(Z)-3,3-dimethyl-1-(quinolin-2(1H)-ylidene)butan-2-imine | 1415752-93-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (Z)-3,3-dimethyl-1-(quinolin-2(1H)-ylidene)butan-2-imine
• CAS: 1415752-93-0
• 化学式: C₁₅H₁₈N₂
• 分子量: 226.321
• InChiKey: NDJIJDQUBKMJSK-ZNIRDAAXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.08
• 重原子数：
  17.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  35.88
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (Z)-3,3-dimethyl-1-(quinolin-2(1H)-ylidene)butan-2-imine 在 一水合肼 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 生成 (1Z,2Z)-1,2-bis(3,3-dimethyl-1-(quinolin-2-yl)butan-2-ylidene)hydrazine
  参考文献：
  名称：

  Tautomerism in 2-ketomethylquinolineazines

  摘要：

  A series of new azines were prepared in three steps. Structures of all compounds have been elucidated using spectroscopic methods and elemental analysis. Our studies show that in chloroform solution generally two tautomeric forms are in equilibrium. In some cases, one tautomer was the dominant species. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.05.034
• 作为产物：
  描述：

  2-甲基喹啉 、 三甲基乙腈 在 氮 、 苯基锂 作用下， 以 乙醚 为溶剂， 生成 (Z)-3,3-dimethyl-1-(quinolin-2(1H)-ylidene)butan-2-imine
  参考文献：
  名称：

  Tautomerism in 2-ketomethylquinolineazines

  摘要：

  A series of new azines were prepared in three steps. Structures of all compounds have been elucidated using spectroscopic methods and elemental analysis. Our studies show that in chloroform solution generally two tautomeric forms are in equilibrium. In some cases, one tautomer was the dominant species. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.05.034