[2-(2-[2-(3,5,6-trimethyl-1,4-benzoquinon-2-yl)thioethoxycarbonyl]vinyl)-5,10,15,20-tetraphenylporphyrinato]manganese(III) acetate | 168297-51-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮
• 英文名称: [2-(2-[2-(3,5,6-trimethyl-1,4-benzoquinon-2-yl)thioethoxycarbonyl]vinyl)-5,10,15,20-tetraphenylporphyrinato]manganese(III) acetate
• CAS: 168297-51-6
• 化学式: C₂H₃O₂*C₅₈H₄₂MnN₄O₄S
• 分子量: 1005.04
• InChiKey: GFZPLUJWQLMUJJ-OSPKFNJNSA-K

反应信息

• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 2-(2-[2-(3,5,6-trimethyl-1,4-benzoquinon-2-yl)thioethoxycarbonyl]vinyl)-5,10,15,20-teraphenylporphyrin 以 甲醇 、 氯仿 为溶剂， 以80%的产率得到[2-(2-[2-(3,5,6-trimethyl-1,4-benzoquinon-2-yl)thioethoxycarbonyl]vinyl)-5,10,15,20-tetraphenylporphyrinato]manganese(III) acetate
  参考文献：
  名称：

  Synthesis and catalytic properties of manganese complexes of substituted tetraphenylporphyrins in the stereoselective hydroxylation of cholesterol

  摘要：

  Manganese(III) complexes of 5-(p-aminophenyl)-10,15,20-triphenylporphyrin, 2-(2-carboxyvinyl)-5,10,15,20-tetraphenylporphyrin, and their derivatives containing electron-donor and electron-acceptor substituents have been synthesized. Manganese(III) porphyrinates (PMn) are catalytically active in the stereoselective hydroxylation of cholesterol to form 3 beta,5 alpha-cholestanediol. The influence of substitutents in the porphyrin ring on the ability of PMn to associate in solution, the hydroxylation rate constants, and the turnover number of the catalyst are discussed.

  DOI：

  10.1007/bf00697151