1,4-bis(2-[1,10]-phenanthrolinyl)benzene | 176853-51-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1,4-bis(2-[1,10]-phenanthrolinyl)benzene
• 英文别名: 1,4-di(1,10-phenanthroline-2-yl)benzene；2-[4-(1,10-Phenanthrolin-2-yl)phenyl]-1,10-phenanthroline
• CAS: 176853-51-3
• 化学式: C₃₀H₁₈N₄
• 分子量: 434.5
• InChiKey: VQYDFPFSXHGHOD-UHFFFAOYSA-N

物化性质

• 沸点：
  730.9±55.0 °C(Predicted)
• 密度：
  1.319±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  34
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 cis-[bis(D8-2,2'-bipyridine)dichlororuthenium(II)] dihydrate 、 1,4-bis(2-[1,10]-phenanthrolinyl)benzene 以 乙醇 、 水 为溶剂， 以99%的产率得到[Ru(2,2'-bipyridine-d8)2(1,4-bis(2-[1,10]-phenanthrolinyl)benzene)Ru(2,2'-bipyridine-d8)2](PF6)4
  参考文献：
  名称：

  Wu, Feiyue, Inorganic Chemistry, 1999, vol. 38, # 24, p. 5620 - 5628

  摘要：

  DOI：
• 作为产物：
  描述：

  7-甲基-8-硝基喹啉 在 盐酸 、 氢氧化钾 、 sodium periodate 、 铁粉 作用下， 以 四氢呋喃 、 乙醇 、 水 、 溶剂黄146 、 N,N-二甲基甲酰胺 为溶剂， 反应 39.67h， 生成 1,4-bis(2-[1,10]-phenanthrolinyl)benzene
  参考文献：
  名称：

  弗里德兰德方法学引入苯并[h]喹啉和1,10-菲咯啉亚基。

  摘要：

  已经开发了改进的8-氨基-7-喹啉甲醛的制备方法。通过先用二甲基甲酰胺二甲基乙缩醛，然后用高碘酸钠处理，可以将7-甲基-8-硝基喹啉的甲基氧化为醛。用铁还原得到氨基醛。类似的序列得到1-氨基-2-萘甲醛。喹啉衍生物与一系列乙酰基芳烃的弗里德兰德缩合反应提供了相应的2-芳基-1,10-菲咯啉。氨基醛与1,3-二乙酰基苯或2,6-二乙酰基吡啶的缩合可提供预期的Friedländer产品。对于氨基醛与1,4-二乙酰基苯，4,4'-二乙酰基联苯，1,5-二乙酰基蒽，1,2,3,4,5,6,7,8-八氢ac啶-1的反应描述了相似的化学方法8-dione和四环[6.3.0.0。（4,11）0（5，

  DOI：

  10.1021/jo952164h

文献信息

• ORGANOSULFUR COMPOUND, PROCESS FOR PRODUCING THE SAME, AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING THE SAME
  申请人：Kido Junji

  公开号：US20110140044A1

  公开（公告）日：2011-06-16

  Disclosed is an organosulfur compound denoted by a general formula (a1): in which A denotes —S—, —S(O)— or —S(O) 2 —; Z 1 and Z 4 denote a trivalent aromatic hydrocarbon group or the like; Z 2 and Z 3 denote a bivalent aromatic hydrocarbon group or the like; Ar 1 , Ar 2 , Ar 3 and Ar 4 denote an aromatic hydrocarbon group or the like; and n is 0 or 1, or a general formula (b1): in which A denotes the same meaning as aforesaid; Z 5 denotes a trivalent aromatic hydrocarbon group or the like; Ar denotes a m-valent aromatic hydrocarbon group or the like; Ar 1 and Ar 2 denote the aforesaid meaning; and m is 2 or 3. This compound is useful as an electron transport material, a hole blocking material or a host material of an organic electroluminescence element.

  本发明公开了一种有机硫化合物，其通式为（a1）：其中A表示—S—、—S(O)—或—S(O)2—；Z1和Z4表示三价芳香烃基或类似物；Z2和Z3表示二价芳香烃基或类似物；Ar1、Ar2、Ar3和Ar4表示芳香烃基或类似物；n为0或1，或通式为（b1）：其中A表示如上所述的相同含义；Z5表示三价芳香烃基或类似物；Ar表示m价芳香烃基或类似物；Ar1和Ar2表示如上所述的含义；m为2或3。该化合物可用作电子传输材料、阻挡孔洞材料或有机电致发光元件的主体材料。
• Material for Light Emitting Device and Light Emitting Device
  申请人：Kitazawa Daisuke

  公开号：US20070267958A1

  公开（公告）日：2007-11-22

  The invention provides a light emitting device having a low driving voltage and excellent durability by a material for a light emitting device expressed by the general formula (1): where in each of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 may be the same or different and is selected from hydrogen, an alkyl group, and an aryl group, A represents an n-valent aromatic hydrocarbon group, B represents an alkyl group or an aryl group, X represents carbon or nitrogen, n represents a natural number from 2 to 6, and n substituents having a phenanthroline skeleton or a benzoquinoline skeleton may be the same or different.

