2-{2-[4-(9-{4-[2-(2-Hydroxy-ethoxy)-ethoxy]-phenyl}-[1,10]phenanthrolin-2-yl)-phenoxy]-ethoxy}-ethanol | 184959-54-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-{2-[4-(9-{4-[2-(2-Hydroxy-ethoxy)-ethoxy]-phenyl}-[1,10]phenanthrolin-2-yl)-phenoxy]-ethoxy}-ethanol
• 英文别名: 2-[2-[4-[9-[4-[2-(2-Hydroxyethoxy)ethoxy]phenyl]-1,10-phenanthrolin-2-yl]phenoxy]ethoxy]ethanol
• CAS: 184959-54-4
• 化学式: C₃₂H₃₂N₂O₆
• 分子量: 540.616
• InChiKey: DABOVXQTORBEAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  40
• 可旋转键数：
  14
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  103
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2-{2-[4-(9-{4-[2-(2-Hydroxy-ethoxy)-ethoxy]-phenyl}-[1,10]phenanthrolin-2-yl)-phenoxy]-ethoxy}-ethanol 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 生成
  参考文献：
  名称：

  通过闭环复分解合成链烷结构。

  摘要：

  这项研究对通过闭环复分解获得链烷结构的合成策略进行了详细描述。该方法基于包含邻烯基单元的基于菲咯啉的配体，该配体被设计为围绕铜原子以四面体排列进行配位。用钌催化剂1处理组装的铜络合物，可得到[2] cateates，产率高，达88-92％。脱金属以几乎定量的产率产生了相应的[2]类别。用Crabtree催化剂将链烷烃氢化，然后脱金属，得到完全饱和的链烷烃。由于合成途径由市售的1,10-菲咯啉组成的六个步骤（方案2和4）组成，因此目前描述的程序使[2]邻苯二酚非常容易获得，总收率为51％。

  DOI：

  10.1021/jo990268c
• 作为产物：
  描述：

  1,10-菲罗啉 在 叔丁基锂 、 吡啶盐酸盐 、 caesium carbonate 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 生成 2-{2-[4-(9-{4-[2-(2-Hydroxy-ethoxy)-ethoxy]-phenyl}-[1,10]phenanthrolin-2-yl)-phenoxy]-ethoxy}-ethanol
  参考文献：
  名称：

  通过闭环复分解合成链烷结构。

  摘要：

  这项研究对通过闭环复分解获得链烷结构的合成策略进行了详细描述。该方法基于包含邻烯基单元的基于菲咯啉的配体，该配体被设计为围绕铜原子以四面体排列进行配位。用钌催化剂1处理组装的铜络合物，可得到[2] cateates，产率高，达88-92％。脱金属以几乎定量的产率产生了相应的[2]类别。用Crabtree催化剂将链烷烃氢化，然后脱金属，得到完全饱和的链烷烃。由于合成途径由市售的1,10-菲咯啉组成的六个步骤（方案2和4）组成，因此目前描述的程序使[2]邻苯二酚非常容易获得，总收率为51％。

  DOI：

  10.1021/jo990268c

文献信息

• A transition metal ion assembled catenane bearing linearly-arranged donor and acceptor porphyrins
  作者：David B. Amabilino、Jean-Pierre Sauvage

  DOI：10.1039/cc9960002441

  日期：——

  A new bis(porphyrin) has been synthezised in which a catenane is used as a spacer between the two chromophores, the donor and acceptor porphyrins being located as pendant groups, arranged linearly on each side of the catenane core.

  我们合成了一种新型双（卟啉），其中使用了一个烯烷作为两个发色团之间的间隔，供体卟啉和受体卟啉作为悬垂基团，线性排列在烯烷核心的两侧。
• Templated Synthesis of Highly Stable, Electroactive, and Dynamic Metal–DNA Branched Junctions
  作者：Hua Yang、Hanadi F. Sleiman

  DOI：10.1002/anie.200703741

  日期：2008.3.14
• High-Yield Synthesis of[2] Catenanes by Intramolecular Ring-Closing Metathesis
  作者：Bernhard Mohr、Jean-Pierre Sauvage、Robert H. Grubbs、Marcus Weck

  DOI：10.1002/anie.199713081

  日期：1997.7.4
• Xue, Zheng; Mayers, Michael F., Journal of the American Chemical Society, 2010, vol. 132, p. 3274 - 3276
  作者：Xue, Zheng、Mayers, Michael F.

  DOI：——

  日期：——
• Convergent Synthesis and Photoinduced Processes in Multi-Chromophoric Rotaxanes
  作者：Jackson D. Megiatto、Ke Li、David I. Schuster、Amit Palkar、M. Ángeles Herranz、Luis Echegoyen、Silke Abwandner、Gustavo de Miguel、Dirk M. Guldi

  DOI：10.1021/jp101154k

  日期：2010.11.18

  A series of [2]rotaxane materials, in which [60]fullerene is linked to a macrocycle and ferrocene (Fc) moieties are placed at the termini of a thread, both of which possess a central Cu(I)-1,10-phenanthroline [Cu(phen)(2)](+) complex, were synthesized by self-assembly using Sauvage metal template methodology Two types of threads were constructed one with terminal ester linkages and a second with terminal 1,2,3-triazole linkages derived from Cu(I)-catalyzed "click' 1,3-cycloaddition reactions Model compounds lacking the fullerene moiety were prepared in an analogous manner The ability of the interlocked Fc-[Cu(phen)(2)](+)-C-60 hybrids to undergo electron transfer upon photoexcitation in benzonitrile, dichloromethane, and ortho-dichlorobenzene was investigated by means of time-resolved fluorescence and transient absorption spectroscopy, using excitation wavelengths directed at the fullerene and [Cu(phen)(2)](+) subunits The energies of the electronic excited states and charge separated (CS) states that might be formed upon photoexcitation were determined from spectroscopic and electrochemical data These studies showed that MLCT excited states of the copper complex in the fullerenerotaxanes were quenched by electron transfer to the fullerene in benzonitrile, resulting in charge separated states with oxidized copper and reduced fullerene moieties, (Fc)(2)-[Cu(phen)(2)](2+)-C-60 (-) Even though electron transfer from Fe to the oxidized copper complex is predicted to be exergonic by 0 16 to 0 20 eV, no unequivocal evidence in support of such a process was obtained The conclusion that Fe plays no role in the photoinduced processes in our systems rests on the lack of enhancement of the lifetime of the charge separated state, as measured by decay of C-60 (-) at similar to 1000 nm, since one-electron oxidized Fe is very difficult to detect spectroscopically in the 500-800 nm spectral region