大约 55 Å，最好在约 30-40 Å 的范围内，这样，通过将聚合物加热到熔点，插层很容易剥离成单个小板，从而提供基质聚合物/小板复合材料。
• Intercalates and exfoliates formed with functional monomeric organic compounds; composite materials containing same and methods of modifying rheology therewith
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0780340A1

  公开（公告）日：1997-06-25

  Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer having a functionality selected from the group consisting of a hydroxyl; a polyhydroxyl; an aromatic ring; a carbonyl; a carboxylic acid; a polycarboxylic acid; an aldehyde; a ketone; an amine; an amide; an ether; an ester; and mixtures thereof, to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water), up to about 100 Å and preferably in the range of about 10-45 Å, so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix.

  将层状材料（如叶硅酸盐）与具有以下功能性的插层单体接触而形成的插层物：羟基；多羟基；芳香环；羰基；羧酸；多羧酸；醛；酮；胺；酰胺；醚；酯；及其混合物。在相邻小板之间吸附足够的插层单体，使相邻小板的间距扩大到至少约 5 Å（在除水至最大 5%（重量）水分后测量），最大约 100 Å，最好在约 10-45 Å 的范围内，这样插层单体就很容易剥离成单个小板。插层复合物可与有机液体结合成粘稠的载体材料，用于载体材料的输送或活性化合物的输送；或者插层复合物可与基质聚合物结合，形成坚固的填充聚合物基质。
• Exfoliated layered materials and nanocompositions comprising said exfoliated layered materials having water-insoluble oligomers or polymers adhered thereto
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0822163A2

  公开（公告）日：1998-02-04

  A phyllosilicate material is exfoliated by admixture of the phyllosilicate with water, and a solvent for a water-insoluble oligomer or polymer that is sorbed or electrostatically bonded to the inner surfaces of the phyllosilicate platelets after exfoliation of the phyllosilicate. Intercalation and exfoliation can be achieved via contact of the phyllosilicate with an organic solvent and water to electrostatically bond one or more polar moieties from the organic solvent to a metal cation on the platelet inner surfaces, so that after evaporation of the water used for intercalation of the organic solvent between phyllosilicate platelets, the platelets do not then collapse together, but remain exfoliated. -After exfoliation of the phyllosilicate, the exfoliated platelets are contacted with a polymer/carrier composition that includes a water-insoluble polymer or water-insoluble oligomer, and a solvent for the water-insoluble polymer or oligomer. After exfoliating the phyllosilicate and prior to polymer contact, the individual phyllosilicate platelets are contacted with the polymer/carrier composition to sorb the water-insoluble polymer or water-insoluble oligomer onto one or both surfaces of the exfoliated phyllosilicate platelets and drive off the adhered solvent.

  植物硅酸盐材料的剥离是通过将植物硅酸盐与水和不溶于水的低聚物或聚合物的溶剂混合，在植物硅酸盐剥离后，低聚物或聚合物被吸附或静电结合到植物硅酸盐小板的内表面。插层和剥离可通过有机溶剂和水接触来实现，从而使有机溶剂中的一个或多个极性分子与小板内表面的金属阳离子发生静电结合，这样在有机溶剂用于插层有机硅小板之间的水蒸发后，小板不会塌陷在一起，而是保持剥离状态。-植物硅酸盐剥离后，剥离的小板与聚合物/载体组合物接触，该组合物包括不溶于水的聚合物或不溶于水的低聚物，以及不溶于水的聚合物或低聚物的溶剂。在剥离植物硅酸盐后，在聚合物接触之前，将单个植物硅酸盐小板与聚合物/载体组合物接触，以将水不溶性聚合物或水不溶性低聚物吸附在剥离的植物硅酸盐小板的一个或两个表面上，并驱除附着的溶剂。

表征谱图