  本发明提供了一种具有低驱动电压和优异耐久性的发光装置，其使用的发光装置材料由通式（1）表示，其中R1、R2、R3、R4、R5和R6中的每一个可以相同也可以不同，并且被选择为氢、烷基或芳基，A代表n价芳香族碳氢化合物基团，B代表烷基或芳基，X代表碳或氮，n代表从2到6的自然数，n个具有菲咯啉骨架或苯并喹啉骨架的取代基可以相同也可以不同。
• POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE COMPLEX AND SOLID POLYMER-TYPE FUEL CELL EACH PRODUCED USING SAME
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150295262A1

  公开（公告）日：2015-10-15

  The present invention provides: a polymer electrolyte composition which can achieve excellent proton conductivity under slightly humidified conditions, excellent mechanical strength and excellent physical durability, has excellent practicality, and can be produced using a nitrogen-containing additive, wherein the nitrogen-containing additive can prevent the elution of the additive under a strongly acidic atmosphere during the operation of a fuel cell, has excellent chemical stability so as to tolerate a strongly acidic atmosphere, can be dissolved in various general-purpose organic solvents, has superior processability, can be mixed with an ionic-group-containing polymer, can prevent the occurrence of phase separation during the formation of a film, and can prevent the formation of an island-in-sea-like phase separation structure or the occurrence of bleeding out during the formation of a film; and a polymer electrolyte membrane, a membrane electrode assembly and a polymer electrolyte fuel cell, each of which is produced using the polymer electrolyte composition. The polymer electrolyte composition according to the present invention comprises at least an ionic-group-containing polymer (A) and a nitrogen-containing additive (B), said polymer electrolyte composition being characterized in that the nitrogen-containing additive (B) is represented by a specific structural formula.

  本发明提供了一种聚合物电解质组成物，该组成物在轻微湿润条件下能够实现优异的质子导电性能、优异的机械强度和优异的物理耐久性，具有优异的实用性，并且可以使用含氮添加剂进行制备，其中，该含氮添加剂可以在燃料电池运行时防止添加剂在强酸性气氛下析出，具有优异的化学稳定性以耐受强酸性气氛，可以溶解在各种通用有机溶剂中，具有优越的加工性能，可以与含离子基聚合物混合，并且可以防止在膜形成期间发生相分离，并且可以防止在膜形成期间形成类似于海岛-海洋的相分离结构或者出现出血现象；以及使用该聚合物电解质组成物制备的聚合物电解质膜、膜电极组件和聚合物电解质燃料电池。本发明的聚合物电解质组成物包括至少一种含离子基的聚合物(A)和一种含氮添加剂(B)，所述聚合物电解质组成物的特点是该含氮添加剂(B)由一种特定的结构式表示。
• MATERIAL FOR LUMINESCENT ELEMENT AND LUMINESCENT ELEMENT
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1783189A1

  公开（公告）日：2007-05-09

  The invention provides a light emitting device having a low driving voltage and excellent durability by a material for a light emitting device expressed by the general formula (1) : wherein each of R1, R2, R3, R4, R5 and R6 may be the same or different and is selected from hydrogen, an alkyl group, and an aryl group, A represents an n-valent aromatic hydrocarbon group, B represents an alkyl group or an aryl group, X represents carbon or nitrogen, n represents a natural number from 2 to 6, and n substituents having a phenanthroline skeleton or a benzoquinoline skeleton may be the same or different.

  本发明通过通式（1）表示的发光器件材料，提供了一种驱动电压低、耐用性好的发光器件： 其中，R1、R2、R3、R4、R5 和 R6 中的每一个可以相同或不同，并且选自氢、烷基和芳基；A 代表 n 价芳烃基团；B 代表烷基或芳基；X 代表碳或氮；n 代表 2 至 6 的自然数；具有菲咯啉骨架或苯并喹啉骨架的 n 个取代基可以相同或不同。
• LIGHT EMITTING ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2595208A1

  公开（公告）日：2013-05-22

  Provided is an organic thin film light emitting element which has achieved all of improved luminous efficiency, improved driving voltage and improved durability life. Specifically provided is a light emitting element which comprises a hole transport layer and an electron transport layer between a positive electrode and a negative electrode and emits light by means of electrical energy. The light emitting element is characterized in that: the hole transport layer of the light emitting element contains a compound represented by general formula (1); the electron transport layer contains a donor compound; and the donor compound is an alkali metal, an inorganic salt containing an alkali metal, a complex of an alkali metal and an organic substance, an alkaline earth metal, an inorganic salt containing an alkaline earth metal, or a complex of an alkaline earth metal and an organic substance. (In the formula, R1-R20 each represents one group selected from the group consisting of hydrogen, deuterium, an alkyl group, a cycloalkyl group, an amino group, an aryl group, a heterocyclic group, a heteroaryl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, analkoxy group, an alkylthio group, an arylether group, an arylthioethergroup, a halogen, a cyano group, a -P(=O)R24R25 group and a silyl group;R24 and R25 each represents an aryl group or a heteroaryl group; and these substituents may be further substituted, or adjacent two substituents may combine together to form a ring. Meanwhile, R21-R23 may be the same or different and each represents one group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a heteroaryl group; and these substituents maybe further substituted.)

  本发明提供了一种有机薄膜发光元件，它实现了发光效率的提高、驱动电压的提高和耐用寿命的提高。具体地说，本发明提供了一种发光元件，它包括位于正极和负极之间的空穴传输层和电子传输层，并通过电能发光。该发光元件的特征在于：发光元件的空穴传输层含有通式（1）表示的化合物；电子传输层含有供体化合物；供体化合物是碱金属、含碱金属的无机盐、碱金属和有机物的复合物、碱土金属、含碱土金属的无机盐或碱土金属和有机物的复合物。(式中，R1-R20 各代表一个选自氢、氘、烷基、环烷基、氨基、芳基、杂环基、杂芳基、烯基、环烯基、炔基、烷氧基、烷硫基、芳醚基、芳硫醚基、卤素、氰基、-P(=O)R24R25 基和硅烷基的基团；R24 和 R25 分别代表芳基或杂芳基；这些取代基可以进一步被取代，或者相邻的两个取代基可以结合在一起形成一个环。同时，R21-R23 可以相同或不同，各自代表一个选自烷基、环烷基、芳基和杂芳基的基团；这些取代基可能被进一步取代）。